Using isotopes to understand the evolution of water ages in disturbed mixed land-use catchments

Tracer studies have been key to unravelling catchment hydrological processes, yet most insights have been gained in environments with relatively low human impact. We investigated the spatial variability of stream isotopes and water ages to infer dominant flow paths in a ~10-km² nested catchment in a disturbed, predominantly agricultural environment in Scotland. We collected long-term (>5 years) stable isotope data of precipitation, artificial drainage, and four streams with varying soil and land use types in their catchment areas. Using a gamma model, Mean Transit Times (MTTs) were then estimated in order to understand the spatial variability of controls on water ages. Despite contrasting catchment characteristics, we found that MTTs in the streams were generally very similar and short (<1 year). MTTs of water in artificial drains were even shorter, ranging between 1 to 10 months for a typical field drain and <0.5 to 1 month for a country road drain. At the catchment scale, lack of heterogeneity in the response could be explained by the extensive artificial surface and subsurface drainage, “short-circuiting” younger water to the streams during storms. Under such conditions, additional intense disturbance associated with highway construction during the study period had no major effect on the stream isotope dynamics. Supplementary short-term (~14 months) sampling of mobile soil water in dominant soil-land use units also revealed that agricultural practices (ploughing of poorly draining soils and soil compaction due to grazing on freely draining soils) resulted in subtle MTT variations in soil water in the upper profile. Overall, the isotope dynamics and inferred MTTs suggest that the evolution of stream water ages in such a complex human-influenced environment are largely related to near-surface soil processes and the dominant soil management practices. This has direct implications for understanding and managing flood risk and contaminant transport in such environments.     

Environmental prognostics: an integrated model supporting lysosomal stress responses as predictive biomarkers of animal health status

The potential prognostic use of lysosomal reactions to environmental pollutants is explored in relation to predicting animal health in marine mussels, based on diagnostic biomarker data. Cellular lysosomes are already known to accumulate many metals and organic xenobiotics and the lysosomal accumulation of the carcinogenic polycyclic aromatic hydrocarbon 3-methylcholanthrene (3-MC) is demonstrated here in the hepatopancreatic digestive cells and ovarian oocytes of the blue mussel. Lysosomal membrane integrity or stability appears to be a generic indicator of cellular well-being in eukaryotes; and in bivalve molluscs it is correlated with total oxygen and nitrogen radical scavenging capacity (TOSC), protein synthesis, scope for growth and larval viability; and inversely correlated with DNA damage (micronuclei), as well as lysosomal swelling (volume density), lipidosis and lipofuscinosis, which are all characteristic of failed or incomplete autophagy. Integration of multiple biomarker data is achieved using multivariate statistics and then mapped onto "health status space" by using lysosomal membrane stability as a measure of cellular well-being. This is viewed as a crucial step towards the derivation of explanatory frameworks for prediction of pollutant impact on animal health; and has facilitated the development of a conceptual mechanistic model linking lysosomal damage and autophagic dysfunction with injury to cells, tissues and the whole animal. This model has also complemented the creation and use of a cell-based bioenergetic computational model of molluscan hepatopancreatic cells that simulates lysosomal and cellular reactions to pollutants. More speculatively, the use of coupled empirical measurements of biomarker reactions and modelling is proposed as a practical approach to the development of an operational toolbox for predicting the health of the environment.     

Basaltic fragments in lunar feldspathic meteorites: Connecting sample analyses to orbital remote sensing

Abstract– The feldspathic lunar meteorites contain rare fragments of crystalline basalts. We analyzed 16 basalt fragments from four feldspathic lunar meteorites (Allan Hills [ALHA] 81005, MacAlpine Hills [MAC] 88104/88105, Queen Alexandra Range [QUE] 93069, Miller Range [MIL] 07006) and utilized literature data for another (Dhofar [Dho] 1180). We compositionally classify basalt fragments according to their magma’s estimated TiO₂ contents, which we derive for crystalline basalts from pyroxene TiO₂ and the mineral‐melt Ti distribution coefficient. Overall, most of the basalt fragments are low‐Ti basalts (1–6% TiO₂), with a significant proportion of very‐low‐Ti basalts (<1% TiO₂). Only a few basalt clasts were high‐Ti or intermediate Ti types (>10% TiO₂ and 6–10% TiO₂, respectively). This distribution of basalt TiO₂ abundances is nearly identical to that obtained from orbital remote sensing of the moon (both UV‐Vis from Clementine, and gamma ray from Lunar Prospector). However, the distribution of TiO₂ abundances is unlike those of the Apollo and Luna returned samples: we observe a paucity of high‐Ti basalts. The compositional types of basalt differs from meteorite to meteorite, which implies that all basalt subtypes are not randomly distributed on the Moon, i.e., the basalt fragments in each meteorite probably represent basalts in the neighborhood of the meteorite launch site. These differences in basalt chemistry and classifications may be useful in identifying the source regions of some feldspathic meteorites. Some of the basalt fragments probably originate from ancient cryptomaria, and so may hold clues to the petrogenesis of the Moon’s oldest volcanism.     

