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111.
Allison E. Ray John R. Bargar Alice C. Dohnalkova Brent M. Peyton Timothy S. Magnuson 《Geochimica et cosmochimica acta》2011,75(10):2684-6510
Microbial reduction of hexavalent uranium has been studied widely for its potential role in bioremediation and immobilization of soluble U(VI) in contaminated groundwater. More recently, some microorganisms have been examined for their role in immobilization of U(VI) via precipitation of uranyl phosphate minerals mediated by microbial phosphate release, alleviating the requirement for long-term redox control. Here, we investigated the mechanism of U(VI) removal mediated by an environmental isolate, strain UFO1, that is indigenous to the Field Research Center (FRC) in Oak Ridge, TN and has been detected in U(VI)-contaminated sediments. Changes in U(VI) speciation were examined in the presence and absence of the electron-shuttling moiety, anthraquinone-2,6-disulfonate (AQDS). Cell suspensions were capable of nearly complete removal of 100 μM U(VI) from solution within 48 h; U(VI) removal was not dependent on the presence of an exogenous electron donor or AQDS, although AQDS increased the rate of U(VI) removal. X-ray Absorption Near Edge Structure (XANES) and Extended X-ray Absorption Fine Structure (EXAFS) spectroscopic measurements indicated that U(IV) was the predominant oxidation state of uranium in cell suspensions in both the absence and presence of 100 μM AQDS. Interestingly, 17% of the cell-associated precipitates in a U(VI)-treated suspension that lacked AQDS had spectral characteristics consistent with a uranyl phosphate solid phase. The potential involvement of phosphate was consistent with observed increases in soluble phosphate concentrations over time in UFO1 cell suspensions, which suggested phosphate liberation from the cells. TEM-EDS confirmed the presence of uranyl phosphate with a U:P ratio consistent with autunite (1:1). EXAFS analyses further suggested that U(IV) was bound to low-Z neighbors such as C or P, inferred to be present as functional groups on biomass. These results suggest that strain UFO1 has the ability to facilitate U(VI) removal from solution via reductive and phosphate precipitation mechanisms. Both mechanisms offer potential for the remediation of U-contaminated sediments at the FRC or elsewhere. 相似文献
112.
Hannah H. Kaplan Victoria E. Hamilton Ellen S. Howell F. Scott Anderson M. Antonella Barrucci John Brucato Thomas H. Burbine Beth E. Clark Ed A. Cloutis Harold C. Connolly Elisabetta Dotto Joshua P. Emery Sonia Fornasier Cateline Lantz Lucy F. Lim Frederic Merlin Alice Praet Dennis C. Reuter Scott A. Sandford Amy A. Simon Driss Takir Dante S. Lauretta 《Meteoritics & planetary science》2020,55(4):744-765
The primary objective of the Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS‐REx) mission is to return to Earth a pristine sample of carbonaceous material from the primitive asteroid (101955) Bennu. To support compositional mapping of Bennu as part of sample site selection and characterization, we tested 95 spectral indices on visible to near infrared laboratory reflectance data from minerals and carbonaceous meteorites. Our aim was to determine which indices reliably identify spectral features of interest. Most spectral indices had high positive detection rates when applied to spectra of pure, single‐component materials. The meteorite spectra have fewer and weaker absorption features and, as a result, fewer detections with the spectral indices. Indices targeting absorptions at 0.7 and 2.7–3 μm, which are attributable to hydrated minerals, were most successful for the meteorites. Based on these results, we identified a set of 17 indices that are most likely to be useful at Bennu. These indices detect olivines, pyroxenes, carbonates, water/OH‐bearing minerals, serpentines, ferric minerals, and organics. Particle size and albedo are known to affect band depth but had a negligible impact on interpretive success with spectral indices. Preliminary analysis of the disk‐integrated Bennu spectrum with these indices is consistent with expectations given the observed absorption near 3 μm. Our study prioritizes spectral indices to be used for OSIRIS‐REx spectral analysis and mapping and informs the reliability of all index‐derived data products, including a science value map for sample site selection. 相似文献
113.
