Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

The next few years of the ICES Journal of Marine Science

This issue marks a change in the editorial team of the ICESJournal of Marine Science, in that we have bid farewell to ourformer Editor-in-Chief, Niels Daan, after six years of sterlingservice, and to our Elsevier Publishing Editor, Andrew Richford,after an even longer period of years. Both deserve credit fortheir energy and vision that has left us the legacy of a journalas widely read and cited as the ICES Journal now is, but theyleave a gap that will be a huge challenge for us to meet. However,in my new capacity as Editor-in-Chief and in Els Bosma's capacityas Elsevier's Publishing Editor, I     

Simulation of Hydrophysical Processes in Coastal Regions of the Sea

In the present work, we generalize the results of our investigations in the field of simulation of hydrophysical and ecological processes in coastal regions of various seas and some closed basins. The developed and applied mathematical models and the results of numerical experiments are briefly analyzed.     

Phototoxicity of pyrene and benzo[a]pyrene to embryo-larval stages of the Pacific oyster Crassostrea gigas

There is a growing body of evidence to suggest that certain polycyclic aromatic hydrocarbons (PAHs) pose a greater hazard to aquatic organisms than previously demonstrated, due to their potential to cause photo-induced toxicity when exposed to ultraviolet (UV) radiation. The consequences of photo-induced toxicity are reported here for embryo-larval stages of the pacific oyster Crassostrea gigas, following exposure to pyrene and benzo[a]pyrene. During laboratory investigations, significant increases in toxicity were observed in the presence of environmentally attainable levels of UV-radiation, compared with embryos exposed to PAH alone, at levels previously deemed to have little acute biological effect. The phototoxicity of pyrene and benzo[a]pyrene completely inhibited the development to the D-shell larval stage when embryos were simultaneously exposed to 5 microg l(-1) PAH and ultraviolet light (UVB = 6.3 +/- 0.1 microW/cm2 and UVA = 456.2 +/- 55 microW/cm2). A linear relationship was also demonstrated for benzo[a]pyrene phototoxicity with decreasing UV light intensity.     

Path following control system for a tanker ship model

A two-dimensional path following control system for autonomous marine surface vessels is presented. The guidance system is obtained through a way-point guidance scheme based on line-of-sight projection algorithm and the speed controller is achieved through state feedback linearization. A new approach concerning the calculation of a dynamic line-of-sight vector norm is presented which main idea is to improve the speed of the convergence of the vehicle to the desired path. The results obtained are compared with the traditional line-of-sight scheme. It is intended that the complete system will be tested and implemented in a model of the “Esso Osaka” tanker. The results of simulations are presented here showing the effectiveness of the system aiming in to be robust enough to perform tests either in tanks or lakes.     

Time domain modelling of the transient asymmetric flooding of Ro-Ro ships

This work aims at contributing to improve knowledge on transient asymmetric flooding through theoretical and experimental research. First, a time domain theoretical model of ship motions and flooding is described. Results from experimental work are presented evidencing that transient asymmetric flooding may cause the capsizing of a Ro-Ro shaped barge. The theoretical model is used to predict the capsize of the Ro-Ro shaped barge. Reasonable agreement between experimental and theoretical results was found. Finally, a review of the European Gateway accident is given and the theoretical model is applied to the study of this type of accident. The conclusion is that this theoretical model, together with an accurate modelling of the flooding of machinery compartments, reproduces successfully the capsizing of the European Gateway due to transient asymmetric flooding. Therefore, the internal arrangement of Ro-Ro ships should be carefully studied at the design stage in order to avoid this phenomenon.     

Quantitative distribution of meiobenthos in deep-water zones of the World Ocean

An analysis of published and original data on the meiobenthos abundance in the depth interval from 100 to 9807 m (in total, 665 records, 445 of them obtained for depths exceeding 1000 m) revealed general regularities in its distribution. The influence of the sampling and data processing methods on the quantitative estimates of the meiobenthos abundance is considered to demonstrate changes in the proportions of the main meiobenthic taxa at different depths and to characterize latitudinal changes in the meiobenthos abundance. The dependence of the abundance of free-living nematodes, the most abundant group of metazoan meiobenthos, on trophic conditions is analyzed. No significant differences in the meiobenthos abundance in the samples obtained by box-and multicorers are established. It is shown that the share of nematodes in metazoan meiobenthos communities increases with the depth. In temperate latitudes, a distinct maximum in the population density confined to depths exceeding 1 km is observed. The quantitative distribution of the meiobenthos at the depths gradient is controlled by the bottom macrotopography and trophic conditions.     

Reflection of large-scale inhomogeneities in the air-sea boundary layer on the intensity of surface wave breaking in the ocean

An overview of experiments is given on the observation of the dependence of the intensity of wind wave breaking on large-scale currents' inhomogeneities and atmospheric boundary layer stratification. The data were interpreted using a model in which the variance of the wind wave breaking intensity reflects fluctuations in the influx of energy to wind waves due to various factors. Translated by V. Puchkin.