Vertical distribution and source identification of polycyclic aromatic hydrocarbons in anoxic sediment cores of Chini Lake, Malaysia: Perylene as indicator of land plant-derived hydrocarbons

Four anoxic sediment cores were collected from Chini Lake, Malaysia in order to investigate the variability of polycyclic aromatic hydrocarbon (PAH) and perylene concentrations. The study also determined significant differences of perylene concentrations in different sediment layers. Total PAH concentrations ranged from 248 to 8098 ng g⁻¹ in the samples. Diagnostic PAH ratios such as methylphenanthrenes/phenanthrene (MP/P), phenanthrene/anthracene (P/A) and fluoranthene/(fluoranthene + pyrene) (Fl/(Fl + Py) revealed a dominance of pyrogenic influences and partial petrogenic inputs to the top sediment layers. Perylene concentrations were high in the top layers (<12 cm) and increased with increasing depth. There is a significant positive correlation (r = 0.705, p = 0.01) between perylene concentrations and TOC. Analysis of variance (ANOVA) and LSD revealed significant differences (p < 0.05) in TOC-normalized perylene concentrations between the upper (<12 cm) and bottom layers (>12 cm). The average perylene concentrations accounted for 26–50% (0–12 cm) and 50–77% (12–36 cm) of pentacyclic-aromatic hydrocarbon isomers (PAI) present whereas it made up 10–34% (0–12 cm) and 46–66% (12–36 cm) of the total PAH. The average pyrene concentrations decreased with increasing depth and accounted for 62% (0–3 cm), 20–23% (3–12 cm) and 3–1.4% (12–36 cm) of perylene present. The results of hierarchical cluster analysis based on these ratios suggested different input sources for the top and bottom layers. It is concluded that the activity of termites on woody plants produced perylene which is supplied to the lake by run-off from the heavy and frequent rains in this Asian tropical climate. In addition, there was also in situ formation of perylene in the bottom layers due to diagenetic processes.     

An evolutionary approach to modelling the thermomechanical behaviour of unsaturated soils

A new data‐mining approach is presented for modelling of the stress–strain and volume change behaviour of unsaturated soils considering temperature effects. The proposed approach is based on the evolutionary polynomial regression (EPR), which unlike some other data‐mining techniques, generates a transparent and structured representation of the behaviour of systems directly from raw experimental (or field) data. The proposed methodology can operate on large quantities of data in order to capture nonlinear and complex relationships between contributing variables. The developed models allow the user to gain a clear insight into the behaviour of the system. Unsaturated triaxial test data from the literature were used for development and verification of EPR models. The developed models were also used (in a coupled manner) to produce the entire stress path of triaxial tests. Comparison of the EPR model predictions with the experimental data revealed the robustness and capability of the proposed methodology in capturing and reproducing the constitutive thermomechanical behaviour of unsaturated soils. More importantly, the capability of the developed models in accurately generalizing the predictions to unseen data cases was illustrated. The results of a sensitivity analysis showed that the models developed from data are able to capture and represent the physical aspects of the unsaturated soil behaviour accurately. The merits and advantages of the proposed methodology are also discussed. Copyright © 2014 John Wiley & Sons, Ltd.     

Regionalization of potential evapotranspiration using a modified region of influence

Theoretical and Applied Climatology - This study examined the effect of different attributes on regionalization of potential evapotranspiration (ETp) in Urmia Lake Basin (ULB), Iran, using the...     

Effect of different meander curvatures on spatial variation of coherent turbulent flow structure inside ingoing multi-bend river meanders

In this paper, the effect of different curvatures on the spatial variation of coherent flow structure inside two physical models with both strongly curved and mild multi-bend meanders is investigated. Three dimensional flow velocities at three sequential meanders were measured using an Acoustic Doppler Velocity meter (Micro-ADV). Three dimensions of flow velocity are classified into two major classes and eight different bursting events. The contribution probability and transition probability of each zone is calculated from experimental data. The results indicated that the effect of curvature in sequential bends was important particularly for strongly curved bends. The contribution probability of the events for strongly curved meanders with relative curvature (R_c/B) of 2.6 were found to be higher than for mild curved meanders with relative curvature (R_c/B) of 4.43. The minimum contribution probability was found in external inward interaction event. In addition, analysis of bursting events showed that the highest values of transition probabilities occurred in the stable organizations for both models. The influences of different curvatures on distributions of the Reynolds shear stress, the turbulent kinetic energy, the streamwise velocity and the vertical velocity were also shown to be in good agreement with eroded bed. The above results can be useful for finding meandering patterns inside rivers and also in river training works.     

A new indicator of elastic spectral shape for the reliable selection of ground motion records

How to select a limited number of ground motion records (GMRs) is an important challenge for the non‐linear analysis of structures. Since epsilon (ε_Sa) is an indicator of spectral shape, which has a significant correlation with the non‐linear response of a structure, the selection of GMRs based on the hazard‐related target ε_Sa is a reasonable approach. In this paper, an alternative indicator of spectral shape is proposed, which results in a more reliable prediction of the non‐linear response for the structures with the natural period of 0.25 to 3.0 s. This new parameter, named eta (η), is a linear combination of ε_Sa and the peak ground velocity epsilon (ε_PGV). It is shown that η, as a non‐linear response predictor, is remarkably more efficient than the well‐known and convenient parameter ε_Sa. The influence of η‐filtration in the collapse analysis of an eight‐story reinforced concrete structure with special moment‐resisting frames was studied. Statistical analysis of the results confirmed that the difference between ε‐filtration and η‐filtration can be very significant at some hazard levels. In the case of this structure, the resulting annual frequency of collapse was found to be lower in the case of η‐based record selection, in comparison with the ε‐based record‐selection approach. Copyright © 2011 John Wiley & Sons, Ltd.     

