Characterization of coal maceral concentrates by curie-point pyrolysis mass spectrometry

A set of 30 maceral concentrates consisting of 5 exinites (sporinites), 14 vitrinites and 11 inertinites (fusinites and semifusinites) was analyzed by Curie-point pyrolysis mass spectrometry in combination with computerized multivariate statistical analysis techniques. Seventeen samples, representing sink/flotation concentrates of 7 different coals, were obtained through the British National Coal Board, whereas the remaining samples represent cesium-chloride density-gradient centrifugation fractions of two different U.S. coals prepared at the University of Utah.It is found that vitrinites, (semi)fusinites and, to some extent, sporinites show qualitatively similar rank-related changes, such as a decrease in dihydroxybenzene signals and an increase in napthalene signals with increasing rank. In fact, the overall pyrolysis MS patterns of inertinities show a close similarity to those of vitrinites of corresponding carbon content (as obtained from higher rank coals).Notwithstanding these similarities, however, the presence of basic differences in maceral structure is indicated by relatively minor but characteristic peak series in the liptinite (sporinite) as well as inertinite samples. Whereas inertinite spectra show relatively pronounced peak series at the high mass end of the spectrum which can be tentatively identified as representative of polynuclear aromatic compounds, sporinites are characterized by series of branched aliphatic and/or alicyclic polyenic hydrocarbons, possibly representing isoprenoids and related biomarker compounds.     

What if negative emission technologies fail at scale? Implications of the Paris Agreement for big emitting nations

A cumulative emissions approach is increasingly used to inform mitigation policy. However, there are different interpretations of what ‘2°C’ implies. Here it is argued that cost-optimization models, commonly used to inform policy, typically underplay the urgency of 2°C mitigation. The alignment within many scenarios of optimistic assumptions on negative emissions technologies (NETs), with implausibly early peak emission dates and incremental short-term mitigation, delivers outcomes commensurate with 2°C commitments. In contrast, considering equity and socio-technical barriers to change, suggests a more challenging short-term agenda. To understand these different interpretations, short-term CO₂ trends of the largest CO₂ emitters, are assessed in relation to a constrained CO₂ budget, coupled with a ‘what if’ assumption that negative emissions technologies fail at scale. The outcomes raise profound questions around high-level framings of mitigation policy. The article concludes that applying even weak equity criteria, challenges the feasibility of maintaining a 50% chance of avoiding 2°C without urgent mitigation efforts in the short-term. This highlights a need for greater engagement with: (1) the equity dimension of the Paris Agreement, (2) the sensitivity of constrained carbon budgets to short-term trends and (3) the climate risks for society posed by an almost ubiquitous inclusion of NETs within 2°C scenarios.

POLICY RELEVANCE

Since the Paris meeting, there is increased awareness that most policy ‘solutions’ commensurate with 2°C include widespread deployment of negative emissions technologies (NETs). Yet much less is understood about that option’s feasibility, compared with near-term efforts to curb energy demand. Moreover, the many different ways in which key information is synthesized for policy makers, clouds the ability of policy makers to make informed decisions. This article presents an alternative approach to consider what the Paris Agreement implies, if NETs are unable to deliver more carbon sinks than sources. It illustrates the scale of the climate challenge for policy makers, particularly if the Agreement’s aim to address ‘equity’ is accounted for. Here it is argued that much more attention needs to be paid to what CO₂ reductions can be achieved in the short-term, rather than taking a risk that could render the Paris Agreement’s policy goals unachievable.     

Cosmo-SkyMed X-band SAR data for classification of ice-free areas and glacier facies on Potter Peninsula,King George Island Antarctica

The climate change phenomena have been influencing terrestrial and glacial ecosystems around the planet. Maritime Antarctica is especially sensitive to these climate variations and over the last 50 years increasing global air temperatures have caused extensive glacial retreat. The objective of this study is to evaluate the potential use of the SAR technology in monitoring the surface dynamics of the Potter Peninsula, King George Island, maritime Antarctica. An image generated by the SAR satellite COSMO-SkyMed, obtained on 2 February 2011, was used to extract the backscattering values of targets on the surface for further processing and classification, using a supervised statistic classifier of maximum likelihood for the determination of the surface classes. The average backscattering of water bodies presented high similarity, which made its separation unattainable. On the other hand, the surface classes’ bare ice and wet snow over the glacier presented distinct average backscattering values, which allowed an efficient and precise classification using only this parameter. The classification process showed satisfactory results for periglacial environments, presenting high fidelity to the field data.     

