Neoproterozoic diamictite in the Eastern Desert of Egypt and Northern Saudi Arabia: evidence of ~750 Ma glaciation in the Arabian–Nubian Shield?

The Neoproterozoic Atud diamictite in Wadi Kareim and Wadi Mobarak in the Eastern Desert of Egypt and the Nuwaybah formation in NW Saudi Arabia consist of poorly sorted, polymictic breccia, with clasts up to 1 m of granitoid, quartz porphyry, quartzite, basalt, greywacke, marble, arkose, and microconglomerate in fine-grained matrix. Stratigraphic relations indicate that the diamictite was deposited in a marine environment. Integrated field investigation, petrographic study and U–Pb SHRIMP zircon ages demonstrate that the Atud and Nuwaybah are correlative. The distribution of zircon ages indicate that ~750 Ma ages are dominant with a significant component of older materials, characterized by minor Mesoproterozoic and more abundant Paleoproterozoic and Neoarchean ages. Some matrix and metasedimentary clast zircons yield ages that are a few 10s of Ma younger than the age of the youngest clast (754 ± 15 Ma), suggesting Atud/Nuwaybah diamictite deposition ~750 Ma or slightly later, broadly consistent with being deposited during the Sturtian glaciation (740–660 Ma). The Paleoproterozoic and Neoarchean clasts have no source within the ensimatic Arabian–Nubian Shield. The distribution of the pre-Neoproterozoic ages are similar to the distribution of the pre-Neoproterozoic ages in Yemen and Saharan Metacraton, suggesting that these clasts have been transported hundreds of kilometers, maybe by ice-rafting. The Atud diamictite may represent important evidence for Cryogenian “Snowball Earth” in the Arabian–Nubian Shield.     

Late Cenozoic tectonics and stratigraphy of northwestern Anatolia: the effects of the North Anatolian Fault to the region

In northwest Anatolia, there is a mosaic of different morpho-tectonic fragments within the western part of the right-lateral strike-slip North Anatolian Fault (NAF) Zone. These were developed from compressional and extensional tectonic regimes during the paleo- and neo-tectonic periods of Turkish orogenic history. A NE-SW-trending left-lateral strike-slip fault system (Adapazari-Karasu Fault) extends through the northern part of the Sakarya River Valley and began to develop within a N–S compressional tectonic regime which involved all of northern Anatolia during Middle Eocene to early Middle Miocene times. Since the end of Middle Miocene times, this fault system forms a border between a compressional tectonic regime in the eastern area eastwards from the northern part of the Sakarya River Valley, and an extensional tectonic regime in the Marmara region to the west. The extension caused the development of basins and ridges, and the incursions of the Mediterranean Sea into the site of the future Sea of Marmara since Late Miocene times. Following the initiation in late Middle Miocene times and the eastward propagation of extension along the western part of the NAF, a block (North Anatolian Block) began to form in the northern Anatolia region since the end of Pliocene times. The Adapazari-Karasu Fault constitutes the western boundary of this block which is bounded by the NAF in the south, the Northeast Anatolian Fault in the east, and the South Black Sea Thrust Fault in the north. The northeastward movement of the North Anatolian Block caused the formation of a marine connection between the Black Sea and the Aegean/Mediterranean Sea during the Pleistocene.     

Temperature inversion and mixing height: critical indicators for air pollution in hot arid climate

Natural Hazards - Boundary layer temperature inversion and mixing heights are important parameters in understanding the atmospheric dispersion of air pollution. Surface and elevated inversions were...     

Influence of saturation on rainfall generated landslides in shale along Murree-Kohala road,Pakistan

