A sample of 6C radio sources designed to find objects at redshift z > 4 — I. The radio data

We describe the selection of a sample of 34 radio sources from the 6C survey from a region of sky covering 0.133 sr. The selection criteria for this sample, hereafter called 6C*, were chosen to optimize the chances of finding radio galaxies at redshift z  > 4. Optical follow-up observations have already led to the discovery of the most distant known radio galaxy at z  = 4.41. We present VLA radio maps and derive radio spectra for all the 6C* objects.     

Kinetics of the reactions of hydroxyl radicals with alkyl nitrates and with some oxygen-containing organic compounds studied under simulated atmospheric conditions

Rate constants have been measured for the reactions of hydroxyl radicals with alkyl nitrates and with some oxygen-containing organic compounds by a competitive technique. Mixtures of synthetic air containing a few ppm of nitrous acid, ethylene and the organic substrate were photolysed in a Teflon bag smog chamber. Based on the value k _HO+C2H₄}=8.1×10^-12 cm³ molecule^-1 s^-1 the following rate constants were obtained for the hydroxyl radical reactions at 750 Torr and at 303 K in units of 10^-12 cm³ molecule^-1: CH₃ONO₂, 0.37±0.09; C₂H₅ONO₂, 0.48±0.20; n-C₃H₇ONO₂, 0.70±0.22; C₂H₅OH, 3.6±0.4; CH₃COCH₃, 0.26±0.08; CH₃CO₂ i-C₃H₇, 3.0±0.8; CH₃CO₂ n-C₃H₇, 2.4±0.2. The results are discussed in relation to the available literature data and the implications of the results are considered in terms of the smog reactivity of these molecules.     

Geological setting and tectonic subdivision of the Neoproterozoic orogenic belt of Tuludimtu, western Ethiopia

The N–S trending Tuludimtu Belt in the extreme west of Ethiopia has been subdivided into five lithotectonic domains, from east to west, the Didesa, Kemashi, Dengi, Sirkole and Daka domains. The Kemashi, Dengi and Sirkole Domains, forming the core of the belt, contain volcano-sedimentary successions, whilst the Didesa and Daka Domains are gneiss terranes, interpreted to represent the eastern and western forelands of the Tuludimtu Belt. The Kemashi Domain, which consists of an ophiolitic sequence of ultramafic and mafic volcanic and plutonic rocks together with sedimentary rocks of oceanic affinity, is interpreted as oceanic crust and is considered to represent an arc-continent suture zone. The Dengi Domain, composed of mafic to felsic volcanic and plutonic rocks, and a sequence of volcanoclastic, volcanogenic, and carbonate sediments, is interpreted as a volcanic arc. The Sirkole Domain consists of alternating gneiss and volcano-sedimentary sequences, interpreted as an imbricated basement-cover thrust-nappe complex. All the domains are intruded by syn- and post-kinematic Neoproterozoic granitoids. Structural analysis within the Didesa and Daka Domains indicate the presence of pre-Pan African structures, upon which Neoproterozoic deformation has been superimposed. The gneissic rocks of these two domains are regarded as pre-Pan African continental fragments amalgamated to West Gondwana during Neoproterozoic collision events. Unconformably overlying all of the above are a series of tilted but internally undeformed conglomerate–sandstone–shale sequences, regarded as post-accretionary molasse-type deposits, formed during gravitational collapse of the Tuludimtu Belt. The Tuludimtu Belt is interpreted as a collision orogenic belt formed during the assembly of West Gondwana prior to final closure of the Mozambique Ocean.     

Vitellogenin in the blood plasma of male cod (Gadus morhua): a sign of oestrogenic endocrine disruption in the open sea?

