Evaluating different GCMs for predicting spatial recharge in an irrigated arid region

Groundwater systems in arid regions will be particularly sensitive to climate change owing to the strong dependence of rates of evapotranspiration on temperature, and shifts in the precipitation regimes. Irrigation use in these arid regions is typically a large component of the water budget, and may increase due to changes in soil moisture resulting from higher temperatures and changes in the timing of precipitation events. In this study, future predicted climate change scenarios from three global climate models (CGCM1 GHG+A1, CGCM3.1 A2, and HadCM3 A2) are used to determine the sensitivity of recharge to different climate models in an irrigated agricultural region. The arid Oliver region (annual precipitation 300 mm) in the Okanagan Basin, British Columbia, is used to demonstrate the approach. Irrigation return flow, as a contribution to total diffuse recharge, is simulated by calculating the daily applied irrigation based on estimates of seasonal crop water demand and the forecasted precipitation and evaporation data. The relative contribution of irrigation return flow to groundwater recharge under current and future climate conditions is modelled. Temperature data were downscaled using Statistical Downscaling Model (SDSM), while precipitation and solar radiation changes were estimated directly from the GCM data. Shifts in climate, from present to future predicted, were applied to a stochastic weather generator, and used to force a one-dimensional hydrologic model, HELP 3.80D. Results were applied spatially, according to different soil profiles, slope and vegetation, over a 22.5 km by 8.6 km region. Changes to recharge in future time periods for each GCM result in modest increases of recharge with the peak recharge shifting from March to February. Lower recharge rates and higher potential evapotranspiration rates are similarly predicted by all three models for the summer months. All scenarios show that the potential growing season will expand between 3 and 4 weeks due to increases in temperature. However, the magnitude of the change varies considerably between models. CGCM3.1 has the largest increases of recharge rates, CGCM1 has very minor increases, and HadCM3 is relatively stable (as indicated by the near-zero changes between climate states). The significant differences between these three models indicate that prediction of future recharge is highly dependent on the model selected. The minor increase of annual recharge in future predicted climate states is due the shift of peak recharge from increased temperature. Irrigation rates dominate total recharge during the summer months in this arid area. Recharge in irrigated areas is significantly higher than natural recharge, with irrigation return flow between 25% and 58%. A comparison of recharge results for the least efficient and the most efficient irrigation systems indicates that the latter are more sensitive to choice of GCM.     

The partitioning of Triclosan between aqueous and particulate bound phases in the Hudson River Estuary

The distribution of Triclosan within the Hudson River Estuary can be explained by a balance among the overall effluent inputs from municipal sewage treatment facilities, dilution of Triclosan concentrations in the water column with freshwater and seawater inputs, removal of Triclosan from the water column by adsorption to particles, and loss to photodegradation. This study shows that an average water column concentration of 3 ± 2 ng/l (in the lower Hudson River Estuary) is consistent with an estimate for dilution of average wastewater concentrations with seawater and calculated rates of adsorption of Triclosan to particles. An average Triclosan sediment concentration of 26 ± 11 ng/g would be in equilibrium with the overlying water column if Triclosan has a particle-to-water partitioning coefficient of k_d  10⁴, consistent with laboratory estimates.     

Characterization of a mud deposit offshore of the Patos Lagoon,southern Brazil

Rapid deposition of mud on the beach along the shoreface of Rio Grande do Sul, Brazil dramatically influences the normal operations in the littoral zone. In the surf zone, fluid and suspended mud opposes water-wave movement and dissipates water-wave energy; on the beach, mud limits trafficability. As part of a multinational, multidisciplinary program to evaluate the influence of mud strength, density and viscosity on water-wave attenuation, sediments were evaluated in situ or collected for evaluation from an area offshore of Cassino Beach, slightly south of the Patos Lagoon mouth. Shear strength of deposited sediments ranged from 0.6 kPa at the seafloor to 3.4 kPa at ∼1 m below the seafloor. Mud sediments were also collected to simulate the in situ response of fluid mud to shear stresses. For this determination, rheological evaluations were made using a strain-controlled Couette viscometer on numerous remixed samples that ranged in density from 1.05 to 1.30 g/cm³. It was determined that this mud is a non-ideal Bingham material in that it has a true initial yield stress as well as a upper Bingham yield stress. Initial yield stress ranged from 0.59 to 2.62 Pa, upper Bingham yield stress ranged from 1.05 to 7.6 Pa. Apparent viscosity ranged from 0.02 to 4.7 Pa s with the highest viscosities occurring between the two yield stresses. Sediment strength in the remixed samples is 2 to 3 orders of magnitude lower than the horizontal shear strength of the sediment bed as determined by shear vane or predicted from penetrometer measurements. This difference is partially due to the fact that rheological evaluations are made on fully remixed sediments, whereas horizontal shear strength is determined within relatively undisturbed sediments. Similar values of viscosity and shear strength are comparable to those determined for mud in other coastal areas where fluid mud deposits occur.     