Teleconnections in recent time and prediction of Indian summer monsoon rainfall

Summary The prediction of Indian Summer Monsoon Rainfall (ISMR) is vital for Indian economic policy and a challenge for meteorologists. It needs various predictors among which El Niño-Southern Oscillation (ENSO) is the most important. It has been established by various researchers that ENSO and ISMR relationship is weakening in recent years. It has been also argued that changes in ENSO-ISMR relationship may be due to decadal fluctuations, or it may be the indicative of longer-term trends related to anthropogenic-induced climate changes.In the present communication, an attempt is made to discuss the variability and predictability of ISMR in recent years. It is found that three different indices associated with different regions in the tropics and extra-tropics at different levels of the atmosphere-Asian land mass index represented by geopotential height at upper troposphere (A1), Caribbean-North Atlantic index represented by geopotential height at middle troposphere (A2) and tropical Pacific index at surface level (A3) – have different mechanisms to interact mutually and separately with ISMR in different periods. In recent years ISMR shows weak association with A1 and A3 while strong association with A2. Thus, if these three indices could be combined objectively, they can give rise to the predictability of ISMR. This objective combination is achieved here using Artificial Neural Network (ANN) and a model is developed to predict ISMR. This model has predicted reasonably well during the whole period of consideration (1958–2000) with a correlation coefficient of 0.92 in last 11 years (1990–2000) whereas most of the models fail to predict the variability in recent time.Current affiliation: Department of Physics, Federal University of Parana, Curitiba, Brazil.Received June 2002; revised October 1, 2002; accepted November 12, 2002 Published online: April 10, 2003     

Postglacial sedimentary record and history of West Hawk Lake crater,Manitoba

West Hawk Lake (WHL) is located within the glacial Lake Agassiz basin, 140 km east of Winnipeg, Manitoba. The small lake lies in a deep, steep-sided, meteorite impact crater, which has been partly filled by 60 m of sediment that today forms a flat floor in the central part of the basin below 111 m of water. Four cores, 5–11 m in length, were collected using a Kullenberg piston gravity corer. All sediment is clay, contains no unconformities, and has low organic content in all but the upper meter. Sample analyses include bulk and clay mineralogy, major and minor elements, TOC, stable isotopes of C, N, and O, pollen, charcoal, diatoms, and floral and faunal macrofossils. The sequence is divided into four units based mainly on thickness and style of lamination, diatoms, and pollen. AMS radiocarbon dates do not provide a clear indication of age in the postglacial sequence; possible explanations include contamination by older organic inwash and downward movement of younger organic acids. A chronological framework was established using only selected AMS dates on plant macrofossils, combined with correlations to dated events outside the basin and paleotopographic reconstructions of Lake Agassiz. The 822 1-cm-thick varves in the lower 8 m of the cored WHL sequence were deposited just prior to 10,000 cal years BP (∼8,900 ¹⁴C years BP), during the glacial Lake Agassiz phase of the lake. The disappearance of dolomite near the top of the varved sequence reflects the reduced influence of Lake Agassiz and the carbonate bedrock and glacial sediment in its catchment. The lowermost varves are barren of organisms, indicating cold and turbid glacial lake waters, but the presence of benthic and planktonic algae in the upper 520 varves indicates warming; this lake phase coincides with a change in clay mineralogy, δ¹⁸O and δ¹³C in cellulose, and in some other parameters. This change may have resulted from a major drawdown in Lake Agassiz when its overflow switched from northwest to east after formation of the Upper Campbell beach of that lake 9,300–9,400 ¹⁴C years ago. The end of thick varve deposition at ∼10,000 cal years BP is related to the opening of a lower eastern outlet of Lake Agassiz and an accompanying drop in West Hawk Lake level. WHL became independent from Lake Agassiz at this time, sedimentation rates dropped, and only ∼2.5 m of sediment was deposited in the next 10,000 years. During the first two centuries of post-Lake Agassiz history, there were anomalies in the diatom assemblage, stable O and C isotopes, magnetic susceptibility, and other parameters, reflecting an unstable watershed. Modern oligotrophic conditions were soon established; charcoal abundance increased in response to the reduced distance to the shoreline and to warmer conditions. Regional warming after ∼9,500 cal years BP is indicated by pollen and diatoms as well as C and O isotope values. Relatively dry conditions are suggested by a rise in pine and decrease in spruce and other vegetation types between 9,500 and 5,000 cal years BP (∼8,500–4,400 ¹⁴C years BP), plus a decrease in δ¹³C_cell values. After this, there was a shift to slightly cooler and wetter conditions. A large increase in organic content and change in elemental concentration in the past several thousand years probably reflects a decline in supply of mineral detritus to the basin and possibly an increase in productivity.     

