Upper mantle anisotropy of southeast Arabia passive margin [Gulf of Aden northern conjugate margin], Oman

In this study, we used data recorded by two consecutive passive broadband deployments on the Gulf of Aden northern margin, Dhofar region, Sultanate of Oman. The objective of these deployments is to map the young eastern Gulf of Aden passive continental margin crust and upper mantle structure and rheology. In this study, we use shear-wave splitting analysis to map lateral variations of upper mantle anisotropy beneath the study area. In this study, we found splitting magnitudes to vary between 0.33 and 1.0 s delay times, averaging about 0.6 s for a total of 17 stations from both deployment periods. Results show distinct abrupt lateral anisotropy variation along the study area. Three anisotropy zones are identified: a western zone dominated by NW–SE anisotropy orientations, an eastern zone dominated with NE–SW anisotropy orientations, and central zone with mixed anisotropy orientations similar to the east and west zones. We interpret these shorter wavelength anisotropy zones to possibly represent fossil lithospheric mantle anisotropy. We postulate that the central anisotropy zone may be representing a Proterozoic suture zone that separates two terranes to the east and west of it. The anisotropy zones west and east were being used indicative of different terranes with different upper mantle anisotropy signatures.     

Bed sediment entrainment by streamflow: State of the science

In fluvial sedimentology, bed sediment entrainment by streamflow has a decisive role in controlling several fluvial processes. Owing to its huge practical importance, the subject has been painstakingly explored for over a century. However, a detailed understanding of the mechanism of the bed sediment entrainment phenomenon achieved hitherto is far from complete. The central theme of bed sediment entrainment is occupied by the sediment entrainment threshold, which varies enormously in its qualitative definition, identification and quantification encompassing a broad range of spatiotemporal scales. This article presents the state of the science of the entrainment of non‐cohesive bed sediments under a steady‐unidirectional streamflow. It begins with the diverse definitions and representations of the entrainment threshold criterion from both qualitative and quantitative perspectives, scrutinising its suitability and ambit of applicability. Then, the effects of energetic factors that drive the entrainment threshold criterion are critically appraised. The indispensable mechanisms of bed sediment entrainment, including the theoretical background and modelling strategies, the role of turbulent bursting phenomenon and the phenomenological perspective into the origin of the scaling laws of sediment entrainment, are explained. Throughout the article, special emphasis is given to the strengths and weaknesses of the current state of the science. In addition, a deliberate attempt is made to invoke the thought‐provoking ideas on the multifarious features of bed sediment entrainment. Finally, the innovative perspectives on the bed sediment entrainment are provided and the concluding remarks are made, elucidating the major challenges and suggesting the prospective ways to resolve them as a future scope of research.     

Spectral wheat yield prediction modeling using SPOT satellite imagery and leaf area index

As wheat represents the main staple food and strategic crop in Egypt and worldwide and since remote sensing satellite imagery is the tool to obtain synoptic, multi-temporal, dynamic, and time-efficient information about any target on the Earth, the main objective of the current study is to use remote sensing satellite imagery to generate remotely sensed empirical preharvest wheat yield prediction models. The main input parameters of these models are spectral data either in the form of spectral reflectance data released from Satellite Pour l’Observation de la Terre (SPOT) 4 satellite imagery or in the form of spectral vegetation indices. The other input factor is leaf area index (LAI) that was measured by LAI Plant Canopy Analyzer. The four spectral bands of SPOT4 imagery are green, red, near-infrared, and middle infrared; the five vegetation indices that are forms of ratios between red and near-infrared bands are normalized difference vegetation index, ratio vegetation index, soil-adjusted vegetation index, difference vegetation index, and infrared percentage vegetation index. Another vegetation index is green vegetation index that is calculated through a ratio between green band and near-infrared band. Each of the above-mentioned factors was used as an input factor against wheat yield to generate wheat yield prediction models. All generated models are site-specific limited to the area and the environment and could be applicable under similar conditions in Egypt. The study was carried out in Sakha experimental station by using the dataset from two wheat season 2007/2008 and 2009/2010. The total wheat area was 1.3 ha cultivated by Sakha 93 cultivar. Modeling and validation process were carried out for each season independently. Modeled yield was tested against reported yield through two common statistical tests; the standard error of estimate between modeled yield and reported yield, and the correlation coefficient for a direct regression analysis between modeled and reported yield with each generated model. Generally, as shown from the correlation coefficient of the generated models, green and middle infrared bands did not show good accuracy to predict wheat yield, while the other spectral bands (red and near-infrared) bands showed high accuracy and sufficiency to predict yield. This was proven through the correlation coefficient of the generated models and through the generated models with the wheat crops for the two seasons. Accordingly, the green vegetation index that is generally calculated from green and near-infrared bands showed relatively lower accuracy than the rest of the vegetation index models that are calculated from red and near-infrared bands. LAI showed high accuracy to predict yield as shown from the statistical analysis. The models are applicable after 90 days from sowing stage and applicable in similar regions with the same conditions.     

