Treatment of Malting Wastewater in a Granular Sludge Sequencing Batch Reactor (SBR)

Aerobic granular sludge was successfully cultivated in a sequencing batch reactor (SBR) treating wastewater from the malting process with a high content of particulate organic matter. At an organic loading rate of 3.2 kg/(m³ d) COD_total and an influent particle concentration of 0.95 g/L MLSS an average removal of 50% in COD_total and 80% in COD_dissolved could be achieved. A comparison of granular and flocculent sludge grown under the same operating conditions showed no significant difference in removal efficiency although granules exhibited a higher metabolic activity in terms of specific oxygen uptake rate (r_{O2, X}). Two distinct mechanisms of particle removal were observed for granular sludge: during initial granule formation, particles were incorporated into the biofilm matrix. For mature granules, a high level of protozoa growth on the granule surface accounted for the ability to remove particulate COD. Combined evaluation of the development in MLSS content and sludge bed settling rate (i.e., mean derivative of the normalized sludge volume) was found to be an adequate method for monitoring the characteristic settling properties of a granulizing sludge bed. By means of this method, a distinct substrate gradient out of several operating conditions was concluded to have the biggest impact on the formation of aerobic granular sludge.     

Estimating the seismic displacement of friction pendulum isolators based on non‐linear response history analysis

A procedure for developing equations that estimate the isolator displacement due to strong ground motion is applied to buildings isolated with the friction pendulum system. The resulting design equations, based on rigorous non‐linear analysis, offer an alternative to the iterative equivalent‐linear methods used by current U.S. building codes. The governing equations of the system are reduced to a form such that the median normalized displacement of the system due to an ensemble of ground motions is found to depend on only the isolation period—a function of the curvature of the isolator—and the friction force at incipient slip normalized by peak ground velocity. The normalization is effective in minimizing the dispersion of the normalized displacement for an ensemble of ground motions, implying that the median normalized displacement is a reliable estimate of response. The design equations reflect the significant (20 to 38%) increase in displacement when the excitation includes two lateral components of ground motion instead of just one component. Equivalent‐linear methods are shown to underestimate by up to 30% the exact median displacement determined by non‐linear response history analysis for one component of ground motion, and building codes include at most a 4.4% increase for a second component. Copyright © 2003 John Wiley & Sons, Ltd.     

Uniting space, ground, and underwater measurements for improved estimates of rain rate

Global precipitation is monitored from a variety of platforms including spaceborne, ground-, and ocean-based platforms. Intercomparisons of these observations are crucial to validating the measurements and providing confidence for each measurement technique. Probability distribution functions of rain rates are used to compare satellite and ground-based radar observations. A preferred adjustment technique for improving rain rate distribution estimates is identified using measurements from ground-based radar and rain gauges within the coverage area of the radar. The underwater measurement of rainfall shows similarities to radar measurements, but with intermediate spatial resolution and high temporal resolution. Reconciling these different measurement techniques provides understanding and confidence for all of the methods.     

Web-cam’s potential for collaborative activities in the Earth sciences

We report here our experiences from using easily acquired web-cam components for collaborative ventures in the Earth sciences. We have used a variety of hardware and different software. We demonstrate from various locations in the U.S.A. the feasibility of using web-cam in multitudinous activities, relevant for conducting research and knowledge dissemination. We summarize the quality of the connections from the various combinations of communicating parties. Today, web-cams can be utilized as an economical and viable means of point-to-point communication in the Earth science community. Greater bandwidth is sorely needed for activities such as multi-party conferencing on the present internet network. We propose that web-cam can be readily deployed as a web-service for facilitating collaborative research over the GRID infrastructure, using the middleware Narada-Brokering. Web-cam will play an important role in the emerging field of geoinformatics.     

Organic matter in small mesopores in sediments and soils

The three-way correlation among organic matter concentrations, specific surface area and small mesopores observed for many soils and sediments led to the hypothesis that enclosure within the pores might explain the apparent protection of organic matter by minerals. We test this hypothesis by examining whether the bulk of organic matter resides within small mesopores. Pore volumes as a function of pore width were measured before and after organic matter removal, and the volume differences ascribed to organic matter filling of pores. Minor changes in small mesopore size distributions upon treatments such as centrifugation and muffling indicate the robustness of the mineral matrices that form these pores. We developed an additional method to assess organic matter densities using high-resolution pycnometry, and used these densities to convert pore volumes to organic matter contents. Although smaller mesopores are shown to have sufficient volumes to contain significant fractions of the total organic matter, only small fractions of total organic matter were found to reside in them. These results are consistent with preferential association between organic matter and aluminous clay particle edges, rather than the largely siliceous clay faces that contribute most surface area and form pore walls. While simple enclosure within smaller mesopores cannot, therefore, explain protection, network effects working at larger size scales may account for exclusion of digestive agents and hence organic matter protection.     