Measuring and monitoring persistent organic pollutants in the context of risk assessment

Due to growing concerns regarding persistent organic pollutants (POPs) in the environment, extensive studies and monitoring programs have been carried out in the last two decades to determine their concentrations in water, sediment, and more recently, in biota. An extensive review and analysis of the existing literature shows that whilst the vast majority of these efforts either attempt to compare (a) spatial changes (to identify "hot spots"), or (b) temporal changes to detect deterioration/improvement occurring in the environment, most studies could not provide sufficient statistical power to estimate concentrations of POPs in the environment and detect spatial and temporal changes. Despite various national POPs standards having been established, there has been a surprising paucity of emphasis in establishing accurate threshold concentrations that indicate potential significant threats to ecosystems and public health. Although most monitoring programs attempt to check compliance through reference to certain "environmental quality objectives", it should be pointed out that many of these established standards are typically associated with a large degree of uncertainty and rely on a large number of assumptions, some of which may be arbitrary. Non-compliance should trigger concern, so that the problem can be tracked down and rectified, but non-compliance must not be interpreted in a simplistic and mechanical way. Contaminants occurring in the physical environment may not necessarily be biologically available, and even when they are bioavailable, they may not necessarily elicit adverse biological effects at the individual or population levels. As such, we here argue that routine monitoring and reporting of abiotic and biotic POPs concentrations could be of limited use, unless such data can be related directly to the assessment of public health and ecological risks. Risk can be inferred from the ratio of predicted environmental concentration (PEC) and the predicted no effect concentration (PNEC). Currently, the paucity of data does not allow accurate estimation of PNEC, and future endeavors should therefore, be devoted to determine the threshold concentrations of POPs that can cause undesirable biological effects on sensitive receivers and important biological components in the receiving environment (e.g. keystone species, populations with high energy flow values, etc.), to enable derivation of PNECs based on solid scientific evidence and reduce uncertainty. Using the threshold body burden of POPs required to elicit damages of lysosomal integrity in the green mussel (Perna virvidis) as an example, we illustrate how measurement of POPs in body tissue could be used in predicting environmental risk in a meaningful way.     

Is the connectivity function a good indicator of soil infiltrability distribution and runoff flow dimension?

Among the studies on runoff connectivity of soils with heterogeneous properties, the need to understand the relationships between soil heterogeneity and the associated runoff organization and amount is frequently mentioned. In this study, we simulate the stationary runoff–runon process on bi‐dimensional (2D) flat slopes for five infiltrability distributions, one of them correlated, as a function of rainfall intensity and flow dimension. We define flow dimension by 1 + ε, where ε is the outflow fraction transferred from one pixel to each of the two lateral downslope pixels. Our aim is to assess the effect of ε and soil heterogeneity on the connectivity function compared to the mean runoff flow rate, the wet area and the number of runoff patterns. The analysis of connectivity is carried within the percolation framework. The results show that the integral connectivity scale is more sensitive to the flow dimension and soil heterogeneity compared to the other variables. The wet area fraction does not depend on ε. Unlike previous studies, we find that increased runoff production is not necessarily related to increased connectivity. The use of the connectivity function within the percolation framework appears to be a valuable method for assessing the impact of soil heterogeneity and flow dimension on the runoff organization during a rainfall event. Copyright © 2014 John Wiley & Sons, Ltd.     

Crystallographic preferred orientation in albite samples deformed experimentally by dislocation and solution precipitation creep

The crystallographic preferred orientations of a series of experimentally deformed fine-grained albite aggregates were measured by synchrotron source X-ray diffraction. Most samples were deformed and extensively recrystallized by low-temperature recrystallization-accommodated dislocation creep. In axial compression as well as simple shear these samples developed weak but distinct crystallographic preferred orientations consistent with intracrystalline slip on {001}<100>; the sheared samples have a marked asymmetry of the <100> maxima with respect to the shear zone boundaries. One sample was axially compressed by solution precipitation creep; it developed a somewhat different but equally strong preferred orientation, perhaps reflecting crystallographic anisotropy in rates of dissolution and growth.     

Geoarchaeology at Gilman Falls: An Archaic quarry and manufacturing site in central Maine,U.S.A.

Interdisciplinary investigations at the Milford Reservoir, central Maine, resulted in excavation and analysis of a Middle Archaic quarry and manufacturing site at Gilman Falls, dated to between 7300 and 6300 yr B.P. Lithological analysis indicates that the majority of the artifacts came from very local outcrops, providing low‐grade metamorphic rocks. Native Americans used a specialized technique to reduce the granofels and other rocks to long rods, artifacts commonly placed in local cemeteries. The Gilman Falls site was largely abandoned once these artifacts were no longer in vogue. Therefore, access to particular bedrock outcrops seems to have played an important role in site selection. Gilman Falls and other early to middle Holocene sites are preserved where bedrock sill dams ponded water that deposited fine sand. Early site sedimentation history is paralleled by a drainage change in the headwaters of the Penobscot River. Evidence for lower mid‐Holocene lake levels and a period of higher temperatures and lower precipitation may correlate with the sedimentation history. © 2001 John Wiley & Sons, Inc.