Association between Messinian drainage network formation and major tectonic activity in the Marche Apennines (Italy)

The Marche Apennines (Italy) offer an excellent opportunity to constrain the temporal and spatial relationships between drainage network formation and tectonic activity. Using a combination of field data, seismic lines and boreholes we show that the main deformation phase took place during the Messinian when the area, affected by the Messinian sea level drop, emerged and evolved from marine to continental conditions. The results highlight that during the Messinian emersion a drainage network developed contemporaneously with an increase in tectonic activity that could be related to sea level fall and river erosion. The present‐day river system, which is dominated by transverse rivers that cut straight across the tectonic grain, is located in older Messinian palaeovalleys, even though the region was subsequently covered by water until the late Pliocene–early Pleistocene.     

Chandra imaging of the complex X-ray core of the Perseus cluster

We report subarcsec-resolution X-ray imaging of the core of the Perseus cluster around the galaxy NGC 1275 with the Chandra X-ray Observatory . The ROSAT -discovered holes associated with the radio lobes have X-ray bright rims which are cooler than the surrounding gas and not a result of shocks. The holes themselves may contain some hotter gas. We map strong photoelectric absorption across the northern lobe and rim owing to a small infalling irregular galaxy, known as the high-velocity system. Two outer holes, one of which was previously known, are identified with recently found spurs of low-frequency radio emission. The spiral appearance of the X-ray cooler gas and the outer optical parts of NGC 1275 may be due to angular momentum in the cooling flow.     

The timing and extent of the eruption of the Siberian Traps large igneous province: Implications for the end-Permian environmental crisis

We present new high-precision ⁴⁰Ar/³⁹Ar ages on feldspar and biotite separates to establish the age, duration and extent of the larger Siberian Traps volcanic province. Samples include basalts and gabbros from Noril'sk, the Lower Tunguska area on the Siberian craton, the Taimyr Peninsula, the Kuznetsk Basin, Vorkuta in the Polar Urals, and from Chelyabinsk in the southern Urals. Most of the ages, except for those from Chelyabinsk, are indistinguishable from those found at Noril'sk. Cessation of activity at Noril'sk is constrained by a ⁴⁰Ar/³⁹Ar age of 250.3 ± 1.1 Ma for the uppermost Kumginsky Suite.The new ⁴⁰Ar/³⁹Ar data confirm that the bulk of Siberian volcanism occurred at 250 Ma during a period of less than 2 Ma, extending over an area of up to 5 million km². The resolution of the data allows us to confidently conclude that the main stage of volcanism either immediately predates, or is synchronous with, the end-Permian mass extinction, further strengthening an association between volcanism and the end-Permian crisis. A sanidine age of 249.25 ± 0.14 Ma from Bed 28 tuff at the global section and stratotype at Meishan, China, allows us to bracket the P–Tr boundary to 0.58 ± 0.21 myr, and enables a direct comparison between the ⁴⁰Ar/³⁹Ar age of the Traps and the Permo–Triassic boundary section.Younger ages (243 Ma) obtained for basalts from Chelyabinsk indicate that volcanism in at least the southern part of the province continued into the Triassic.     

Evaluating different GCMs for predicting spatial recharge in an irrigated arid region