A new look on the Jurassic formations of the western part of Iraq

The Jurassic succession of western Iraq includes the Ubaid, Hussainiyat, Amij, Muhaiwir, and Najmah formations. Each formation is composed of basal clastic unit overlain by upper carbonate unit. Extensive and huge erosional unconformity occurred at the Triassic–Jurassic boundary due to marked shifting of structural (E–W) strike of the Triassic (Rhaetic) Zor Hauran Formation to (NE–SW) Jurassic formations. Sea level falling (lowstand system tracts) would result in the progradation of the land on the expense of the sea forming the recognizable progradation of the fluvial and deltaic deposits of the lower clastic units of the Jurassic formations, whereas sea level rising (highstand system tract), i.e., sea prograding, causes deposition of the carbonate units of the Jurassic formations system. This progradation resulted to various carbonate environments of deposition ranging from subtidal, intertidal, to supratidal. The main target on most of the exploration blocks in the western part of Iraq focused on the lower Paleozoic successions, whereas prospects in Triassic, Jurassic, and lower Cretaceous targets are less extensive but may have significant potential on certain blocks in both stratigraphic and structural traps. The western part of Iraq was subjected to intermittent pulses of uplifting (sea regression) and subsidence (sea transgression) to form the Jurassic basin system in the area. The Jurassic formations lack the characteristics of petroleum systems. In contrast, in the central and northern parts of Iraq, the Jurassic formations (Najmah and Gotnia formations) were deposited in subsiding basins in which the reservoir and sealed evaporitic rocks existed. In turn, in the western desert of Iraq, the Jurassic formations lack these petroleum system characteristics. Hence, it can be proposed that the petroleum–nonpetroleum inflection could be proposed in the east of area km 160.     

Risk assessment of polycyclic aromatic hydrocarbons in the West Port semi-enclosed basin (Malaysia)

Sediment samples collected from the West Port, the west coastal waters of Malaysia, were analyzed by standard methods to determine the degree of hydrocarbon contamination and identify the sources of polyaromatic hydrocarbons (PAHs). Concentrations of PAHs in the port sediments ranged from 100.3 to 3,446.9 μg/kg dw. The highest concentrations were observed in stations close to the coastline, locations affected by intensive shipping activities and industrial input. These were dominated by high-molecular-weight PAHs (4–6 rings). Source identification showed that PAHs originated mostly pyrogenically, from the combustion of fossil fuels, grass, wood, and coal or from petroleum combustion. Regarding ecological risk estimation, only station 7 was moderately polluted, the rest of the stations suffered rare or slight adverse biological effects with PAH exposure in surface sediment, suggesting that PAHs are not considered as contaminants of concern in the West Port.     

Flood risk perception and its determinants among rural households in two communities in Khyber Pakhtunkhwa,Pakistan

Natural Hazards - Risk perception plays a vital part in flood risk management and mitigation strategies. Therefore, this study aims at first to measure the risk perception of the vulnerable...     

Geochemical Characteristics,Origin, and Evolution of Ore‐Forming Fluids of the Khut Copper Skarn Deposit,West of Yazd in Central Iran

The Khut copper skarn deposit is located at about 50 km northwest of Taft City in Yazd province in the middle part of the Urumieh‐Dokhtar magmatic arc. Intrusion of granitoid of Oligocene–Miocene age into carbonate rocks of the Triassic Nayband Formation led to the formation of marble and a calcic skarn. The marble contains high grade Cu mineralization that occurs mainly as open space filling and replacement. Cu‐rich sulfide samples from the mineralized marble are also anomalous in Au, Zn, and Pb. In contrast, the calcic skarn is only weakly anomalous in Cu and W. The calcic skarn is divided into garnet skarn and garnet–pyroxene skarn zones. Paragenetic relationships and microthermometric data from fluid inclusions in garnet and calcite indicate that the compositional evolution of skarn minerals occurred in three main stages as follows. (i) The early prograde stage, which is characterized by Mg‐rich hedenbergite (Hd_53.7Di_42.3–Hd_86.1Di_9.5) with Al‐bearing andradite (69.8–99.5 mol% andradite). The temperature in the early prograde skarn varies from 400 to 500°C at 500 bar. (ii) The late prograde stage is manifested by almost pure andradite (96.2–98.4 mol% andradite). Based on the fluid inclusion data from garnet, fluid temperature and salinity in this stage is estimated to vary from 267 to 361°C and from 10.1 to 21.1 wt% NaCl equivalent, respectively. Pyrrhotite precipitation started during this stage. (iii) The retrograde stage occurs in an exoskarn, which consists of an assemblage of ferro‐actinolite, quartz, calcite, epidote, chlorite, sphalerite, pyrite, and chalcopyrite that partially replaces earlier mineral assemblages under hydrostatic conditions during fracturing of the early skarn. Fluids in calcite yielded lower temperatures (T < 260°C) and fluid salinity declined to ～8 wt% NaCl equivalent. The last stage mineralization in the deposit is supergene weathering/alteration represented by the formation of iron hydroxide, Cu‐carbonate, clay minerals, and calcite. Sulfur isotope data of chalcopyrite (δ³⁴S of +1.4 to +5.2‰) show an igneous sulfur source. Mineralogy and mineral compositions of the prograde assemblage of the Khut skarn are consistent with deposition under intermediately oxidized and slightly lower fS₂ conditions at shallow crustal levels compared with those of other typical Fe‐bearing Cu–Au skarn systems.     