On August 10, 2010 a series of landslides of more than 90,000 m³ occurred along the Muree-Kohala road in the northern area of Pakistan. A study was undertaken to evaluate the likely impacts of percent saturation and bulk density on mobilized shear strength along the basal rupture surface of the landslide. A series of unconfined compression test and unconsolidated undrained triaxial tests were performed on remolded samples of different densities with varied percentages of saturation. The results of these tests suggest that soil cohesion and friction decreases with increasing saturation. The tests also showed that the shear strength parameters tend to increase with increasing dry density; however, all the samples exhibited a noticeable loss of shear strength with increasing degree of saturation, independent of soil density.Limit equilibrium slope stability analyses were performed along the most probable failure planes, based on shear strength parameters corresponding to degrees of saturation, which varied between 30% to about 100%. This resulted in drop of factor of safety from FS = 1.64 down to 0.51 as the degree of saturation approaches unity.These results suggest that the causative factor in triggering the landslide along Murree-Kohala was the partial saturation of the zone that developed the basal rupture plane. As rain infiltrated the slope, the bulk unit weight of the soil increased, while the shear strength along the developing plane of rupture decreased sufficiently to concentrate shear strain when the material became more than 60% saturation (FS < 1.0).     

Health risk assessment of trace elements in drinking water from Najran City,southwestern Saudi Arabia

The concentrations of 16 trace elements (Ag, Al, As, B, Ba, Cd, Cr, Cu, Hg, Mn, Ni, Pb, Se, Ti, U, and Zn) in drinking water from Najran City, Saudi Arabia, were determined by inductively coupled plasma-mass spectrometry (ICP-MS) and compared with local, regional, and international guidelines. Water samples from 22 water treatment plants and 13 commercial bottled water brands were analyzed. Except for B and U, the trace element concentrations were below the permitted limits defined in SASO, GSO, and WHO drinking water quality guidelines. The B concentrations in three brands of bottled water were 533.19, 602.29, and 1471.96 μg/L, which were all higher than the GSO and SASO limit (500 μg/L). The U concentrations were higher than the SASO limits for drinking water in two samples; one in treatment plant (2.39 μg/L) and another in foreign bottled water (2.17 μg/L). The median As, Ba, Cu, Ni, U, and Zn concentrations were statistically significantly higher in the treatment plant water samples than those in the bottled water samples, and conversely, the B concentrations were higher in the bottled water samples. The Cd, Hg, and Ti concentrations were below the detection limits of ICP-MS in all of the water samples. Apart from few exceptions, trace element concentrations in drinking water of Najran City were all within limits permitted in the national, regional, and international drinking water quality guideline values.     

Local versus regional processes: can soil characteristics overcome climate and fire regimes by modifying vegetation trajectories?

We analysed charcoal and pollen from sediments obtained from two lakes in the northwestern mixed‐wood Canadian boreal forest in order to reconstruct fire‐return intervals and vegetation dynamics over the last 8000 years. Sites were selected with contrasting soil properties (mesic versus dry‐sandy soils), allowing an estimation of the potential influence of soils on long‐term vegetation and fire dynamics. The sites likely experienced fewer fires during the period extending from 8000 to 4000 cal. a BP than over the last 4000 years. At both sites, eastern white pine (Pinus strobus) populations were most extensive shortly after deglaciation, with vegetation later shifting towards mixed woodlands with less P. strobus and more extensive Picea and Pinus banksiana populations. This gradual vegetation shift was probably induced by the establishment of colder and moister conditions along with a fire‐regime change. In spite of the parallel long‐term vegetation trajectories, vegetation composition differed between the two sites in both the past and present. Whereas Picea was more abundant at the mesic site, the fire‐adapted P. banksiana populations were more extensive at the sandy‐soil site. These differences in vegetation composition indicate that, in addition to climate changes and fire occurrence, soil properties also influenced vegetation dynamics. A likely increase in fire frequency in the Canadian boreal forest during the 21st century might therefore favour the expansion of these two disturbance‐adapted trees with spatial heterogeneity in the populations due to varying soil types. Copyright © 2012 John Wiley & Sons, Ltd.     