Groundwater systems in arid regions will be particularly sensitive to climate change owing to the strong dependence of rates of evapotranspiration on temperature, and shifts in the precipitation regimes. Irrigation use in these arid regions is typically a large component of the water budget, and may increase due to changes in soil moisture resulting from higher temperatures and changes in the timing of precipitation events. In this study, future predicted climate change scenarios from three global climate models (CGCM1 GHG+A1, CGCM3.1 A2, and HadCM3 A2) are used to determine the sensitivity of recharge to different climate models in an irrigated agricultural region. The arid Oliver region (annual precipitation 300 mm) in the Okanagan Basin, British Columbia, is used to demonstrate the approach. Irrigation return flow, as a contribution to total diffuse recharge, is simulated by calculating the daily applied irrigation based on estimates of seasonal crop water demand and the forecasted precipitation and evaporation data. The relative contribution of irrigation return flow to groundwater recharge under current and future climate conditions is modelled. Temperature data were downscaled using Statistical Downscaling Model (SDSM), while precipitation and solar radiation changes were estimated directly from the GCM data. Shifts in climate, from present to future predicted, were applied to a stochastic weather generator, and used to force a one-dimensional hydrologic model, HELP 3.80D. Results were applied spatially, according to different soil profiles, slope and vegetation, over a 22.5 km by 8.6 km region. Changes to recharge in future time periods for each GCM result in modest increases of recharge with the peak recharge shifting from March to February. Lower recharge rates and higher potential evapotranspiration rates are similarly predicted by all three models for the summer months. All scenarios show that the potential growing season will expand between 3 and 4 weeks due to increases in temperature. However, the magnitude of the change varies considerably between models. CGCM3.1 has the largest increases of recharge rates, CGCM1 has very minor increases, and HadCM3 is relatively stable (as indicated by the near-zero changes between climate states). The significant differences between these three models indicate that prediction of future recharge is highly dependent on the model selected. The minor increase of annual recharge in future predicted climate states is due the shift of peak recharge from increased temperature. Irrigation rates dominate total recharge during the summer months in this arid area. Recharge in irrigated areas is significantly higher than natural recharge, with irrigation return flow between 25% and 58%. A comparison of recharge results for the least efficient and the most efficient irrigation systems indicates that the latter are more sensitive to choice of GCM.     

The partitioning of Triclosan between aqueous and particulate bound phases in the Hudson River Estuary

The distribution of Triclosan within the Hudson River Estuary can be explained by a balance among the overall effluent inputs from municipal sewage treatment facilities, dilution of Triclosan concentrations in the water column with freshwater and seawater inputs, removal of Triclosan from the water column by adsorption to particles, and loss to photodegradation. This study shows that an average water column concentration of 3 ± 2 ng/l (in the lower Hudson River Estuary) is consistent with an estimate for dilution of average wastewater concentrations with seawater and calculated rates of adsorption of Triclosan to particles. An average Triclosan sediment concentration of 26 ± 11 ng/g would be in equilibrium with the overlying water column if Triclosan has a particle-to-water partitioning coefficient of k_d  10⁴, consistent with laboratory estimates.     

Characterization of a mud deposit offshore of the Patos Lagoon,southern Brazil

Rapid deposition of mud on the beach along the shoreface of Rio Grande do Sul, Brazil dramatically influences the normal operations in the littoral zone. In the surf zone, fluid and suspended mud opposes water-wave movement and dissipates water-wave energy; on the beach, mud limits trafficability. As part of a multinational, multidisciplinary program to evaluate the influence of mud strength, density and viscosity on water-wave attenuation, sediments were evaluated in situ or collected for evaluation from an area offshore of Cassino Beach, slightly south of the Patos Lagoon mouth. Shear strength of deposited sediments ranged from 0.6 kPa at the seafloor to 3.4 kPa at ∼1 m below the seafloor. Mud sediments were also collected to simulate the in situ response of fluid mud to shear stresses. For this determination, rheological evaluations were made using a strain-controlled Couette viscometer on numerous remixed samples that ranged in density from 1.05 to 1.30 g/cm³. It was determined that this mud is a non-ideal Bingham material in that it has a true initial yield stress as well as a upper Bingham yield stress. Initial yield stress ranged from 0.59 to 2.62 Pa, upper Bingham yield stress ranged from 1.05 to 7.6 Pa. Apparent viscosity ranged from 0.02 to 4.7 Pa s with the highest viscosities occurring between the two yield stresses. Sediment strength in the remixed samples is 2 to 3 orders of magnitude lower than the horizontal shear strength of the sediment bed as determined by shear vane or predicted from penetrometer measurements. This difference is partially due to the fact that rheological evaluations are made on fully remixed sediments, whereas horizontal shear strength is determined within relatively undisturbed sediments. Similar values of viscosity and shear strength are comparable to those determined for mud in other coastal areas where fluid mud deposits occur.     