Genesis of the Nasirabad manganese occurrence,Fars province,Iran: Geochemical evidences

The Nasirabad manganese occurrence is located to the south of the Neyriz in the Fars province. Structurally and lithologically, this occurrence lies in the southwest part of the Zagros Thrust Belt and was deposited as Mn-nodules and interconnected ore-bearing interlayer's with radiolarite cherts in the vicinity of the Neyriz ophiolites. The present work deals with the geology and geochemistry of the Nasirabad manganese occurrence with a discussion of its genesis. High Mn/Fe (average 18.85) and high Ba (average 28,830 ppm) with low Pb (2.0 ppm) and LREE > HREE, La_n/Nd_n (average 4.5), Dy_n/Yb_n (average 1.2) and negative Eu anomaly suggest distal hydrothermal source. The Co/Zn (average 2.2), Ce/La ratio (average 0.67) and trace element discrimination diagrams indicate hydrothermal–hydrogenous processes. Y/Ho ratio (average 24.85) and strong positive correlation coefficient between major oxides and some high field strength elements (HFSE) like; TiO₂ vs Fe₂O₃ (r = 0.98), Al₂O₃ vs Zr (r = 0.97), Al₂O₃ vs Fe₂O₃ (r = 0.98), Zr vs K₂O (r = 0.98), Nb vs TiO₂ (r = 0.92), Th vs Fe₂O₃ (r = 0.76), Th vs MgO (r = 0.86) reveal the presence of volcaniclastics and (or) terrigenous detritals of mafic composition being deposited into the depositional basin. It seems that intermittent interlayering of mafic detrital material derived from volcanic eruption of the Neyriz island arc directly affected the physicochemical conditions of hydrothermal ore precipitation in this basin and consequently the Nasirabad manganese ores represent hydrothermal–hydrogenous geochemical characteristics. The Nasirabad is an example of non-sulphidic, oxic Mn-mineralization. Similar trend between the enrichment and depletion of some bioessential elements (e.g., Mn, As, Ba, Sr, Co, Ce) might have been resulted from selective sequestering of metal ions by microbial processes and hence hydrogenous characteristics may also be the result of biogenetic processes. Moreover the high dilution of distal hydrothermal exhalations by sea water cannot be ruled out.     

The effects of incubation on phosphorus desorption properties, phosphorus availability, and salinity of biosolids-amended soils

Phosphorus (P) desorption characteristics may be altered due to the biosolids decomposition during the incubation period. In our previous work we studied the phosphorus release kinetics in biosolids-amended calcareous soils with no prior incubation. The objectives of this work were (1) to assess the phosphorus desorption behavior in soils as influenced by biosolids after 5 months of incubation and (2) to evaluate the influences of six levels of the biosolids on phosphorus availability and salinity of soil. The results showed that the biosolids addition significantly increased the soil available P and salinity. The P availability and salinity of the soils increased as level of the biosolids application increased. However, there was no significant difference between some application rates for some soils. The results indicated that the incubation can affect the factors controlling the P release rate. Also, the results showed that the soil organic matter negatively affected the P desorption rate in the biosolids-treated soils.     

Structural analysis of the Hasan-Robat marbles as traces of folded basement in the Sanandaj–Sirjan Zone,Iran

Cherty marbles of Hasan-Robat area, northwest of Isfahan, in the Sanandaj–Sirjan Zone of Iran preserves evidences of multiple deformational events. The Sanandaj–Sirjan Zone is the inner crystalline zone of the Zagros Orogen, which has been highly deformed and exhumed during continental collision between the Arabian Plate and Central Iran. The Hasan-Robat area is an example of the exposed Precambrian–Paleozoic basement rocks that stretched along two NW–SE-trending faults and located in the inner part of the HasanRobat positive flower strcuture. The Hasan-Robat marbles record a complex shortening and shearing history. This lead to the development of disharmonic ptygmatic folds with vertical to sub-vertical axes and some interference patterns of folding that may have been created from deformations during the Pan-African Orogeny and later phases. Based on this research, tectonic evolution of the Hasan-Robat area is interpreted as the product of three major geotectonic events that have been started after Precambrian to Quaternary: (1) old deformation phases (2) contractional movements and (3) strike-slip movements. Different sets and distributions of joints, faults and folds are confirmed with effect of several deformational stages of the area and formation of the flower structure.     

Post-cyclic Pullout Response of Geogrid in Compacted Sand and Clayey Sand with Emphasis on Pre-cyclic Load Effect

Geotechnical and Geological Engineering - Soil-geosynthetic interface behavior under cyclic loading will differ from that under static loading. To this end, a series of static and multistep tests...