The potential origins and palaeoenvironmental implications of high temporal resolution δO heterogeneity in coral skeletons

δ¹⁸O was determined at high spatial resolution (beam diameter ∼30 μm) by secondary ion mass spectrometry (SIMS) across 1-2 year sections of 2 modern Porites lobata coral skeletons from Hawaii. We observe large (>2‰) cyclical δ¹⁸O variations that typically cover skeletal distances equivalent to periods of ∼20-30 days. These variations do not reflect seawater temperature or composition and we conclude that skeletal δ¹⁸O is principally controlled by other processes. Calcification site pH in one coral record was estimated from previous SIMS measurements of skeletal δ¹¹B. We model predicted skeletal δ¹⁸O as a function of calcification site pH, DIC residence time at the site and DIC source (reflecting the inputs of seawater and molecular CO₂ to the site). We assume that oxygen isotopic equilibration proceeds at the rates observed in seawater and that only the aqueous carbonate ion is incorporated into the precipitating aragonite. We reproduce successfully the observed skeletal δ¹⁸O range by assuming that DIC is rapidly utilised at the calcification site (within 1 h) and that ∼80% of the skeletal carbonate is derived from seawater. If carbonic anhydrase catalyses the reversible hydration of CO₂ at the calcification site, then oxygen isotopic equilibration times may be substantially reduced and a larger proportion of the skeletal carbonate could be derived from molecular CO₂. Seasonal skeletal δ¹⁸O variations are most pronounced in the skeleton deposited from late autumn to winter (and coincide with the high density skeletal bands) and are dampened in skeleton deposited from spring to summer. We observed no annual pattern in sea surface temperature or photosynthetically active radiation variability which could potentially correlate with the coral δ¹⁸O. At present we are unable to resolve an environmental cue to drive seasonal patterns of short term skeletal δ¹⁸O heterogeneity.     

Paleoenvironmental reconstruction of Holocene coastal sediments adjacent to archaeological ruins in Aqaba,Jordan

Stratified cultural remains from the Early Roman/Nabataean to Byzantine periods in the coastal zone of Aqaba, Jordan, and analyses of thirteen sediment cores provide evidence for changes in the depositional environment during the Holocene. The overall trend in subsurface sediments is a basal marine transgressive layer overlain by a regressional sequence of embayment lagoonal sediments identified from microfossil analyses, and backshore pond, alluvium, and eolian deposits until the 1st century B.C., when mudbrick structures appear. Based on two radiocarbon dates, a brackish water coastal embayment formed prior to ca. 5900–5700 B.C. and was subsequently filled by siltation. Local tectonic subsidence along faults of the Dead Sea transform may have helped form the lagoon. Freshwater Candona sp. ostracods found in sand layers in the lagoon facies show signs of having been transported and redeposited. These data indicate that lakes or marshes were likely located inland of the study area. Supporting faunal and floral evidence for wetter climatic conditions, wetland habitats, and extensive water diversion and agricultural terraces has been excavated at late Chalcolithic (4000–3500 B.C.) sites in the Aqaba region (Khalil & Schmidt, 2009 ). By the 8th century B.C., the depositional environment along the coastal plain of Aqaba was dominated by distal alluvial fan and eolian sedimentation and the shoreline had prograded about 400m seaward. The migration of human settlements since the 8th century B.C. from the center of the valley toward the southeast may be driven by the changing course of Wadi Yutim and conditions along the coastal plain. © 2010 Wiley Periodicals, Inc.     

Tropical and extratropical cyclone damages under climate change

This paper provides the first quantitative synthesis of the rapidly growing literature on future tropical and extratropical cyclone damages under climate change. We estimate a probability distribution for the predicted impact of changes in global surface air temperatures on future storm damages, using an ensemble of 478 estimates of the temperature-damage relationship from nineteen studies. Our analysis produces three main empirical results. First, we find strong but not conclusive support for the hypothesis that climate change will cause damages from tropical cyclones and wind storms to increase, with most models predicting higher future storm damages due to climate change. Second, there is substantial variation in projected changes in losses across regions. Potential changes in damages are greatest in the North Atlantic basin, where the multi-model average predicts that a 2.5 °C increase in global surface air temperature would cause hurricane damages to increase by 63 %. The ensemble predictions for Western North Pacific tropical cyclones and European wind storms (extratropical cyclones) are +28 % and +23 %, respectively. Finally, our analysis shows that existing models of storm damages under climate change generate a wide range of predictions, ranging from moderate decreases to very large increases in losses.     

A temperature-induced reversible transformation between paratacamite and herbertsmithite

The crystal chemistry of paratacamite has been re-evaluated by studying a crystal from the holotype specimen BM86958 of composition Cu_3.71Zn_0.29(OH)₆Cl₂ using single-crystal X-ray diffraction at 100, 200, 300, 353, 393 and 423 K. At 300 K paratacamite has space group $R\bar{3}$ with unit-cell parameters a 13.644 and c 14.035 Å and exhibits a pronounced subcell, a′ = ½a and c′ = c, analogous to that of the closely related mineral herbertsmithite, Cu₃Zn(OH)₆Cl₂. Between 353 and 393 K, paratacamite undergoes a reversible phase transformation to the herbertsmithite-like substructure, space group $R\bar{3}m$ , unit-cell parameters a 6.839 and c 14.072 Å (393 K). The transformation is characterised by a gradual reduction in intensity of superlattice reflections, which are absent at 393 and 443 K. On cooling from 443 to 300 K at ~10 K min^?1, the superlattice reflections reappear and the refined structures ( $R\bar{3}$ ) of the initial and recovered 300 K states are almost identical. The complete reversibility of the transformation establishes that paratacamite of composition Cu_3.71Zn_0.29(OH)₆Cl₂ is thermodynamically stable at ambient temperatures. The nature of the rhombic distortion of the M(2)O₆ octahedron is discussed by considering two possibilities that are dependent upon the nature of cation substitution in the interlayer sites.     