Interactions of copper, organic acids, and sulfate in goethite suspensions

Sorption of copper and sulfate onto goethite (-FeOOH) in aqueous solution is examined in Cu---SO₄ binary-sorbate systems and in Cu-SO₄-organic acid (either phthalic acid or chelidamic acid) ternary-sorbate systems. Compared to single-sorbate systems, sorption of Cu onto goethite was enhanced at low pH values in the presence of sulfate. Sorption data for Cu and SO₄ in Cu---SO₄ binary-sorbate systems were described with the Generalized Two Layer Model by proposing formation of a Cu---SO₄ ternary surface complex. Addition of sulfate to a Cu-phthalic acid binary sorbate system had little effect on Cu sorption. However, addition of sulfate to Cu-chelidamic acid binary-sorbate systems resulted in significant reduction of Cu sorption at low pH values, primarily due to competition for surface sites between sulfate and Cu-chelidamic acid ternary surface complexes. While organic acids such as humic substances can potentially influence sorption of metal ions, results from this study suggest that the extent of such influence may be strongly dependent on the presence of other sorbing anions, such as sulfate. Sorption of Cu and SO₄ in Cu---SO₄-organic acid ternary-sorbate systems was predicted reasonably well, based on surface reactions and equilibrium constants derived from fitting of sorption data from single- and binary-sorbate systems. These modeling results provide a validation of the extrapolation of sorption from simple systems to multicomponent systems through surface complexation modeling.     

Depositional systems and sequence stratigraphy analysis of the Upper Callovian to Tithonian sediments in the Central and Western Kopet‐Dagh Basin,Northeast Iran

Upper Callovian to Tithonian (late Jurassic) sediments represent an important hydrocarbon reservoir in the Kopet‐Dagh Basin, NE Iran. These deposits consist mainly of limestone, dolostone, and calcareous mudstone with subordinate siliciclastic interbeds. Detailed field surveys, lithofacies and facies analyses at three outcrop sections were used to investigate the depositional environments and sequence stratigraphy of the Middle to Upper Jurassic interval in the central and western areas of the basin. Vertical and lateral facies changes, sedimentary fabrics and structures, and geometry of carbonate bodies resulted in recognition of various carbonate facies related to tidal flats, back‐barrier lagoon, shelf‐margin/shelf‐margin reef, slope and deep‐marine facies belts. These facies were accompanied by interbedded beach and deep marine siliciclastic petrofacies. Field surveys, facies analysis, parasequences stacking patterns, discontinuity surfaces, and geometries coupled with relative depth variation, led to the recognition of six third‐order depositional sequences. The depositional history of the study areas can be divided into two main phases. These indicate platform evolution from a rimmed‐shelf to a carbonate ramp during the late Callovian–Oxfordian and Kimmeridgian–Tithonian intervals, respectively. Significant lateral and vertical facies and thickness changes, and results obtained from regional correlation of the depositional sequences, can be attributed to the combined effect of antecedent topography and differential subsidence related to local tectonics. Moreover, sea‐level changes must be regarded as a major factor during the late Callovian–Tithonian interval. Copyright © 2015 John Wiley & Sons, Ltd.     

GIS-based landslide susceptibility modeling: A comparison between fuzzy multi-criteria and machine learning algorithms

Hazards and disasters have always negative impacts on the way of life.Landslide is an overwhelming natural as well as man-made disaster that causes loss of natural resources and human properties throughout theworld.The present study aimed to assess and compare the prediction efficiency of different models in landslide susceptibility in the Kysuca river basin,Slovakia.In this regard,the fuzzy decision-making trial and evaluation laboratory combining with the analytic network process(FDEMATEL-ANP),Na?ve Bayes(NB)classifier,and random forest(RF)classifier were considered.Initially,a landslide inventory map was produced with 2000 landslide and nonlandslide points by randomly dividedwith a ratio of 70%:30%for training and testing,respectively.The geospatial database for assessing the landslide susceptibility was generated with the help of 16 landslide conditioning factors by allowing for topographical,hydrological,lithological,and land cover factors.The ReliefF methodwas considered for determining the significance of selected conditioning factors and inclusion in the model building.Consequently,the landslide susceptibility maps(LSMs)were generated using the FDEMATEL-ANP,Na?ve Bayes(NB)classifier,and random forest(RF)classifier models.Finally,the area under curve(AUC)and different arithmetic evaluation were used for validating and comparing the results and models.The results revealed that random forest(RF)classifier is a promising and optimum model for landslide susceptibility in the study area with a very high value of area under curve(AUC=0.954),lower value of mean absolute error(MAE=0.1238)and root mean square error(RMSE=0.2555),and higher value of Kappa index(K=0.8435)and overall accuracy(OAC=92.2%).