Gas and particle emissions from Soufrière Hills Volcano, Montserrat, West Indies: characterization and health hazard assessment

 The Soufrière Hills Volcano, Montserrat, erupting since 18 July 1995, intensified its degassing in early 1996 with the continuing growth of the lava dome inside the summit crater. During this period of increased activity, between 11 and 18 March 1996, we measured gases and particles within the visible plume to determine whether at that time it posed a health risk to the population of Plymouth, the capital town, which is 5 km southwest (downwind) and was then still occupied. Gravimetric measurements were made of total suspended particles (TSP) and particles having an aerodynamic diameter of less than 10 μm (PM₁₀). Measurements were made of sulphur dioxide (SO₂), hydrochloric acid (HCl), hydrofluoric acid (HF), nitric acid (HNO₃), acetic acid (CH₃COOH), formic acid (HCOOH), and particulate sulphate (SO₄ ^2–), chloride (Cl^–), nitrate (NO₃ ^–), fluoride (F^–), methanesulphonate (CH₃SO₃ ^–), acetate (CH₃COO^–), formate (HCOO^–), ammonium (NH₄ ⁺), sodium (Na⁺) and acidity (H⁺). Trace metals having human health implications [chromium (Cr), nickel (Ni), cobalt (Co), copper (Cu), zinc (Zn), arsenic (As), selenium (Se), cadmium (Cd), tin (Sn), mercury (Hg) and lead (Pb)] were also determined. Mean concentrations of HCl, SO₂ and HF obtained in the town of Plymouth were 14.0, 5.9 and 0.8 ppbv, respectively. Corresponding concentrations in the mixed plume on the crater edge were 533, 168 and 22 ppbv. There were no direct emissions of HNO₃, although nitrate was detected in coarse particles at the source. Higher concentrations of CH₃COOH and HCOOH were measured close to the crater. Mean TSP and PM₁₀ were 64 and 15 μg m^–3 in Plymouth, and 455 and 47 μg m^–3 on the upper volcano slope. Aerosols were highly acidic at the source but rapidly neutralised during transport. Trace metals were enriched in the aerosol relative to crater surface material. The concentrations of the acid gases, sulphur dioxide in particular, and particles were found to be too small to pose a health hazard at the time of these measurements, when relatively modest volcanic activity was occurring. Received: 9 September 1998 / Accepted: 29 August 1999     

Potential application of oxygen-18 and deuterium in mining effluent and acid rock drainage studies

 Oxygen-18 (¹⁸O) and deuterium (D, or ²H) are routinely used in hydrologic, climatologic and geothermal studies. In hydrology, stable isotopes provide information on the type and topology (altitude and latitude) of the recharge waters and the historical effects on water, related to such physical processes as evaporation (in ponds), melting (of snow or ice), condensation, evapotranspiration and mixing. In geothermal studies, stable isotopes provide key information related to recharge and the various temperature-dependent water/rock isotope exchange reactions. The latter is assessed through the oxygen shift in the ¹⁸O/D correlation. At acid rock drainage (ARD) sites, water/rock interactions are primarily controlled by pH and oxidation potential. Using the isotopic characteristics of the rocks and the recharge waters as a basis, the relative oxygen shift of the ARD effluent can provide information on: (1) the residence time, (2) the rate of water/rock reactions, and (3) the actual pH at the rock/water interface. This paper offers a methodology for conducting oxygen and hydrogen isotope studies related to ARD and other mineral effluent problems. The methodology is based on: (1) comprehensive sampling of regional waters, ARD effluent and major contributing minerals and rocks, (2) isotopic and elemental analysis, and (3) data interpretation on the basis of a zero-dimensional (mass balance), multi-component mixing model. Received: 15 January 1999 · Accepted: 3 May 1999