Sulfur contents of the parental metallic cores of magmatic iron meteorites

Magmatic iron meteorites are thought to be samples of the central metallic cores of asteroid-sized parent bodies. Sulfur is believed to have been an important constituent of these parental cores, but due to the low solubility of S in solid metal, initial S-contents for the magmatic groups cannot be determined through direct measurements of the iron meteorites. However, experimental solid metal-liquid metal partition coefficients show a strong dependence on the S-content of the metallic liquid. Thus, by using the experimental partition coefficients to model the fractional crystallization trends within magmatic iron meteorite groups, the S-contents of the parental cores can be indirectly estimated. Modeling the Au, Ga, Ge, and Ir fractionations in four of the largest magmatic iron meteorite groups leads to best estimates for the S-contents of the parental cores of 12 ± 1.5 wt% for the IIIAB group, 17 ± 1.5 wt% for the IIAB group, and 1 ± 1 wt% for the IVB group. The IVA elemental fractionations are not adequately fit by a simple fractional crystallization model with a unique initial S-content. These S-content estimates are much higher than those recently inferred from crystallization models involving trapped melt. The discrepancy is due largely to the different partition coefficients that are used by the two models. When only partition coefficients that are consistent with the experimental data are used, the trapped melt model, and the low S-contents it advocates, cannot match the Ge and Ir fractionations that are observed in IIIAB iron meteorites.     

Beryllium-10 in Australasian tektites: Constraints on the location of the source crater

By using accelerator mass spectrometry we have measured the ¹⁰Be concentrations of 86 Australasian tektites. Corrected to the time of tektite production ∼0.8 My ago, the ¹⁰Be concentrations (10⁶ atom/g) range from 59 for a layered tektite from Huai Sai, Thailand, to 280 for an australite from New South Wales, Australia. The average value is 143 ± 50. When tektites are sorted by country, their average measured ¹⁰Be concentrations increase slowly with increasing distance from Southeast Asia, the probable location of the tektite producing event, from 59 ± 9 for 6 layered tektites from Laos to 136 ± 20 for 20 splash-form tektites from Australia. The lowest ¹⁰Be concentrations for tektites fall on or within a contour centered off the shore of Vietnam, south of the Gulf of Tonkin (107°E; 17°N), but also encompassing two other locations in the area of northeastern Thailand previously proposed for the site of a single tektite-producing impact. The ¹⁰Be concentrations of layered tektites show only a weak anticorrelation (R ∼ −0.3) with the numbers of relict crystalline inclusions.Loosely consolidated, fine-grained terrestrial sediments or recently consolidated sedimentary rocks are the most likely precursor materials. Dilution of sediments with other kinds of rock raises problems in mixing and is not supported by petrographic data. Sedimentary columns that have the right range of ¹⁰Be concentrations occur off the coasts of places where sedimentation rates are high relative to those in the deep sea. A single impact into such a region, 15 to 300 m thick, could have propelled near-surface, high-¹⁰Be material farthest—to Australia—while keeping the deeper-lying, low-¹⁰Be layers closer to home. We do not rule out, however, other proposed mechanisms for tektite formation.     

The pattern of supergranular in a solar active region and the formation of filaments

The formation of filaments in solar bipolar active regions is investigated, giving particular attention to the relationship between this process and the pattern of supergranular convection. SOHO MDI and Kitt Peak magnetograms and Hα filtergrams are used. The large decaying active region NOAA 8525 is considered over the period May 4–7, 1999. The boundaries of supergranules are identified as concentrations of the line-of-sight photospheric field in magnetograms. Filaments in the central part of the active region are studied; as a whole, they are aligned with the supergranule boundaries. Variations in the magnetic field in this period were manifest primarily in the form of “cancellations” and spatial-redistribution processes consistent with the pattern of developing supergranules. These factors created the conditions necessary for the formation of a filament stretched across the entire active region; i.e., the straightening of the polarity-inversion line and reduction of the horizontal gradients of the magnetic field. One possible explanation of the results is that the magnetic-field component along the filament axis is associated with the vortical structure of horizontal flows in the supergranulation cells.     

Differential rotation and meridional circulation near the boundaries of the solar convection zone

Although the theory of differential rotation is in satisfactory agreement with helioseismological data for the deep convection zone, there are considerable discrepancies near the solar surface. This disagreement can be eliminated if the anisotropy of turbulent convection is taken into account together with the effects of nonuniformity of the medium, on which the most recent models for differential rotation are based. The model for the differential rotation of the convection envelope is supplemented by computations for the transition layer between nonuniform and rigid-body rotation in the upper layers of the solar radiative zone. These are the first computations of differential rotation for the entire volume of the Sun.