A probabilistic model to improve reconciliation of estimated and actual grade in open-pit mining

Many of the open-pit mines suffer from the lack of reconciliation between estimated and actual grades. In a mining operation, grade reconciliation is the comparison between the values of the estimated grade calculated in exploration stage and the actual grade obtained from more reliable data such as blast holes?? samples. Many different factors affect the degree of reconciliation in a mining operation. In this paper, the factors related to estimated grade which affect the reconciliation process in the exploration stage of the orebody are investigated. These factors constitute the sources of uncertainty for the upcoming phases of the mining life. Among these parameters, the inherent variability, statistical uncertainty, and systematic uncertainty are the most important factors. In this work, these parameters are studied in further detail, and, accordingly, for each of these uncertainties, a correction factor is determined in the proposed model. The model was applied to the study of real data taken from an iron open-pit mine in Iran. The results of the case study indicated that the systematic uncertainty, inherent variability, and statistical uncertainty are, in order, the main sources of uncertainty on grade reconciliation process. Applying the correction factors to estimated grade values has increased the amount of grade reconciliation from 10%, at original condition, to 50%, at new condition, in the case study.     

Synthesis of biochar from sugarcane filter-cake and its impacts on physiological performance of lettuce (<Emphasis Type="Italic">Lettuce sativa</Emphasis>) grown on cadmium contaminated soil

Soil contamination with cadmium has become major concern all over the world because of its adverse impacts on ecosystem health and agricultural land. Soil amendment with biochar may have varied effects on physical and chemical properties of soil. The objective of the study was to explore the impact of sugarcane filter-cake biochar on physiological performance and growth of lettuce in an aged soil. Four different doses (0, 1.5%, 3%, and 5%) of biochar were used in the soil and conditioned for 1 month. After this, lettuce seedlings were grown in the soil. The results showed that the biochar treatment improved the fresh and dry biomass of leaves and roots as well as plant height while diminished the bioavailability of cadmium from the soil. As compared to control, biochar significantly enhanced the chlorophyll content in lettuce leaves. Due to the biochar amendment, the oxidative stress decreased in lettuce shoots over the control. As compared to control, concentration of cadmium in lettuce significantly decreased after the application of biochar. It was concluded that biochar could mitigate the toxicity of cadmium in lettuce by altering the biochemical and physiological processes in cadmium contaminated soil.     

Impact of drilling mud on chemistry and microbiology of an Upper Triassic groundwater after drilling and testing an exploration well for aquifer thermal energy storage in Berlin (Germany)

After completion of an exploration well, sandstones of the Exter Formation were hydraulically tested to determine the hydraulic properties and to evaluate chemical and microbial processes caused by drilling and water production. The aim was to determine the suitability of the formation as a reservoir for aquifer thermal energy storage. The tests revealed a hydraulic conductivity of 1–2 E-5 m/s of the reservoir, resulting in a productivity index of 0.6–1 m³/h/bar. A hydraulic connection of the Exter Formation to the overlaying, artesian “Rupelbasissand” cannot be excluded. Water samples were collected for chemical and microbiological analyses. The water was similarly composed as sea water with a maximum salinity of 24.9 g/L, dominated by NaCl (15.6 g/L Cl and 7.8 g/L Na). Until the end of the tests, the water was affected by drilling mud as indicated by the high pH (8.9) and high bicarbonate concentration (359 mg/L) that both resulted from the impact of sodium carbonate (Na₂CO₃) additives. The high amount of dissolved organic matter (>?58 mg/L) and its molecular-weight distribution pattern indicated that residues of cellulose, an ingredient of the drilling mud, were still present at the end of the tests. Clear evidence of this contamination gave the measured uranine that was added as a tracer into the drilling mud. During fluid production, the microbial community structure and abundance changed and correlated with the content of drilling mud. Eight taxa of sulfate-reducing bacteria, key organisms in processes like bio-corrosion and bio-clogging, were identified. It can be assumed that their activity will be affected during usage of the reservoir.