Peculiarities of slick formation on the sea surface

This paper deals with surface slicks, their nature, and causes of formation in context of the development of remote detection methods and investigation of dynamic processes in the ocean and at the air–ocean interface. A simplified formalism is introduced for slick–sea surface contrast formation which takes into account the upward sea radiation and qualitatively explains in situ measurement results. The results of a detection of slicks on the coastal water surface are also described, which, together with the simplified formalism suggested, provide optimal experimental conditions for slick–sea surface contrast measurements; i.e., the contrast of the P component of reflected radiation is measured at viewing angles close to the horizon.     

Temporal Variability of Total Ozone in the Asian Region Inferred from Ground-Based and Satellite Measurement Data

This paper reports investigation data on the temporal variability of total ozone content (TOC) in the Central Asian and Tibet Plateau mountain regions obtained by conventional methods, as well as by spectral, cross-wavelet, and composite analyses. The data of ground-based observation stations located at Huang He, Kunming, and Lake Issyk-Kul, along with the satellite data obtained at SBUV/SBUV2 (SBUV merged total and profile ozone data, Version 8.6) for 1980–2013 and OMI (Ozone Monitoring Instrument) and TOU (Total Ozone Unit) for 2009–2013 have been used. The average relative deviation from the SBUV/SBUV2 data is less than 1% in Kunming and Issyk-Kul for the period of 1980–2013, while the Huang He Station is characterized by an excess of the satellite data over the ground-based information at an average deviation of 2%. According to the Fourier analysis results, the distribution of amplitudes and the periods of TOC oscillations within a range of over 14 months is similar for all series analyzed. Meanwhile, according to the cross-wavelet and composite analyses results, the phase relationships between the series may considerably differ, especially in the periods of 5–7 years. The phase of quasi-decennial oscillations in the Kunming Station is close to the 11-year oscillations of the solar cycle, while in the Huang He and Issyk-Kul stations the TOC variations go ahead of the solar cycle.     

Features of wind waves at the southeastern coast of Sakhalin according to bottom-pressure measurements

The results of wind-wave measurements with bottom-pressure sensors are discussed. These measurements were performed at the southeastern coast of the Island of Sakhalin in 2006–2009. The problems of converting data obtained with these sensors into water-level displacent in the context of the linear theory are noted. Twenty records with a duration of 2 weeks to 3 months were obtained. These records contain from 150000 to 1200000 waves for three different observation points located at the southeastern coast of Sakhalin in the regions of the village of Vzmor’ye, Lake Izmenchivoye, and the Cape of Ostryi. The estimates obtained for wave-height distributions were approximated by the Weibull distribution. They were compared to the theoretical Rayleigh, Forristall, Weibull, and Glukhovskii distributions. As one would expect, in the region of small wave heights, all distributions prove to be close to one another, and, for large wave heights, the Weibull distribution is preferred.     

Ecohydrographic constraints on biodiversity and distribution of phytoplankton and zooplankton in coral reefs of the Red Sea,Saudi Arabia

An integral concept of ecological research is the constraint of biodiversity along latitudinal and environmental gradients. The Red Sea features a natural example of a latitudinal gradient of salinity, temperature and nutrient richness. Coral reefs along the Red Sea coasts are supported with allochthonous resources such as oceanic and neritic phytoplankton and zooplankton; however, relatively little is known about how the ecohydrography correlates with plankton biodiversity and abundance. In this article we present the biodiversity of phytoplankton and zooplankton in Red Sea coral reefs. Oceanographic data (temperature, salinity), water samples for nutrient analysis, particulate organic matter, phytoplankton and zooplankton, the latter with special reference to Copepoda (Crustacea), were collected at nine coral reefs over ~1500 km distance along the Red Sea coast of Saudi Arabia. The trophic state of ambient waters [as indicated by chlorophyll a (Chl a)] changed from strong oligotrophy in the north to mesotrophy in the south and was associated with increasing biomasses of Bacillariophyceae, picoeukaryotes and Synechococcus as indicated by pigment fingerprinting (CHEMTAX) and flow cytometry. Net‐phytoplankton microscopy revealed a Trichodesmium erythraeum (Cyanobacteria) bloom north of the Farasan Islands. Several potentially harmful algae, including Dinophysis miles and Gonyaulax spinifera (Dinophyceae), were encountered in larger numbers in the vicinity of the aquaculture facilities at Al Lith. Changes in zooplankton abundance were mainly correlated to the phytoplankton biomass following the latitudinal gradient. The largest zooplankton abundance was observed at the Farasan Archipelago, despite high abundances of copepodites, veligers (Gastropoda larvae) and Chaetognatha at Al Lith. Although the community composition changed over latitude, biodiversity indices of phytoplankton and zooplankton did not exhibit a systematic pattern. As this study constitutes the first current account of the plankton biodiversity in Red Sea coral reefs at a large spatial scale, the results will be informative for ecosystem‐based management along the coastline of Saudi Arabia.     

