Double carbonate breakdown reactions at high pressures: an experimental study in the system CaO–MgO–FeO–MnO–CO2

The pressure–temperature conditions of the reactions of the double carbonates CaM(CO₃)₂, where M = Mg (dolomite), Fe (ankerite) and Mn (kutnohorite), to MCO₃ plus CaCO₃ (aragonite) have been investigated at 5–8 GPa, 600–1,100°C, using multi-anvil apparatus. The reaction dolomite = magnesite + aragonite is in good agreement with the results of Sato and Katsura (Earth Planet Sci 184:529–534, 2001), but in poor agreement with the results of Luth (Contrib Mineral Petrol 141:222–232, 2001). The dolomite is partially disordered at 620°C, and fully disordered at 1,100°C. All ankerite and kutnohorite samples, including the synthetic starting materials, are disordered. The P–T slopes of the three reactions increase in the order M = Mg, Fe, Mn. The shallower slope for the reaction involving magnesite is due partly to its having a higher compressibility than expected from unit-cell volume considerations. At low pressures there is a preference for partitioning into the double carbonate of Mg > Fe > Mn. At high pressures the partitioning preference is reversed. Using the measured reaction positions, the P–T conditions at which dolomite solid solutions will break down on increasing P and T in subduction zones can be estimated.     

Triggering transformative change: a development path approach to climate change response in communities

While climate change action plans are becoming more common, it is still unclear whether communities have the capacity, tools, and targets in place to trigger the transformative levels of change required to build fundamentally low-carbon, resilient, healthy communities. Evidence increasingly supports the finding that this transformation is not triggered by climate policy alone, but rather is shaped by a broad array of decisions and practices that are rooted in underlying patterns of development. Even so, these findings have rarely penetrated the domain of practice, which often remains squarely focused on a relatively narrow set of climate-specific policies. This article builds a conceptual framework for understanding the dynamics of community-level development path transformations that may both dramatically reduce GHG emissions and significantly enhance community resilience. This framework illuminates eight critical enablers of innovation on climate change, each of which is illustrated by compelling examples of community-level experimentation on climate change across the province of British Columbia, Canada. It is concluded that community-based climate (or sustainability) policy might be more likely to trigger development path shifts if it employs a longer time horizon, recognition of adaptability and feedbacks, integrated decision making, and systems thinking.     

How Waterlogged Microsites Help an Annual Plant Persist Among Salt Marsh Perennials

Annual plants that coexist among perennial dominants might persist in microsites that are stressful to their competitors. In Californian salt marshes, where cover of annual and perennial Salicornia species are negatively correlated, we hypothesized that waterlogged depressions support the annual (Salicornia bigelovii) but not the region’s dominant perennial (Salicornia virginica). In a large restoration site, S. virginica cover was low in naturally formed pools, and our 10-cm depressions decreased its cover by approximately 30% compared to the controls. S. bigelovii grew taller and produced more flowers in waterlogged sites with low soil redox potential, and it completed its life cycle in the 5-cm-deep depressions that we created. Experimentally reducing S. virginica canopy cover in shallow depressions also increased the survival of the annual. In the greenhouse, rhizosphere oxidation was indicated as a mechanism for tolerating waterlogging, as S. bigelovii elevated the soil redox potential by 50 mV more than S. virginica did. Also, in the greenhouse, S. bigelovii seedlings actually suppressed the growth of S. virginica seedlings under increased flooding. We conclude that waterlogged microsites help sustain S. bigelovii in Californian salt marshes and that this increasingly rare plant could be managed by adding shallow depressions to restoration sites.     

Diversity and burglary: Do community differences matter?

Diversity within a population has been linked to levels of both social cohesion and crime. Neighborhood crimes are the result of a complex set of factors, one of which is weak community cohesion. This article seeks to explore the impacts of diversity on burglary crime in a range of neighborhoods, using Leeds, UK as a case study. We propose a new approach to quantifying the correlates of burglary in urban areas through the use of diversity metrics. This approach is useful in unveiling the relationship between burglary and diversity in urban communities. Specifically, we employ stepwise multiple regression models to quantify the relationships between a number of neighborhood diversity variables and burglary crime rates. The results of the analyses show that the variables that represent diversity were more significant when regressed against burglary crime rates than standard socio‐demographic data traditionally used in crime studies, which do not generally use diversity variables. The findings of this study highlight the importance of neighborhood cohesion in the crime system, and the key place for diversity statistics in quantifying the relationships between neighborhood diversities and burglary. The study highlights the importance of policy planning aimed at encouraging community building in promoting neighborhood safety.     