The COPAS’08 expedition to the Patagonian Shelf: Physical and environmental conditions during the 2008 coccolithophore bloom

Here we present observations of the hydrography of the Patagonian Shelf, shelf break and offshore waters, with reference to the environmental conditions present during the period of peak coccolithophore abundance. Analysis of a hydrographic dataset collected in December 2008 (austral spring/summer), as part of the Coccolithophores of the Patagonian Shelf (COPAS) research cruise, identified 5 distinct surface water masses in the region between 37°S and 55°S. These water masses, identified through salinity gradients, displayed varying mixed layer depths, macronutrient inventories and chlorophyll-a fluorescence. Subantarctic Shelf Water (SSW), located to the north of the Falkland Islands and extending north along the shelf break, was also host to a large coccolithophore bloom. The similarities between the distribution of calcite, as seen in remote sensing data, and SSW indicate that the coccolithophore bloom encountered conditions conducive to bloom development within this water mass. Analysis of chemical and environmental data also collected during the COPAS cruise revealed that many of the commonly cited conditions for coccolithophore bloom development were present within SSW (e.g. low N:P ratio, high N:Si ratio, shallow mixed layer depth). In the other water masses present on the Patagonian Shelf greater variability in these same parameters may explain the more diffuse concentration of calcite, and the smaller size of possible coccolithophore blooms. The distribution of SSW is strongly influenced by the latitudinal variation in shelf break frontal width, which varies from 20 to 200 km, and consequently strong hydrographic controls underlie the position of the coccolithophore bloom during austral summer.     

Nekton Use of Flooded Salt Marsh and an Assessment of Intertidal Creek Pools as Low-Tide Refuges

Patterns of nekton occurrence on the salt marsh surface at high tide and in an adjacent intertidal creek pool at low tide were used to investigate movements of nekton in an intertidal basin. Paired collections were made in North Inlet estuary, SC on 67 dates over 9 years. Comparisons of high- and low-tide total abundance indicated that what remained in the creek pool at low tide was representative of the nekton on the flooded marsh. Of the 64 taxa collected, the same 8 species ranked in the top 10 in both the high- and low-tide collections. Abundances of most resident species were positively correlated with the area of marsh flooded, but mummichog (Fundulus heteroclitus), the most abundant resident, was not. Abundances of young-of-the-year transient species were not related to the extent of tidal flooding. Some transient species used the flooded marsh but did not occupy the pool at low tide, and others found in the pool did not use the marsh. Differences in abundance, biomass, and length between the marsh and pool collections indicated differences in the tendency of species and life stages to retreat downstream of the pool to the subtidal channel. Proportionately more of the nekton that were present on the flooded marsh left the intertidal basin when large changes in temperature and salinity occurred between high and low tides. More transients left the basin following higher tides, but more residents did not. The results demonstrate a wide range of taxonomic and ontogenetic patterns among nekton using intertidal salt marsh basins and the underappreciated importance of intertidal creek pools as alternative low-tide refuges.     

Virus occurrence in private and public wells in a fractured dolostone aquifer in Canada

Groundwater samples from 22 wells completed in a regional fractured dolostone aquifer in the Guelph region of southern Ontario, Canada, were collected over an 8-month period and analyzed for viruses and Campylobacter jejuni. Only 8% of the 118 samples exhibited viruses at extremely low concentrations, but of the 22 wells sampled, 10 (45%) were positive for human enteric viruses (polyomavirus, adenovirus A, and GII norovirus) including 5 of the 8 public supply wells (62.5%) and 5 of the 11 private wells (45%). Each virus-positive well had only one virus occurrence with six sampling events during the 8-month sampling campaign and only one virus type was detected in each well. The probability of virus detection was positively associated with well open-interval length. Virus concentration (in the wells that were virus-positive) was negatively associated with well depth and open-interval length and positively associated with overburden thickness (i.e., the thickness of unconsolidated materials overlying bedrock facies) and the amount of precipitation 8–14 and 15–21 days prior to the sampling date. The ephemeral nature of the virus detections and the low detection rate on a per sample basis were consistent with previous studies. The percentage of virus-positive wells, however, was much higher than previous studies, but consistent with the fact that the hydrogeologic conditions of fractured bedrock aquifers create wide capture zones and short groundwater travel times to wells making them more vulnerable to contamination occurrence but at very low concentrations.     

Seeing through the magnetite:Reassessing Eoarchean atmosphere composition from Isua(Greenland) ≥3.7 Ga banded iron formations