Comparison of Near Coastal Significant Wave Height Measurements from SARAL/AltiKa with Wave Rider Buoys in the Indian Region

Significant Wave Height (SWH) measurement data from the AltiKa Radar Altimeter (RA) for the first 13 cycles of satellite coverage are compared with the SWH from Wave Rider Buoys (WRB) located at nine stations along the Indian coast to assess the performance of the altimeter over the coastal region. AltiKa SWH observations within a 30-minute interval and 50 km distance from WRBs are found to be over estimated by 6%, the Root Mean Square Error (RMSE) is 0.36 m, the Scatter Index (SI) is 26%, and the correlation coefficient (r) is 0.91. Relaxing the distance criteria by 50 km leads to increase in RMSE and deterioration of r to 0.89. There is a marked difference in the statistics on the comparison pairs pooled separately for the buoys near west and east coasts, with the latter showing RMSE error 26% more than the former. The method of Cressman weights adopted to correct for the errors arising out of the temporal and spatial differences in altimeter and buoy data comparison pairs resulted in reduction of RMSE by 5% and 25%, respectively, for the 30-minute and 50 km criteria and 4% and 56% for the 30-minute and 100 km criteria.     

Modeling of oil spreading in a problem of radar multiangle diagnostics of Sea surface pollutions

The possibilities of a multiangle method of radar diagnostics to determine thickness of an oil film on a sea surface by comparing the radar data with the quantitative modeling results obtained using the model of oil spreading dynamics are analyzed. The experimental results of the remote sensing of the Caspian Sea water area near the Neftyanye Kamni oil field by the Envisat-1 synthetic aperture radar (SAR) and the new Floating Objects Tracking System (FOTS) model of oil spreading are used for the analysis. The model allows to calculate the dynamics and change in the mass and size of an oil slick basing only on the available data of satellite measurements and atmospheric reanalysis.The model takes into account the main processes that influence the slick formation (gravity spreading, advective transport, dispersion, emulsification, turbulent mixing, and evaporation). This model is used to calculate the thickness evolution and dynamics of the displacement of oil slicks in the period between two consecutive radar images of this region (0.5–4 days) and to estimate the volumes of oil spilled in the field. The good consistence of the height of the oil film calculated using radar measurements and the modeling results confirms the method’s reliability.     

Observations of a cycle of intense coastal upwelling and downwelling at the research site of the Shirshov Institute of Oceanology in the Black Sea

The paper presents the results of joint analysis of the response of vertical temperature and current velocity profile distributions in the coastal zone of the Gelendzhik region of the Black Sea to strong wind forcing in the third ten-day period of September 2013. This forcing was caused by the propagation of an atmospheric cyclone, which first initiated coastal upwelling that was later replaced by downwelling. We formulate a criterion for the development of full coastal upwelling and demonstrate its efficiency. We assume that frequent events of incomplete coastal upwelling and downwelling are associated with changes in the water dynamics (variations in the intensity and direction of the alongshore current) generally not related to local wind forcing.     

