Performance and environmental impact of a turbojet engine fueled by blends of biodiesels

Depletion of conventional fuels, concerns about environmental pollution and the tightening of exhaust emission legislations are the main reasons for increasing research on alternative fuels produced from agricultural feedstock. In this study, biodiesel fuels produced from cotton and corn vegetable oils are investigated as renewable fuels for a gas turbine engine for aviation. The biodiesel fuels are defined as cotton methyl ester (CTME) and corn methyl ester. The performance characteristics and exhaust emissions of the gas turbine engine are investigated when the engine fueled with three blends of 10%(B10), 20%(B20) and 50%(B50) of biodiesel/JetA-1 by volume. The biodiesel fuels were produced using transesterification process and characterized according to ASTM biodiesel specifications. Chemical and physical properties show a real potential of using biodiesel blends as an alternative for JetA-1. The measured engine performance parameters and exhaust emissions are compared with that of pure JetA-1 over a range of throttle setting. The gas turbine engine used in this study is equipped with pressure, flow, temperature, thrust and speed sensors that connected to data acquisition system and control unit in addition to exhaust gas analyzer. The experimental results show that biodiesel fuels can be used up to blend of 50% with JetA-1 in gas turbine engines with slight enhancement in engine performance and significant improvements in exhaust emissions. The engine static thrust is increased with 2% for B50 at lower and medium engine speeds and decreased with 11% at high engine speed compared to conventional JetA-1 fuel. The thrust-specific fuel consumption for biodiesel blends is lower than that for regular JetA-1 fuel. The gas turbine engine efficiency is increased for biodiesel blends by 14% compared to JetA-1, and this is reported for CTME B50. For oxygen concentration in exhaust gases emissions, the higher the biodiesel blend, the higher the O₂ concentration in the exhaust compared with JetA-1 fuel. The O₂ level increased by 6% for biodiesel blend of B50 compared to JetA-1 fuel. The emissions of CO and HC emissions decreased by 5 and 37%, respectively, compared with conventional JetA-1. Additionally, the biodiesel blends achieve a higher CO₂ and NO_x emissions with 11 and 27%, respectively, compared to JetA-1. The sulfur dioxide SO₂ decreased by 75% compared to the regular JetA-1 fuel.     

Organic Material and Trace Elements of Bituminous Rocks in the Ozankiiy Field, Ankara, Turkey

Bituminous rocks in the Ozankoey （Ankara） field are different from those of the Paleocene- Eocene Mengen and Giineytepe （Bolu） regions in metal enrichment levels. Organic carbon （Corg） content of organic material-rich rocks in the Ozankoey （Ankara） field is 3.66-40.72% wt averaging 14.34%. The dominant organic materials are algae/amorphous accompanied by minor amount of herbaceous material （The dominant kerogen type is Type-I with a limited amount of Type-Ⅱ kerogen.）. The bituminous rocks in the Ozankoey field are enriched in heavy metals such as Ni, Mn, As and Cr. In comparison with the average enrichment values of dements, Ni, Mn, As and Cr in bituminous shales of the Ozankoey field are as about 4.38, 14.93, 10.90 and 5.58 times as average values. The average concentrations of these heavy metals are also as high as 215× 10^-6, 828 × 10^-6, 58.54 × 10^-6, and 148 × 10^-6 respectively. In addition, sorption properties of day and organic materials are also important for metal enrichments in the bituminous shales.     

Interfacial instability of sand patterns induced by turbulent shear flow

When a turbulent shear flow above a plane sand surface entrains sand grains,it generates a variety of sand patterns.Fluvial sand forms two major interfacial patterns:meso-scale dunes and antidunes,and large-scale bars.Measurements have evidenced that under erosive conditions,meso-scale patterns either change to or coexist with large-scale patterns.However,it remains elusive what exactly drives the switching of interfacial patterns and how the switching occurs.Here,we showdcombing a flow model with a grain transport model,allowing for both the surface and suspended sand fluxes dthat the switching of patterns emerges from the shear-driven complex feedback between grain transport and topographic perturbations.The switching predominantly depends on the magnitudes of the Rouse number and the grain size to undisturbed flow depth ratio.The model offers quantitative predictions of the maximum amplification of sand patterns and unveils a new attraction erepulsion phenomenon.     

