Records of nutrient-enhanced coastal ocean productivity in sediments from the Louisiana continental shelf

Shelf sediments from near the mouth of the Mississippi River were collected and analyzed to examine whether records of the consequences of anthropogenic nutrient loading are preserved. Cores representing approximately 100 yr of accumulation have increasing concentrations of organic matter over this period, indicating increased accumulation of organic carbon, rapid early diagenesis, or a combination of these processes. Stable carbon isotopes and organic tracers show that virtually all of this increase is of marine origin. Evidence from two cores near the river mouth, one within the region of chronic seasonal hypoxia and one nearby but outside the hypoxic region, indicate that changes consistent with increased productivity began by approximately the mid-1950s when the inorganic carbon in benthic forams rapidly became isotopically lighter at both stations. Beginning in the mid-1960s, the accumulation of organic matter, organic δ¹³C, and δ¹⁵N all show large changes in a direction consistent with increased productivity. This last period coincides with a doubling of the load of nutrients from the Mississippi River, which levelled off in the mid-1980s. These data support the hypothesis that anthropogenic nutrient loading has had a significant impact on the Louisiana shelf.     

Chemistry and palynology of carbon seams and associated rocks from the Witwatersrand goldfields, South Africa

Carbon seams in the Witwatersrand System of South Africa host some of the richest gold concentrations in the world. A study of the microscopic characteristics in thin sections and acid residues, and of the chemical and physical nature of the carbon-bearing phases, was undertaken to gain some understanding of the biological precursors and thermal changes that have occurred since the seams were buried.The HCl---HF acid-resistant organic tissues in this Early Proterozoic coal are filamentous and spherical, which are typical morphologies for microorganisms. The tissues are carbonized black as would be expected for metamorphic rocks, so usual palynological techniques were of limited use. Therefore, the chemical and physical nature of the organic remains was studied by ratios, X-ray diffraction (XRD), ¹³C nuclear magnetic resonance (NMR), reductive chemistry, crosspolarization/magic angle spinning NMR (CP/MAS), and electron spin resonance (ESR).The ratios of the samples examined are similar to those of semi-anthracite and petroleum cokes from delayed cokers. XRD shows graphite is not present and that the gold is in elemental form, not chemically bound or intercalated between carbon planes. NMR shows that both aromatic and paraffinic carbons are present. Integration of the carbon NMR spectra suggests that 80% of the carbon is sp²-hybridized and 20% is sp³-hybridized. Reductive chemistry shows that the benzenoid entities are larger than common polynuclear aromatic hydrocarbons such as perylene and decacyclene. Dipolar dephasing CP/MAS NMR suggests the presence of two types of paraffinic carbons, a rigid methylene group and a rotating methyl group. The narrowing of the ESR linewidth between room temperature and 300°C shows that the materials examined have not previously been subjected to temperatures as high as 300°C.     

Comparison of four numerical models for simulating seepage from salt marsh sediments

A boundary integral equation method (BIEM) model and three differently formulated finite element method (FEM) models were implemented to explore the spatial and temporal patterns in marsh pore water seepage that each generated. The BIEM model is based on the Laplace equation coupled to a dynamic free-surface condition that assumes that, as the water-table changes, the aquifer instantaneously loses or gains an amount of water equal to the change in head times the specific yield. The FEM models all implement a simplified Richards equation that allows gradual desaturation or resaturation and thus flow in both the saturated and unsaturated zones of the aquifer. Two of the FEM models are based on the governing equation for the USGS model SUTRA and thus take into account fluid and aquifer compressibility. One of these was modified to take into account the effect of tidal loading on the total stress, which is assumed to be constant in the derivation of the original version of SUTRA. The third FEM model assumes that neither the fluid or aquifer matrix is compressible so that changes in storage are due solely to changes in saturation. The unmodified SUTRA model generated instantaneous boundary fluxes that were up to two orders of magnitude greater, and spatially more uniform, than those of the other models. The FEM model without compressibility generated spatial and temporal patterns of the boundary fluxes very similar to those produced by the BIEM model. The SUTRA model with the tidal stress modification gave fluxes similar in magnitude to the BIEM and no compressibility models but with distinctly different distributions in space and time. These results indicate that accurate simulation of seepage from marsh soils is highly sensitive to aquifer compressibility and to proper formulation of the effect of tidal loading on the total stress in the aquifer. They also suggest that accurate simulation may require total stress correction not only for tidal loading but for changes in the water table as well. Finally, to aid the development of methods for the measurement of compressibility, we present a schematic, pore-scale model to illustrate the factors that may govern the compressibility of marsh soils.     