Neutral aldoses as source indicators for marine snow 总被引:2,自引:0,他引:2
Annelie Skoog Alice Alldredge Uta Passow John Dunne James Murray 《Marine Chemistry》2008,108(3-4):195-206
The chemical characteristics of aggregating material in the marine environment are largely unknown. We investigated neutral aldose (NA) abundance and composition in aggregation of marine snow and other organic matter (OM) size fractions in the field. Four sample sets were fractionated using membrane filtration and ultrafiltration into the following size fractions: particulate material, high-molecular-weight (HMW) material, and low-molecular-weight (LMW) material. We also collected three sample sets of marine-snow aggregates. Each sample set contained small, medium, and large aggregate size fractions and each size fraction consisted of 25–50 aggregates. For 7 marine-snow samples and for each water-sample size fraction, we determined monomeric and polymeric NA concentration, NA yield (amount of NA-C normalized to organic carbon), and composition; total organic carbon (TOC) concentration; transparent exopolymer particles (TEP) concentration, and TEP propensity (TEP concentration after inducing TEP formation in filtered samples). This is the first study to include compound-specific NA determinations on these four marine OM size fractions.The mass balances of organic carbon and NA indicated that there were no serious contamination or loss problems. Concentrations, yields, and NA mol fractions in water samples were similar to results from other studies. Glucose and galactose had the highest relative abundance in all size fractions. The NA yield increased with increasing molecular weight or particle size for all fractions except marine snow. The NA yield increased in the order: LMW< marine snow< HMW< particles. Marine snow had a higher average NA yield than the LMW fraction, but lower than particle and HMW-fractions. This indicates that OM in marine snow could have been diagenetically derived from particulate and HMW-fractions, that is, marine snow may include material from the particulate and the colloidal phase.TEP concentration or TEP propensity was positively correlated with concentrations of all individual NAs as well as the sum NA concentrations, indicating that TEP contains neutral sugars in addition to the acidic polysaccharides stained in the determination of TEP concentrations.Despite the relatively low NA yield in marine snow, marine snow was enriched in NA when compared with seawater, with enrichment factors of 34–225 (average 125). By combining data from this study with data from other studies, we estimate that < 10% of carbohydrates in marine snow comprise NAs.There was no clear correlation between marine-snow aggregate size and NA yield, that is, there appears to be no general age difference between small and large marine-snow aggregates. NA composition was similar among different marine-snow size fracions collected during the same day, indicating that aggregation/disaggregation reactions resulted in homogenizing NA composition in marine-snow aggregates of all sizes. The NA composition of marine snow was different from that of other OM size fractions, indicating either that bacterial degradation has modified the composition of marine snow to a larger extent than other OM size fractions or that marine snow is formed through the aggregation of selected subcomponents of OM. 相似文献
114.
Alice K. Harding Isabelle A. Grenier Peter L. Gonthier 《Astrophysics and Space Science》2007,309(1-4):221-230
Radio-quiet γ-ray pulsars like Geminga may account for a number of the unidentified EGRET sources in the Galaxy. The number of Geminga-like
pulsars is very sensitive to the geometry of both the γ-ray and radio beams. Recent studies of the shape and polarization of pulse profiles of young radio pulsars have provided
evidence that their radio emission originates in wide cone beams at altitudes that are a significant fraction (1–10%) of their
light cylinder radius. Such wide radio emission beams will be visible at a much larger range of observer angles than the narrow
core components thought to originate at lower altitude. Using 3D geometrical modeling that includes relativistic effects from
pulsar rotation, we study the visibility of such radio cone beams as well as that of the γ-ray beams predicted by slot gap and outer gap models. From the results of this study, one can obtain revised predictions
for the fraction of Geminga-like, radio quiet pulsars present in the γ-ray pulsar population.
相似文献
115.
A new picture of pulsar high-energy emission is proposed that is different from both the traditional polar cap and outer gap
models, but combines elements of each. The slot gap model is based on electron acceleration along the edge of the open field
region from the neutron star surface to near the light cylinder and thus could form a physical basis for the two-pole caustic
model of Dyks and Rudak (2003). Along the last open field line, the pair formation front rises to very high altitude forming
a slot gap, where the accelerating electric field is unscreened by pairs. The resulting radiation features both hollow cones
from the lower-altitude pair cascades, seen at small viewing angles, as well as caustic emission on the trailing-edge field
lines at high altitude, seen from both poles at large viewing angle. The combination of the small solid angle of slot gap
emission (≪ 1 sr) with a high probability of viewing the emission predicts that more gamma-ray pulsars could be detected at
larger distances. In this picture, many of the positional coincidences of radio pulsars with unidentified EGRET sources become
plausible as real associations, as the flux predicted by the slot gap model for many of the pulsars would provide the observed
EGRET source flux. The expected probability of seeing radio-quiet gamma-ray pulsars in this model will also be discussed. 相似文献
116.