An ELISA for cod vitellogenin (VTG) has been set up using cod lipovitellin for plate coating and standardisation. The assay has been applied to plasma samples collected from male and female cod caught in three distinct areas around the UK, three areas off the Norwegian coast and also to cod reared initially at an aquaculture site and subsequently maintained at a research station. The aim of the study was to determine whether there were any signs of oestrogenic endocrine disruption in a fish species living offshore. VTG induction was found in male cod caught in the North Sea, the Shetland Box area, in Oslofjord and also in cultivated fish. There was a strong relationship between concentrations of VTG and fish size. There was no evidence that the presence of VTG in the plasma of males is a natural part of their life cycle. On the other hand, the size of fish at which these elevated VTG concentrations appear (ca. 5 kg) is about the size that cod change from feeding primarily on benthic invertebrates to mainly other fish, both benthic and pelagic. The possibility is suggested that large cod pick up oestrogenic endocrine disrupters through the food chain.     

Risks of airborne pollution accidents in a major conurbation: case study of Zhangjiakou,a host city for the 2022 Winter Olympics

The number of airborne pollution accidents is second only to that of water-borne pollution accidents, in recorded environmental disasters. Acute casualties and public health costs have prompted many airborne pollution risk analyses. To date, few assessment methods have been carried out at regional-scale to quantify acute airborne pollution risk. Herein, a Hybrid Simulation and Risk Analysis approach, involving a systematic combination of simulation, risk ranking, and standardized analysis, is proposed at regional scale. Gaussian and heavy-gas models are utilized in the simulation process, and acute exposure limits preferentially adopted in the risk analysis. The case study shows that 34 of 243 townships in Zhangjiakou City of north China, one of the twin cities selected to host the 2022 Winter Olympics, are threatened by airborne risk sources. It is found that the accidental air pollution risk is comparatively higher in the Xuanhua and Wanquan conurbations. High-risk chemical enterprises (312–432 risk scores) are mostly located near urban areas with high population density where many people are vulnerable receptors to potential air pollution accidents. The resulting risk map indicates that acute airborne pollution from Zhangjiakou would not be a threat either to the proposed Olympic site at Chongli or to downwind Beijing.     

Askival: An altered feldspathic cumulate sample in Gale crater

Askival is a light-toned, coarsely crystalline float rock, which was identified near the base of Vera Rubin Ridge in Gale crater. We have studied Askival, principally with the ChemCam instrument but also using APXS compositional data and MAHLI images. Askival and an earlier identified sample, Bindi, represent two rare examples of feldspathic cumulate float rocks in Gale crater with >65% relict plagioclase. Bindi appears unaltered whereas Askival shows textural and compositional signatures of silicification, along with alkali remobilization and hydration. Askival likely experienced multiple stages of alteration, occurring first through acidic hydrolysis of metal cations, followed by deposition of silica and possible phyllosilicates at low T and neutral-alkaline pH. Through laser-induced breakdown spectroscopy compositional analyses and normative calculations, we suggest that an assemblage of Fe-Mg silicates including amphibole and pyroxene, Fe phases, and possibly Mg-rich phyllosilicate are present. Thermodynamic modeling of the more pristine Bindi composition predicts that amphibole and feldspar are stable within an upper crustal setting. This is consistent with the presence of amphibole in the parent igneous rocks of Askival and suggests that the paucity of amphiboles in other known Martian samples reflects the lack of representative samples of the Martian crust rather than their absence on Mars.     

The economic cost and control of marine debris damage in the Asia-Pacific region

Oceans in the Asia-Pacific region are being impacted by increasing levels of marine debris, with many governments unaware of the extent that marine debris damages marine industries, the economy and the marine environment. We examine the economic costs associated with marine debris and present a simple marine debris cycle model to discuss the costs and benefits of prevention, clean-up and the benefits of using biodegradable materials. For the 21 economies of the Asia- Pacific rim we estimate that marine debris-related damage to marine industries costs US$1.26bn per annum in 2008 terms. Marine debris imposes an avoidable cost that can be reduced through policy implementation to economically optimal levels. Options to control debris, using regulations, technical intervention and market based instruments, may have a role. In this pollution policy area, additional economic cost data are required to inform governments on the most economical ways to control levels of marine debris.