Spatial and temporal structure of a high-latitude transient ULF pulsation

Auroral radar observations of transient ULF pulsations with latitudinally varying period have recently been reported. An event of this type is analysed using data from the Scandinavian Magnetometer Array, the STARE radar, and the GEOS-2 satellite. The magnetometers show long-period (～450 s) oscillations consistent with the pulsations observed in the ionosphere using STARE, and confirm that the geomagnetic field shells are resonating in the toroidal mode. There is also a localised, small-amplitude component with 250-s period South of the STARE pulsations. Electric field measurements at GEOS-2 show only an impulsively stimulated pulsation of 250-s period. The wave fields at GEOS-2 imply that the satellite was earthward of a localised toroidal standing-wave resonance, which mapped to the ionosphere at least one degree South of the expected position. A radial profile of equatorial plasma mass density is inferred from the GEOS-2 and STARE results. This shows a radially increasing density near GEOS-2, and a radially decreasing density outside the satellite position.An interpretation of the event is given in which a tailward propagating hydromagnetic impulse directly stimulates field shells outside 7 R_E to oscillate at their eigenperiods. In the region of increasing density near GEOS-2, a relatively highly-damped surface wave is excited. This feeds energy rapidly into a narrow monochromatic toroidal field-line resonance, which subsequently decays more slowly through ionospheric dissipation.     

The nature of publishing and assessment in Geography and Environmental Studies: evidence from the Research Assessment Exercise 2008

We present a summary of the kinds of outputs submitted to the Geography and Environmental Studies sub-panel (H-32) for the 2008 Research Assessment Exercise (RAE), and examine the relationships between the peer assessment of research quality that the RAE process has typified, and alternative modes of assessment based on bibliometrics. This comparison is effected using (in aggregate form) some of the results from the RAE, together with citation data gathered after completion of the RAE assessment, specifically for the purpose of this paper. We conclude that, if it continues to be necessary and desirable to assess, in some measure and however imprecisely, research quality, then peer assessment cannot be replaced by bibliometrics. Bibliometrics permit measurement of something that may be linked to quality but is essentially a different phenomenon – a measure of 'impact', for example.     

Water Quality Co-Effects of Greenhouse Gas Mitigation in U.S. Agriculture

This study develops first-order estimates of water quality co-effects of terrestrial greenhouse gas (GHG) emission offset strategies in U.S. agriculture by linking a national level agricultural sector model (ASMGHG) to a national level water quality model (NWPCAM). The simulated policy scenario considers GHG mitigation incentive payments of $25 and $50 per tonne, carbon equivalent to landowners for reducing emissions or enhancing the sequestration of GHG through agricultural and land-use practices. ASMGHG projects that these GHG price incentives could induce widespread conversion of agricultural to forested lands, along with alteration of tillage practices, crop mix on land remaining in agriculture, and livestock management. This study focuses on changes in cropland use and management. The results indicate that through agricultural cropland about 60 to 70 million tonnes of carbon equivalent (MMTCE) emissions can be mitigated annually in the U.S. These responses also lead to a 2% increase in aggregate national water quality, with substantial variation across regions. Such GHG mitigation activities are found to reduce annual nitrogen loadings into the Gulf of Mexico by up to one half of the reduction goals established by the national Watershed Nutrient Task Force for addressing the hypoxia problem.     

Mixing of magmas from enriched and depleted mantle sources in the northeast Pacific: West Valley segment,Juan de Fuca Ridge

The 50 km-long West Valley segment of the northern Juan de Fuca Ridge is a young, extension-dominated spreading centre, with volcanic activity concentrated in its southern half. A suite of basalts dredged from the West Valley floor, the adjacent Heck Seamount chain, and a small near-axis cone here named Southwest Seamount, includes a spectrum of geochemical compositions ranging from highly depleted normal (N-) MORB to enriched (E-) MORB. Heck Seamount lavas have chondrite-normalized La/Sm_cn0.3, ⁸⁷Sr/⁸⁶Sr=0.70235–0.70242, and ²⁰⁶Pb/²⁰⁴Pb=18.22–18.44, requiring a source which is highly depleted in trace elements both at the time of melt generation and over geologic time. The E-MORB from Southwest Seamount have La/Sm_cn1.8, ⁸⁷Sr/⁸⁶Sr=0.70245–0.70260, and ²⁰⁶Pb/²⁰⁴Pb=18.73–19.15, indicating a more enriched source. Basalts from the West Valley floor have chemical compositions intermediate between these two end-members. As a group, West Valley basalts from a two-component mixing array in element-element and element-isotope plots which is best explained by magma mixing. Evidence for crustal-level magma mixing in some basalts includes mineral-melt chemical and isotopic disequilibrium, but mixing of melts at depth (within the mantle) may also occur. The mantle beneath the northern Juan de Fuca Ridge is modelled as a plum-pudding, with plums of enriched, amphibole-bearing peridotite floating in a depleted matrix (DM). Low degrees of melting preferentially melt the plums, initially removing only the amphibole component and producing alkaline to transitional E-MORB. Higher degrees of melting tap both the plums and the depleted matrix to yield N-MORB. The subtly different isotopic compositions of the E-MORBs compared to the N-MORBs require that any enriched component in the upper mantle was derived from a depleted source. If the enriched component crystallized from fluids with a DM source, the plums could evolve to their more evolved isotopic composition after a period of 1.5–2.0 Ga. Alternatively, the enriched component could have formed recently from fluids with a less-depleted source than DM, such as subducted oceanic crust. A third possibility is that enriched material might be dispersed as plums throughout the upper mantle, transported from depth by mantle plumes.