Marine reservoir age is reported for Foxe Basin, Canada, during deglaciation of the Laurentide Ice Sheet. Radiocarbon (14C) measurements were made on pairs of contemporaneous molluscs and Salix (willow) macrofossils, yielding a mean marine reservoir age of 985 ± 10 14C a. Mean regional ΔR is calculated to be 615 ± 20 14C a relative to a mean global reservoir age of ca. 400 14C a. Previous studies in the Canadian Arctic that have been conducted on modern pre‐bomb molluscs give ΔR values of ca. 100–300 14C a. The difference between modern and deglacial reservoir ages indicates that ΔR in Foxe Basin has changed over time, which has implications for the reconstruction of past events based on marine 14C dates. We recalculate the timing of deglaciation of Hudson Strait with this new reservoir age and relate this to the 8.2 cal. ka event. We recommend that local ΔR be determined for the time period being examined whenever possible, and that in cases where this is impossible a ΔR value of 615 14C a be applied when calibrating marine samples from Foxe Basin and vicinity during deglaciation. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
117.
We describe a parallel hybrid symplectic integrator for planetary system integration that runs on a graphics processing unit (GPU). The integrator identifies close approaches between particles and switches from symplectic to Hermite algorithms for particles that require higher resolution integrations. The integrator is approximately as accurate as other hybrid symplectic integrators but is GPU accelerated. 相似文献
118.
119.
Marine and river bedforms are rhythmic features driven by unidirectional or reversing currents and waves. They are ubiquitous on the floors of rivers, estuaries, coastal and marine settings. Despite a considerable history of dedicated studies, many aspects of their origin, development and dynamics are still the subject of scientific debate in various disciplines. The MARID conferences series hosts experts from geosciences, physics, engineering and other disciplines to provide a platform for the interdisciplinary exchange of fundamental and applied knowledge of marine and river dune dynamics. MARID VI took place in April 2019 in Bremen, Germany. Related scientific contributions are presented in this special issue of Earth Surface Processes and Landforms. An overview of the conference series and the specifics of MARID VI, as well as considerations in the context of equity, diversity and inclusion, are given. This introduction highlights the progress made with the papers published in the special issue. 相似文献
120.
A. K. Sahai D. R. Pattanaik V. Satyan Alice M. Grimm 《Meteorology and Atmospheric Physics》2003,84(3-4):217-227
Summary The prediction of Indian Summer Monsoon Rainfall (ISMR) is vital for Indian economic policy and a challenge for meteorologists. It needs various predictors among which El Niño-Southern Oscillation (ENSO) is the most important. It has been established by various researchers that ENSO and ISMR relationship is weakening in recent years. It has been also argued that changes in ENSO-ISMR relationship may be due to decadal fluctuations, or it may be the indicative of longer-term trends related to anthropogenic-induced climate changes.In the present communication, an attempt is made to discuss the variability and predictability of ISMR in recent years. It is found that three different indices associated with different regions in the tropics and extra-tropics at different levels of the atmosphere-Asian land mass index represented by geopotential height at upper troposphere (A1), Caribbean-North Atlantic index represented by geopotential height at middle troposphere (A2) and tropical Pacific index at surface level (A3) – have different mechanisms to interact mutually and separately with ISMR in different periods. In recent years ISMR shows weak association with A1 and A3 while strong association with A2. Thus, if these three indices could be combined objectively, they can give rise to the predictability of ISMR. This objective combination is achieved here using Artificial Neural Network (ANN) and a model is developed to predict ISMR. This model has predicted reasonably well during the whole period of consideration (1958–2000) with a correlation coefficient of 0.92 in last 11 years (1990–2000) whereas most of the models fail to predict the variability in recent time.Current affiliation: Department of Physics, Federal University of Parana, Curitiba, Brazil.Received June 2002; revised October 1, 2002; accepted November 12, 2002
Published online: April 10, 2003 相似文献