Gathering in Thoreau's backyard: nontimber forest product harvesting as practice

Understanding of the gathering of nontimber forest products (NTFPs) in woodlands has focused heavily on politics surrounding public lands and harvester communities. Yet forest gathering may be far more universal. This paper reports the results of a survey of residents in New England, querying whether people gather wild things and for what purposes. The results suggest that gathering in New England, and elsewhere in the developed world, is not restricted to a unique type of community or economy, but instead is a form of practice. Those analytical approaches to NTFPs that seek to produce 'alternatives' to the dominant economy may therefore ironically work to reinforce a capitalocentric view of daily life.     

Comparison of marine and river water humic substances in a Patagonian environment (Argentina)

Structural aspects of humic substances (HSs) in marine waters of Engaño Bay (Atlantic Ocean) and water from the Chubut River (Patagonia, Argentina) were compared. The HSs were isolated, purified, and analyzed using a multiple-method approach for structural characterization: elemental analysis, nuclear magnetic resonance (¹³C and ¹H NMR), infrared spectroscopy (FTIR), UV-visible absorption and fluorescence. Similarities between the marine and freshwater components were evaluated on the basis of N and O contents, H/C and C/N atomic ratios, infrared bands from nitrogen-containing and carboxylic groups, percentage of functional groups obtained from NMR spectra, spectral slope coefficient of absorption spectra, absorbance ratios at 250 and 365 nm (E ₂/E ₃), aromaticity, excitation–emission matrices and fluorescence quantum yield. Both the Engaño Bay and Chubut River waters have HSs that are mainly composed of fulvic acids (FAs); although they are very similar, they may be distinguished from one another. Similarities include the predominance of aliphatic carbon content (low aromatic content); however, the water bodies differed in their content of proteins and carboxylic acids. The Engaño Bay FAs have mainly an aquatic origin; although the Chubut River FAs suggest a similar aquagenic origin, there is also evidence of contributions from pedogenic FAs.     

Set-up of a decision support system to support sustainable development of the Laguna de Bay,Philippines

Over recent decades, population expansion, deforestation, land conversion, urbanisation, intense fisheries and industrialisation have produced massive changes in the Laguna de Bay catchment, Philippines. The resulting problems include rapid siltation of the lake, eutrophication, inputs of toxics, flooding problems and loss of biodiversity. Rational and systematic resolution of conflicting water use and water allocation interests is now urgently needed in order to ensure sustainable use of the water resources. With respect to the competing and conflicting pressures on the water resources, the Laguna Lake Development Authority (LLDA) needs to achieve comprehensive management and development of the area. In view of these problems and needs, the Government of the Netherlands was funding a two-year project entitled 'Sustainable Development of the Laguna de Bay Environment'.A comprehensive tool has been developed to support decision-making at catchment level. This consists of an ArcView GIS-database linked to a state-of-the-art modelling suite, including hydrological and waste load models for the catchment area and a three-dimensional hydrodynamic and water quality model (Delft3D) linked to a habitat evaluation module for the lake. In addition, MS Office based tools to support a stakeholder analysis and financial and economic assessments have been developed. The project also focused on technical studies relating to dredging, drinking water supply and infrastructure works. These aimed to produce technically and economically feasible solutions to water quantity and quality problems. The paper also presents the findings of a study on the development of polder islands in the Laguna de Bay, addressing the water quantity and quality problems and focusing on the application of the decision support system.     