3D Elastic Solutions for Laterally Loaded Discs: Generalised Brazilian and Point Load Tests

This paper investigates the application of a double Fourier series technique to the construction of an elastic stress field in a cylindrical bar subject to lateral boundary loads. The lateral loads, including the constant load boundary conditions, are represented by two Fourier series: one on the perimeter of the circular section (r ₀, θ) and the other on the longitudinal curved surface parallel to the bar axis (z). The technique invokes acceptable potential functions of the Papkovich–Neuber displacement field, satisfying the governing partial differential equations, to assign appropriate odd and even trigonometric Fourier terms in cylindrical coordinates (r, θ, z). The generic solution decomposes the problem of interest to a state of stress caused by two independent boundary conditions along the z axis and θ-polar angle, both superimposed on a solution for which these potentials are the product of the trigonometric terms of the independent variables (θ, z). Constants appearing in the resultant second-order partial differential equations are determined from the generally mixed (tractions and/or displacements) boundary conditions. While the solutions are satisfied exactly at the ends of an infinite bar, they are satisfied weakly on average, in the light of Saint Venant’s approximation at the two ends of a finite bar. The application of the proposed analysis is verified against available elastic solutions for axisymmetric and non-axisymmetric engineering problems such as the indirect Brazilian Tensile Strength and Point Load Strength tests.     

Automated design of gravity-assist trajectories to Mars and the outer planets

In this paper, a new approach to planetary mission design is described which automates the search for gravity-assist trajectories. This method finds all conic solutions given a range of launch dates, a range of launch energies and a set of target planets. The new design tool is applied to the problems of finding multiple encounter trajectories to the outer planets and Venus gravity-assist trajectories to Mars. The last four-planet grand tour opportunity (until the year 2153) is identified. It requires an Earth launch in 1996 and encounters Jupiter, Uranus, Neptune, and Pluto. Venus gravity-assist trajectories to Mars for the 30 year period 1995–2024 are examined. It is shown that in many cases these trajectories require less launch energy to reach Mars than direct ballistic trajectories.Assistant Professor, School of Aeronautics and AstronauticsGraduate Student, School of Aeronautics and Astronautics     

The structure and composition of metal particles in two type 6 ordinary chondrites

Abstract— The purpose of this study is to examine, using light optical and electron optical techniques, the microstructure and composition of metal particles in ordinary chondritic meteorites. This examination will lead to the understanding of the low temperature thermal history of metal particles in their host chondrites. Two type 6 falls were chosen for study: Kernouvé (H6) and Saint Severin (LL6). In both meteorites, the taenite particles consisted of a narrow rim of high Ni taenite and a central region of cloudy zone similar to the phases observed in iron meteorites. The cloudy zone microstructure was coarser in Saint Severin than in Kernouvé due to the higher bulk Ni content of the taenite and the slower cooling rate, 3 K Ma^?1 vs. 17 K Ma^?1. Three microstructural zones were observed within the high Ni taenite region in both meteorites. The origin of the multiple zones is unknown but is most likely due to the high Ni taenite cooling into the two phase γ″ (FeNi) + γ′ (FeNi₃) region of the low temperature Fe-Ni phase diagram. Another explanation may be the presence of uniform size antiphase boundaries within the high Ni taenite. Finally, abnormally wide high Ni taenite regions are observed bordering troilite. The wide zones are probably caused by the diffusion of Ni from troilite into the high Ni taenite borders at low cooling temperatures.     

Petroleum geoscience in Norden - exploration, production and organization

Offshore exploration in Norway and Denmark-in the North Sea, the Norwegian Sea and the Barents Sea-has involved drilling about 850 wildcat wells, resulting in about 300 oil and gas finds, of which 84 are fields with production. The recoverable resources of all these finds total about 65 billion barrels of oil equivalent. Almost all these hydrocarbons come from a Jurassic source and the main reservoirs and traps are Jurassic sandstones in fault blocks and Paleocene sandstones or Cretaceous chalks in gentle domes. The article describes four major fields-Ekofisk, Gullfaks, Ormen Lange and SnФhvitto illustrate some of the many challenges in developing and producing the hydrocarbons.
Elsewhere in Norden, there has been much less exploration. Drilling results have mostly been negative in mainland Sweden, onshore Denmark, onshore Svalbard and on- and offshore West Greenland. Minor oil finds have been made in Palaeozoic rocks in the Baltic Sea. The first wells have recently been drilled off the Faroe Islands, resulting in one discovery. No drilling has taken place on- or offshore East Greenland.
As a result of the hydrocarbon activities in Norway and Denmark, petroleum geoscience there has flourished, with 2000 geoscientists currently employed in the industry, many technical innovations made, a wealth of publically available information and a great increase in the understanding of the geology.