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61.
The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S2 generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S2 generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S2 generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen. 相似文献
62.
Surface aeration experiments were conducted in two types of rectangular tanks of aspect ratios i.e., length to width ratio (L/W) of 1.5 and 2 and developed simulation equations to correlate the oxygen transfer coefficient, k and power number, P0 with a parameter governing theoretical power per unit volume X. The parameter X is defined as equal to F4/3R1/3, where F and R are impellers’ Froude and Reynolds numbers respectively). Results have shown that the P0 can not be simulated singularly with either Reynolds number, R or Froude number, F, which results in scale-effects; there appears to be a need to incorporate the effects of both F and R. It was found that P0 is uniquely related to X for rectangular aeration tanks of both aspect ratios, however, such relationships are different depending upon the aspect ratios. It has been demonstrated that energy can be saved substantially if the aeration tanks are run at relatively higher input powers. It is also demonstrated that smaller sized tanks are more energy conservative and economical when compared to big sized tanks, while aerating the same volume of water, and at the same time by maintaining a constant input power in all the tanks irrespective of their size. 相似文献
63.
J.K. Tomson Y.J. Bhaskar Rao T. Vijaya Kumar J. Mallikharjuna Rao 《Gondwana Research》2006,10(1-2):115
Major, trace element compositions and Sr–Nd isotopic characteristics of charnockitic gneisses from the Southern Granulite Terrain (SGT), South India are presented. The study region encompasses the central segment of the Cauvery Shear Zone system (CSZ) and regions within the Madurai Block (MB) immediately south of it (designated here as the CSZ/MB and MB domains). Differences in the compositions and source characteristics between charnockitic rocks of the CSZ vis-à-vis those of the CSZ/MB and MB regions are highlighted. Foremost, the charnockites and enderbites of the CSZ show highly fractionated REE patterns with positive Eu-anomalies, depleted HREE, Y and near chondritic εNd0 and initial-87Sr/86Sr at ca. 2.5 Ga, consistent with hydrous partial melting of amphibolitic crust with residual garnet and hornblende for the parental melts. By contrast, modeled at ca. 1.8 Ga and 0.8 Ga, the CSZ/MB and MB charnockitic rocks, which show a wider range of Ti and P, relatively lower degree of HREE depletion, commonly negative Eu-anomalies and undepleted Y, present clear evidence for involvement of Archaean crustal components in sources of their magmatic protoliths. There is also evidence for significant intracrustal melting processes within a thickened crust at elevated temperatures between 800 and 1000 °C. Implications to the controversial Archaean–Neoproterozoic terrane boundary problem of the SGT are discussed. 相似文献
64.
Subrata Kumar Majumder Kamal ChandnaDhiren Sankar De Gautam Kundu 《International Journal of Mineral Processing》2006
Experiments were carried out to investigate the rheological properties of coal–oil–water suspension containing solids of different sizes. Two different coal samples with mean particle sizes of 120 mesh, 175 mesh and 220 mesh were used. The coal concentration was varied from 5% to 25% by weight. Sodium silicate has been used as an additive to study the behavior of the variation of average viscosity of the suspension. A generalized correlation has been developed to predict the average viscosity of suspension in terms of particle diameter of the coal, concentration of coal, viscosity of the suspending medium and the concentration of water. Experimental investigations revealed that coal–oil–water suspensions show an increase in the viscosity with decrease in coal size but with the addition of an additive, the average viscosity tends to decrease initially up to a certain optimum dosages and thereafter it increases with further addition of additives. Two empirical correlations are proposed for average viscosity of the coal–oil–water suspension, μsL in terms of physical properties of the solid and viscosity of the suspending medium with and without additives. 相似文献
65.
Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which
makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization
of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary
to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms
for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model
appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the
random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions
correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they
are layer specific and include uncertainty caused by using variance estimates. 相似文献
66.
67.
68.
韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例 总被引:6,自引:0,他引:6
韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例,通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比,确定等比线斜率,探讨韧性变形对岩石体积和成分变异的影响。计算结果表明,在糜棱岩化过程中,糜棱岩化花岗岩体积亏损21%,花岗质糜棱岩体积亏损31%。质量平衡计算结果和等比线图表明,韧;陛剪切作用导致SiO2,流失量最大,A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失,显示出较强的活动性,MnO、P2O5、Sc位于等比线上或附近,表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的,不活动组分的变异是体.积亏损造成的。 相似文献
69.
K. V. Sanil Kumar P. V. Hareesh Kumar 《Journal of the Indian Society of Remote Sensing》2005,33(1):137-146
Eddies and planetary waves are identified as one of the important factors that control the dynamics of the Arabian Sea. During
10–14 January 1990, Ignat, Paulyuchenkov (USSR ship) conducted an experiment in the central Arabian Sea and of late TOPEX/POSEIDON
satellites collected data on sea surface height (SSH) anomalies of the Arabian Sea. These data sets give an opportunity to
understand the characteristic of eddies and planetary waves in this region during winter. The geostrophic flow revealed three
anticyclonic and two cyclonic eddies of diameters ranging from 75 to more than 150 km from surface to subsurface levels. Current
speeds around different eddies were maximum at surface and varied from 9 cm/s to 25 cm/s (at the middle point between the
center and periphery). The occurrence of eddies were further investigated with the TOPEX/POSEIDON altimetry for the years
1993–97. The analysis revealed multiple eddies of diameter 100 to 550 km occur every year with maximum number of eddies during
1997 and minimum during 1995. The calculated speed varied between 8–30 cm/s around various eddies.
Longitude-Time plots showed annual Rossby waves generating at the eastern Arabian Sea and propagating westwards with a phase
speed of ~ 10 cm/s along 16° N. Further, it was observed that these waves arrived in the study area by January. In addition,
another positive anomaly of SSH was found generating at the western Arabian Sea simultaneously and extended up to the study
region by April–June. Time series of SSH at selected locations along 16°N revealed many small-scale oscillations and their
spatial variability. These oscillations were delineated using the FFT analysis. Other than the Rossby wave, the major components
at the study region were 40–60 and 26–32 day oscillations. The implications of these long period waves associated with eddies
are discussed. 相似文献
70.
S. Nakamoto S. Prasanna Kumar J. M. Oberhuber H. Saito K. Muneyama R. Frouin 《Journal of Earth System Science》2002,111(3):339-349
Western tropical Indian Ocean, Arabian Sea, and the equatorial Pacific are known as regions of intense bio-chemical-physical
interactions: the Arabian Sea has the largest phytoplankton bloom with seasonal signal, while the equatorial Pacific bloom
is perennial with quasi-permanent upwelling. Here, we studied three dimensional ocean thermodynamics comparing recent ocean
observation with ocean general circulation model (OPYC) experiment combined with remotely sensed chlorophyll pigment concentrations
from the Coastal Zone Color Scanner (CZCS). Using solar radiation parameterization representing observations that a higher
abundance of chlorophyll increases absorption of solar irradiance and heating rate in the upper ocean, we showed that the
mixed layer thickness decreases more than they would be under clear water conditions. These changes in the model mixed layer
were consistent with Joint Global Ocean Flux Study (JGOFS) observations during the 1994-1995 Arabian Sea experiment and epi-fluorescence
microscopy (EFM) on samples collected during Equatorial Pacific Ocean Climate Study (EPOCS) in November, 1988. In the Arabian
Sea, as the chlorophyll concentrations peak in October (3 mg/m3) after the summer plankton bloom induced by coastal upwelling, the chlorophyll induced biological heating enhanced the sea
surface temperature (SST) by as much as 0.6‡C and sub-layer temperature decreases and sub-layer thickness increases. In the
equatorial Pacific, modest concentrations of chlorophyll less than 0.3 mg/m3 is enough to introduce a meridional differential heating, which results in reducing the equatorial mixed layer thickness
to more than 20 m. The anomalous meridional tilting of the mixed layer bottom enhances off equatorial westward geostrophic
currents. Consequently, the equatorial undercurrent transports more water from west to east. We proposed that these numerical
model experiments with use of satellite andin situ ocean observations are consistent under three dimensional ocean circulation theory combined with solar radiation transfer
process. 相似文献