Remote Sensing Observations of Ocean Surface Chlorophyll and Temperature with the Impact of Cyclones and Depressions over the Bay of Bengal Water

MODIS-Aqua derived eight-day composite chlorophyll concentration data analyzed to study the impact of cyclones and depressions on the Bay of Bengal productivity. A total of 15 cyclonic storms and depressions picked up from the India Meteorological Department datasets. MODIS-Aqua data analyzed during October 2002 to December 2009. There was observation of depressions (D), deep depressions (DD), cyclonic storms (CS), severe cyclonic storms (SCS), and very severe cyclonic storms (VSCS) with categories of intensities (“T” numbers 1.5–6) and wind speeds (25–108 knots). The chlorophyll concentration observed to be high (1.0–5.0 mg/m³) with the impact in the coastal and offshore waters. Quickscat scatterometer data showed high wind speed (about 10 meters/second). Sea surface temperature (SST) observed to be decreased (roughly 2°C) with effect of cyclones. The cyclone numbers, intensity, and chlorophyll concentration has been observed to be increasing from 2002 to 2009, with observation of VSCS “Sidr” during 2007. The study would be interesting to link carbon flux/sequestration, marine food chain, and harnessing fishery resources in a postcyclone period.     

Assessment of Pollution of the Kerch Strait and Adjacent Black Sea Area Based on Field Measurements of 2019–2020

Oceanology - The paper presents the results of an analysis of the main pollutants (heavy metals, pesticides, detergents, hydrocarbons) in water, suspended particulate matter, and bottom sediments,...     

Methoxy formation in the reaction of CH3O2 radicals with NO

Formation of methoxy (CH₃O) radicals in the reaction (1) CH₃O₂+NOCH₃O+NO₂ at 298 K has been observed directly using time resolved LIF. The branching ratio % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaeqOXdyMaae% 4qaiaabIeadaWgaaWcbaGaae4maaqabaGccaqGpbGaaeiiaiaabIca% ieqacaWF9aGaa8hiaiaa-nbicaWFGaGaeuiLdqKaai4waiaaboeaca% qGibWaaSbaaSqaaiaabodaaeqaaOGaae4taiaac2facaWFVaGaeuiL% dqKaai4waiaaboeacaqGibWaaSbaaSqaaiaabodaaeqaaOGaae4tam% aaBaaaleaacaqGYaaabeaakiaac2facaqGPaaaaa!4E31!\[\phi {\rm{CH}}_{\rm{3}} {\rm{O (}} = -- \Delta [{\rm{CH}}_{\rm{3}} {\rm{O}}]/\Delta [{\rm{CH}}_{\rm{3}} {\rm{O}}_{\rm{2}} ]{\rm{)}}\] has been determined by quantitative cw-UV-laser absorption at 257 nm of CH₃O₂ and CH₃ONO, the product of the consecutive methoxy trapping reaction (2) % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaae4qaiaabI% eadaWgaaWcbaGaae4maaqabaGccaqGpbacbeGaa83kaiaa-bcaieaa% caGFobGaa43taiaa+bcacaGFOaGaa83kaiaa+1eacaGFPaGaa4hiai% abgkziUkaabccacaqGdbGaaeisamaaBaaaleaacaqGZaaabeaakiaa% b+eacaqGGaGaaeOtaiaab+eacaqGGaGaa4hkaiaa-TcacaGFnbGaa4% xkaiaa+5cacaGFGaGaa4hiaiabeA8aMnaaBaaajqwaacqaaiaaboea% caqGibWaaSbaaKazcaiabaGaae4maaqabaqcKfaGaiaab+eaaSqaba% aaaa!55AC!\[{\rm{CH}}_{\rm{3}} {\rm{O}} + NO ( + M) \to {\rm{ CH}}_{\rm{3}} {\rm{O NO }}( + M). \phi _{{\rm{CH}}_{\rm{3}} {\rm{O}}} \] is found to be (1.0±0.2). The rate constant k ₁ is (7±2) 10^-12 cm³/molecule · s in good agreement with previous results.