Spin vectors in the Koronis family: II. Additional clustered spins, and one stray

We recorded 101 new rotation lightcurves of five Koronis family members, and then combined the new observations with previous data to determine the objects' sidereal rotation periods, spin vector orientations, and model shape solutions. The observing program was tailored specifically for spin vector analyses by determining single-apparition Lumme–Bowell solar phase coefficients, and by measuring synodic rotation periods precisely enough to unambiguously count the rotations between two consecutive oppositions, which is a prerequisite for identifying the correct sidereal period. The new data make possible first pole and shape determinations for (263) Dresda, (462) Eriphyla, and (1289) Kutaïssi, and they improve the models for (277) Elvira and (534) Nassovia, two objects previously studied by Slivan et al. [Slivan, S.M., Binzel, R.P., Crespo da Silva, L.D., Kaasalainen, M., Lyndaker, M.M., Kr?o, M., 2003. Icarus 162, 285–307]. Our results increase the number of Koronis family spin vectors reported in the literature to fourteen, a sample which now includes the seven largest family members. The spin properties of Eriphyla (rotation period , spin vector obliquity ε=51°) and Kutaïssi (P=3.62 h, ε=165°) are consistent with the markedly nonrandom distribution reported by Slivan [Slivan, S.M., 2002. Nature 419, 49–51], and explained by Vokrouhlický et al. [Vokrouhlický, D., Nesvorný, D., Bottke, W.F., 2003. Nature 425, 147–151] as the result of the effects of thermal “YORP” torques combined with solar and planetary gravitational torques. Dresda (P=16.81 h, ε=16°) is the first prograde Koronis member whose spin obliquity and spin rate significantly differ from the clustered spin properties previously found for other prograde Koronis members; nevertheless, its spin vector is consistent with several of the spin evolution possibilities that were identified in the YORP modeling.     

Fecundity and spawning of the Atlantic horseshoe crab, Limulus polyphemus, in Pleasant Bay, Cape Cod, Massachusetts, USA

This study provided the first comprehensive analysis of Atlantic horseshoe crab (Limulus polyphemus) fecundity. Limulus appear to be a determinate spawner, maturing all eggs for the breeding season before spawning begins. On average, larger females held a larger number of eggs (63,500) than smaller females (14,500). By the end of the breeding season there was an average of 11,600 mature eggs per female left undeposited, regardless of female size. Larger females laid a higher percentage of the eggs they contained. Thus they not only contain more eggs, but are more effective at laying them as well. Size of spawning females ranged from about 185–300 mm prosomal width, with by far the highest concentration in the mid‐size ranges. Although on an individual basis large females carry and lay the greatest number of eggs, mid‐size crabs as a group contributed more to the horseshoe crab population in Pleasant Bay because they were more plentiful (net fecundity was highest for mid‐size crabs). These results have implications for the management of this important species, which is harvested for bait, scientific, and biomedical uses. Incorporation of these results into models and other management tools can help predict growth rates, effects of size‐selective harvest, reproductive value, and stable stage distribution of populations.     

Past,present and future nutrient loads of the North Sea: Causes and consequences

Comprehensive, aggregate nutrient budgets were established for two compartments of the North Sea, the shallow coastal and deeper open regions, and for three different periods, representing pre-eutrophication (∼1950), eutrophication (∼1990) and contemporary (∼2000) phases. The aim was to quantify the major budget components, to identify their sources of variability, to specify the anthropogenic components, and to draw implications for past and future policy. For all three periods, open North Sea budgets were dominated (75%) by fluxes from and to the North-East Atlantic; sediment exchange was of secondary importance (18%). For the coastal North Sea, fluxes during the eutrophication period were dominated by sediment exchange (49% of all inputs), followed by exchange with the open sea (21%), and anthropogenic inputs (19%). Between 1950 and 1990, N-loading of coastal waters increased by a factor of 1.62 and P-loading by 1.45. These loads declined after 1990. Interannual variability in Atlantic inflow was found to correspond to a variability of 11% in nutrient load to the open North Sea. Area-specific external loads of both the open and coastal North Sea were below Vollenweider-type critical loads when expressed relative to depth and flushing. External area-specific load of the coastal North Sea has declined since 1990 from 1.8 to about 1.4 g P m⁻² y⁻¹ in 2000, which is close to the estimate of 1.3 for 1950. N-load declined less, leading to an increase in N/P ratio.     