An evaluation of glass prisms in boat docks to reduce shading of submerged aquatic vegetation in the lower St. Johns River,Florida

The effectiveness of glass prisms in boat docks was assessed to determine if shading impacts to submerged aquatic vegetation (SAV), primarilyVallisneria americana, were reduced. Six experimental docks, three with prisms and three without prisms, were constructed in the lower St. Johns River, Florida. SAV percent cover and photosynthetically active radiation (PAR) were monitored under each dock and in an adjacent control area with no experimental docks. Subsurface PAR during the growing season of the first year of the study was not significantly greater beneath docks having prisms than beneath docks without prisms. Postconstruction SAV monitoring (February 2000 to May 2002) revealed no significant differences in SAV percent cover between dock treatments, although coverage declined in both dock treatments and the control area. Declining water quality conditions at the study site clearly impacted the health of the SAV habitat as indicated by the decline in SAV coverage in the control area initially in the study. Given the subsequent resurgence of SAV in the control area, the additional light transmitted through the prisms did not appear to be biologically significant or adequate to counteract effects from larger-scale environmental stressors.     

Weathering profiles in granites, Sierra Norte (Córdoba, Argentina)

Two weathering profiles evolved on peneplain-related granites in Sierra Norte, Córdoba province, were examined. Several weathering levels, of no more than 2 m thickness, were studied in these profiles. They had developed from similar parent rock, which had been exposed to hydrothermal processes of varying intensity. Fracturing is the most notable feature produced by weathering; iron oxides and silica subsequently filled these fractures, conferring a breccia-like character to the rock. The clay minerals are predominantly illitic, reflecting the mineral composition of the protolith. Smaller amounts of interstratified I/S RO type are also present, as well as scarce caolinite+chlorite that originated from the weathering of feldspar and biotite, respectively. The geochemical parameters define the weathering as incipient, in contrast to the geomorphological characteristics of Sierra Norte, which point to a long weathering history. This apparent incompatibility could be due to the probable erosion of the more weathered levels of the ancient peneplains, of which only a few relicts remain. Similar processes have been described at different sites in the Sierras Pampeanas. Reconstruction and dating of the paleosurfaces will make it possible to set time boundaries on the weathering processes studied and adjust the paleographic and paleoclimatic interpretations of this great South American region.     

Practical field-portable atomic absorption analyser

A new compact atomic absorption spectrophotometer has been developed. Designated the Scintrex AAZ-2, the system used flameless atomization and Zeeman modulation for maximum sensitivity and selectivity respectively. The most important factor of AA instrumentation is the method used for vapourizing the sample. The atomizer furnace in the AAZ-2 is a tungsten ribbon, rather than the conventional carbon furnace, to avoid the need for high electrical power input and consequent water cooling. The ribbon is U-shaped to fit between the pole pieces of a powerful electromagnet which provides the magnetic field required for Zeeman modulation of the absorption signal. Zeeman modulation refers to the spectral displacement of atomic absorption lines in the presence of a magnetic field. By pulsing the field, the emission from the source lamp alternately does, or does not, coincide with the analyte absorption. A synchronous detection system then allows the extraction of the modulated signal from any unmodulated absorption due to nonspecific absorbers such as particulate scattering or some molecular species. Zeeman modulation provides a method of baseline correction that is both more efficient and simpler than the commonly used deuterium are correction and requires no moving components. The AAZ instrument has already been characterized for a number of metals, in particular, those of exploration interest such as Au, Ag, Cu, Pb, Ni, Co. Zinc has been determined but difficulties in avoiding high blank concentrations have been found. Detection limits are typically 1 ng/ml or better (e.g. Au — 0.5 ng/ml, Ag — 0.06 ng/ml). The metals usually requiring conversion to a gaseous hydride form before analyses have also been studied. Tin in the sub-ppm range has been determined after a simple extraction procedure. Work on arsenic, selenium, antimony and bismuth is planned. The entire machine weighs 26 kg and consumes 0.5 kW making it suitable for use in remote areas using portable power generating equipment. Argon at low pressure and flow rate is the only gas needed for operation. When used for analysis of samples in a base camp, close to the scene of a geochemical drilling program, the AAZ-2 can provide quick turnaround of the results and therefore on-the-spot guidance of these programs without loss of sensitivity or data quality. In addition, the possibility of contamination by high-level samples is somewhat less in a field camp than in a long established laboratory.