Estimates of early atmosphere compositions from metamorphosed banded iron formations(BIFs)including the well-studied ≥3.7 BIFs of the Isua supracrustal belt(Greenland)are dependent on knowledge of primary versus secondary Fe-mineralogical assemblages.Using new observations from locally well preserved domains,we interpret that a previously assumed primary redox indicator mineral,magnetite,is secondary after sedimentary Fe-clays(probably greenalite)±carbonates.Within ~3.7 Ga Isua BIF,pre-tectonic nodules of quartz+Fe-rich amphibole±calcite reside in a finegrained(≤100 μm)quartz+magnetite matrix.We interpret the Isua nodule amphibole as the metamorphosed equivalent of primary Fe-rich clays,armoured from diagenetic oxidative reactions by early silica concretion.Additionally,in another low strain lacunae,~3.76 Ga BIF layering is not solid magnetite but instead fine-grained magnetite+quartz aggregates.These magnetite+quartz aggregates are interpreted as the metamorphosed equivalent of Fe-clay-rich layers that were oxidised during diagenesis,because they were not armoured by early silicification.In almost all Isua BIF exposures,this evidence has been destroyed by strong ductile deformation.The Fe-clays likely formed by abiotic reactions between aqueous Fe~(2+)and silica.These clays along with silica±carbonate were deposited below an oceanic Fe-chemocline as the sedimentary precursors of BIF.Breakdown of the clays on the sea floor may have been by anaerobic oxidation of Fe~(2+),a mechanism compatible with iron isotopic data previously published on these rocks.The new determinations of the primary redoxsensitive Fe-mineralogy of BIF significantly revise estimates of early Earth atmospheric oxygen and CO_2 content,with formation of protolith Fe-rich clays and carbonates compatible with an anoxic Eoarchean atmosphere with much higher CO_2 levels than previously estimated for Isua and in the present-day atmosphere.     

Multiple rainfall event pollution transport by sustainable drainage systems: the fate of fine sediment pollution

A key design criterion of sustainable urban drainage systems is to mitigate urban stormwater pollution. Current research defines sustainable urban drainage systems (SuDS) pollutant treatment efficiency through the detention of total suspended solids, urban nutrients and heavy metal pollutants within the system during a design flow event, with research focusing on sand (>2 mm) sediment movement. The impact of multiple rainfall–runoff events on the fine sediment (<2 mm) treatment efficiency of SuDS is not yet well defined, and the temporal movement of detained sediment has not been investigated in detail. The field research presented in this paper addresses this research gap, monitoring ongoing fine sediment transport through a best-practice-designed SuDS network over 12 months through the use of a novel rare earth oxide trace methodology. Through time-stepped monitoring of the fine sediment pollution across three SuDS treatment trains (networks), the following key conclusions have been drawn. (1) That fine sediment becomes re-suspended and re-deposited within SuDS assets and the network as a result of ongoing multiple rainfall–runoff events. (2) That this re-suspension continues for over 52 weeks. (3) That by area, linear wetlands (within the monitored networks) outperform wetland and swale assets in multiple event fine sediment detention. And (4) that multiple event monitoring and analysis of fine sediment within a SuDS network highlights the under-performance of SuDS assets against current design event expectations.     

Influence of Transport over a Mountain Ridge on the Chemical Composition of Marine Aerosols during the ACE-2 Hillcloud Experiment

Aerosol chemical composition and trace gas measurements were made at twolocations on the northeastern peninsula of Tenerife during the ACE-2HILLCLOUD experiment, between 28 June and 23 July 1997. Measurementswere made of coarse (#gt;2.5 m aerodynamic diameter) and fine (#lt; 2.5m) aerosol Cl^–, NO₃ ^–,SO₄ ^2–, non-sea saltSO₄ ^2– (NSSS),CH₃SO₃ ^– (MSA) andNH₄ ⁺, and gas phase dimethylsulphide (DMS), HCl,HNO₃, SO₂, CH₃COOH, HCOOH andNH₃. Size distributions were measured using a cascadeimpactor. Results show that in marine air masses NSSS and MSA wereformed via DMS oxidation, with additional NSSS present in air massescontaining a continental component. Using a Eulerian box model approachfor aerosols transported between upwind and downwind sites, a mean NSSSproduction rate of 4.36 × 10^–4 gm^–3 s^–1 was calculated for daytimeclear sky periods (highest insolation), with values for cloudy periodsduring daytime and nighttime of 3.55 × 10^–4 and2.40 × 10^–4 g m^–3s^–1, respectively. The corresponding rates for MSA were6.23 × 10^–6, 8.49 × 10^–6and 6.95 × 10^–6 g m^–3s^–1, respectively. Molar concentration ratios forMSA/NSSS were 8.7% (1.8–18.2%) and 1.9%(1.3–3.5%) in clean and polluted air masses, respectively.Reactions occurring within clouds appeared to have a greater influenceon rates of MSA production, than of NSSS, while conversely daytime gasphase reactions were more important for NSSS. For MSA, nighttimein-cloud oxidation rates exceeded rates of daytime gas phase productionvia OH oxidation of DMS. NSSS, MSA and ammonium had trimodal sizedistributions, with modes at 0.3, 4.0 and >10.0 m (NSSS andNH₄ ⁺), and 0.3, 1.5 and 4.0 m (MSA). Nosignificant production of other aerosol species was observed, with theexception of ammonium, which was formed at variable rates dependent onneutralisation of the aerosol with ammonia released from spatiallynon-uniform surface sources. Seasalt components were mainly present incoarse particles, although sub-micrometre chloride was also measured.Losses by deposition exceeded calculated expectations for all species,and were highest for the seasalt fraction and nitrate.