Deep pooling of low degree melts and volatile fluxes at the 85°E segment of the Gakkel Ridge: Evidence from olivine-hosted melt inclusions and glasses

We present new analyses of volatile, major, and trace elements for a suite of glasses and melt inclusions from the 85°E segment of the ultra-slow spreading Gakkel Ridge. Samples from this segment include limu o pele and glass shards, proposed to result from CO₂-driven explosive activity. The major element and volatile compositions of the melt inclusions are more variable and consistently more primitive than the glass data. CO₂ contents in the melt inclusions extend to higher values (167–1596 ppm) than in the co-existing glasses (187–227 ppm), indicating that the melt inclusions were trapped at greater depths. These melt inclusions record the highest CO₂ melt concentrations observed for a ridge environment. Based on a vapor saturation model, we estimate that the melt inclusions were trapped between seafloor depths (～ 4 km) and ～ 9 km below the seafloor. However, the glasses are all in equilibrium with their eruption depths, which is inconsistent with the rapid magma ascent rates expected for explosive activity. Melting conditions inferred from thermobarometry suggest relatively deep (25–40 km) and cold (1240°–1325 °C) melting conditions, consistent with a thermal structure calculated for the Gakkel Ridge. The water contents and trace element compositions of the melt inclusions and glasses are remarkably homogeneous; this is an unexpected result for ultra-slow spreading ridges, where magma mixing is generally thought to be less efficient based on the assumption that steady-state crustal magma chambers are absent in these environments. All melts can be described by a single liquid line of descent originating from a pooled melt composition that is consistent with the aggregate melt calculated from a geodynamic model for the Gakkel Ridge. These data suggest a model in which deep, low degree melts are efficiently pooled in the upper mantle (9–20 km depth), after which crystallization commences and continues during ascent and eruption. Based on our melting model and the assumption that CO₂ is perfectly incompatible, we show that the highest CO₂ concentrations of the melt inclusions (～ 1600 ppm) are consistent with the calculated CO₂ concentrations of primary undegassed melts. The highest measured CO₂/Nb ratio (443) of Gakkel Ridge melt inclusions predicts a mantle CO₂ content of 134 ppm and would result in a global ridge flux of 2.0 × 10¹² mol CO₂/yr.     

High resolution X-ray computed tomography studies of Grasberg porphyry Cu-Au ores,Papua, Indonesia

High-resolution X-ray computed tomography (HRXCT) provides unique information of the geological and metallurgical significance for gold and related ore minerals in the supergiant Grasberg porphyry Cu–Au deposit. Digital radiographs have proved to be an effective means of screening samples for the presence of gold for HRXCT studies. Digital radiograph effectiveness is limited by the thickness of samples (typically to ≤2 cm), as well as the associated minerals. Thus, preselecting samples for gold studies using HRXCT is most effective using digital radiographs combined with assay information. Differentiating between metallic mineral grains with relatively small differences in density, e.g., bornite (5.1 g/cm³) from chalcopyrite (4.2 g/cm³), is relatively straightforward for isolated monominerallic grains or composites in a similar lower-density matrix, but difficulties are encountered with the interpretation of typical intergrown ore minerals. X-ray beam-hardening artifacts lead to inconsistency in attenuation determination, both within and among slice images, complicating quantitative processing. However, differentiation of chalcopyrite and bornite has been successful in smaller-diameter (≤22-mm) cores of Grasberg ores. Small-diameter (≤10 mm) cores of the Grasberg stockwork Cu–Au ore were analyzed using HRXCT methods scanned at the minimum spacing currently available (7.5 μm), and data reduction protocols using the Blob3D program were modified to improve the quantification of grain sizes and shapes. Grains as small as 6.5 μm have been identified. All of these grains are in direct contact with chalcopyrite, providing support for gold distribution in porphyry copper systems being a result of exsolution from copper sulfides. HRXCT scanning (±digital radiography) precisely defines the in situ location of mineral grains of interest within a sample, which then can be studied in conventional petrographic sections, and other types of analytical studies conducted, e.g., gold trace element geochemistry.