天然气水合物形成过程中多组分气-固相平衡系数计算方法研究

大量的实验模拟计算需要知道天然气水合物的形成条件。可利用方程式来确定天然气水合物形成条件的数据。目前这种模式和等式的准确性取决于实验数据和理论值的准确性,二者相互依存。实验数据代表实际的物理条件,数据的获取较困难。虽然理论方法略有改变,但从宏观来讲实验方法和数据仍相对稳定。实验通常测试的是液相,而预测的是固相水合物。有关固相水合物实验数据的准确性很难完全通过实验阐述清楚,因为,固相天然水合物的测试遇到了不少困难,如流体堵塞、多相性、取样困难和固相样品描述等。在预测含低硫天然气和含微量CO2和/或H2S的天然…     

Experimental study on local scour around single oblong pier fitted with a collar in a 180 degree flume bend

In this work, investigation on the development of local scour around an oblong pier in a 180 degree flume bend is presented. Scour hole can cause failure of the bridge especially during the river floods. In this study, the use of oblong collars for reducing the effects of local scour at a bridge pier is presented together with the time aspect of the scour development. Tests were conducted using one oblong pier in positions of 60degree under one flow conditions. The study was conducted using a physical hydraulic model operated under clear-water conditions in cohesionless bed material. In this study, the time development of the local scour around the oblong pier fitted with and without collar plates was studied. Investigated was the effect of size and elevation collar on the time development of scour and its efficacy at preventing scour at a bridge pier. The time development of the scour hole around the model pier with and without a collar installed was compared with similar studies on bridge piers. The results of the model study indicated that the maximum depth of scour is highly dependent on the experimental duration. It was observed that, as the minimum depth of scour occurs for the square collar at width of 3B placed at elevation of 0.1B below the bed and the size of a collar plate increases, the scour decreases. Measuring depth of scouring based on experimental observation, an empirical relation is developed with regression coefficient 95%.     

Metal concentrations in selected tissues and main prey species of the annulated sea snake (Hydrophis cyanocinctus) in the Hara Protected Area, northeastern coast of the Persian Gulf, Iran

This study is the first detailed ecotoxicological study of the annulated sea snake, Hydrophis cyanocinctus. Concentrations of lead, cadmium, nickel and vanadium were evaluated in muscle, liver, kidney, skin and blood of the annulated sea snake (H. cyanocinctus) and in the whole bodies of its main prey species (Periophthalmus waltoni and Boleophthalmus dussumieri) in the Hara Protected Area, the Persian Gulf. The mean concentrations of lead and vanadium were highest in the kidney, which identified the kidney as a target organ for metals in sea snakes as it is in other reptilian groups. Mean concentrations of cadmium and nickel were highest in the liver and skin, respectively. Mean cadmium concentrations were significantly higher in the liver compared to prey species, which indicated that prey items may be a source of cadmium for the annulated sea snake in the study area. Data presented here may be considered as a baseline for further ecotoxicological studies in sea snakes.     

Phenolic endocrine disrupting chemicals (EDCs) in Anzali Wetland, Iran: elevated concentrations of 4-nonylphenol, octhylphenol and bisphenol A

We have studied the distribution and value of phenolic endocrine disrupting chemicals (EDCs) in surface sediment samples taken from Anzali Wetland, Iran. These samples were collected from 22 stations during the time span of June-May 2010. In each of the sampling stations, we detected 4-nonylphenol (4-NP), octylphenol (OP), and bisphenol A (BPA) with maximal concentrations of 29, 4.3, and 7 μg g(-1) dry weight (dw), respectively. High levels of alkylphenols (APs) and BPA were also found near urban areas. Furthermore there were no significant differences between those stations in terms of the detected levels. One of the important factors in controlling the fate of these compounds in the aquatic environment appeared to be Total Organic Carbon (TOC). Hierarchical cluster analysis showed differences in the biomarker characteristics of EDCs and TOC between the stations. Our findings indicate that EDCs are ubiquitous in sediments from northeast Wetlands of Iran, contaminating the aquatic habitats in this area.     

Inversion of surface gravity data for 3-D density modeling of geologic structures using total variation regularization

We develop an inversion procedure using the total variation (TV) regularization method as a stabilizing function to invert surface gravity data to retrieve 3-D density models of geologic structures with sharp boundaries. The developed inversion procedure combines several effective algorithms to solve the TV regularized problem. First, a matrix form of the gradient vector is designed using the Kronecker product to numerically approximate the 3-D TV function. The piecewise polynomial truncated singular value decomposition (PP-TSVD) algorithm is then used to solve the TV regularized inverse problem. To obtain a density model with depth resolution, we use a sensitivity-based depth weighting function. Finally, we apply the Genetic Algorithm (GA) to select the best combination of the PP-TSVD algorithm and the depth weighting function parameters. 3-D simulations conducted with synthetic data show that this approach produces sub-surface images in which the structures are well separated in terms of sharp boundaries, without the need of a priori detailed density model. The method applied to a real dataset from a micro-gravimetry survey of Gotvand Dam, southwestern Iran, clearly delineates subsurface cavities starting from a depth of 40 m within the area of the dam reservoir.     

Flood hazard mapping using synthesis hydraulic and geomorphic properties at watershed scale

The occurrence of natural phenomena such as floods has caused serious consequences for human societies. The simulation of flood hazard maps and its depth in a river is one of the most complex processes in hydrology. In fact both geomorphological and hydraulic procedures for deriving the flood hazard maps and depth are imperfect at watershed scale. In this study, a combination of both procedures, using a probabilistic approach is used. Flood inundation maps for 2-, 10-, 25-,50- and 100-return period floods using flood routine within HEC-RAS in combination of Arc-GIS and topographic wetness index (TWI) map were produced. TWI threshold was identified using a maximum likelihood method in order to produce flood prone areas and calibrated over the reach of Zirab City. The correlation between TWI threshold and the flood depth was carried out and simple linear regression developed for various return periods. The resulting regression model is used in order to create flood hazard maps with various return periods at watershed scale.     

Geochemical Anomaly and Mineral Prospectivity Mapping for Vein-Type Copper Mineralization,Kuhsiah-e-Urmak Area,Iran: Application of Sequential Gaussian Simulation and Multivariate Regression Analysis

Natural Resources Research - In this paper, sequential Gaussian simulation (SGS) and number–size (N–S) fractal modeling were used for copper geochemical anomaly mapping in the western...