Sediment settling in the Latian Dam in Iran

Among the difficulties that influence future dam operations,reservoir sedimentation is the most problematic for engineers.This study predicted the amount and pattern of sedimentation for use in estimation of the useful lifespan of reservoirs and identification of optimal locations for outlets and intakes at the initial stages of dam design.Hydrographic surveys of different dams can provide better insight into this phenomenon.Latian Dam in Iran has conducted hydrographic surveys during 7 time periods.The amount and process of sedimentation in this reservoir were determined,and predictions of distribution of sediments were validated by well-known,common methods.The formation of a delta in the reservoir was investigated for different time periods after operation.Future problems due to the impacts of sedimentation on dam operation and the useful lifespan of the reservoir were predicted.In addition,the study results may be used for developing empirical methods to predict sedimentation patterns in other reservoirs.     

The added value of joint PP–PS inversion for reservoir characterization: A case study using Jubarte PRM seismic data (offshore Brazil)

The added value of the joint pre-stack inversion of PP (incident P-wave and reflected P-wave) and PS (incident P-wave and reflected S-wave) seismic data for the time-lapse application is shown. We focus on the application of this technique to the time-lapse (four-dimensional) multicomponent Jubarte field permanent reservoir monitoring seismic data. The joint inversion results are less sensitive to noise in the input data and show a better match with the rock physics models calibrated for the field. Further, joint inversion improves S-impedance estimates and provides a more robust quantitative interpretation, allowing enhanced differentiation between pore pressure and fluid saturation changes, which will be extremely useful for reservoir management. Small changes in reservoir properties are expected in the short time between the time-lapse seismic acquisitions used in the Jubarte project (only 1 year apart). The attempt to recover subtle fourth-dimensional effects via elastic inversion is recurrent in reservoir characterization projects, either due to the small sensitivity of the reservoirs to fluid and pressure changes or the short interval between the acquisitions. Therefore, looking for methodologies that minimize the uncertainty of fourth-dimensional inversion outputs is of fundamental importance. Here, we also show the differences between PP only and joint PP–PS inversion workflows and parameterizations that can be applied in other projects. We show the impact of using multicomponent data as input for elastic seismic inversions in the analysis of the time-lapse differences of the elastic properties. The larger investment in the acquisition and processing of multicomponent seismic data is shown to be justified by the improved results from the fourth-dimensional joint inversion.     

Link between SSZ ophiolite formation, emplacement and arc inception, Northland, New Zealand: U–Pb SHRIMP constraints; Cenozoic SW Pacific tectonic implications

New U–Pb age-data from zircons separated from a Northland ophiolite gabbro yield a mean ²⁰⁶Pb/²³⁸U age of 31.6 ± 0.2 Ma, providing support for a recently determined 28.3 ± 0.2 Ma SHRIMP age of an associated plagiogranite and  29–26 Ma ⁴⁰Ar/³⁹Ar ages (n = 9) of basalts of the ophiolite. Elsewhere, Miocene arc-related calc-alkaline andesite dikes which intrude the ophiolitic rocks contain zircons which yield mean ²⁰⁶Pb/²³⁸U ages of 20.1 ± 0.2 and 19.8 ± 0.2 Ma. The ophiolite gabbro and the andesites both contain rare inherited zircons ranging from 122–104 Ma. The Early Cretaceous zircons in the arc andesites are interpreted as xenocrysts from the Mt. Camel basement terrane through which magmas of the Northland Miocene arc lavas erupted. The inherited zircons in the ophiolite gabbros suggest that a small fraction of this basement was introduced into the suboceanic mantle by subduction and mixed with mantle melts during ophiolite formation.

We postulate that the tholeiitic suite of the ophiolite represents the crustal segment of SSZ lithosphere (SSZL) generated in the southern South Fiji Basin (SFB) at a northeast-dipping subduction zone that was initiated at about 35 Ma. The subduction zone nucleated along a pre-existing transform boundary separating circa 45–20 Ma oceanic lithosphere to the north and west of the Northland Peninsula from nascent back arc basin lithosphere of the SFB. Construction of the SSZL propagated southward along the transform boundary as the SFB continued to unzip to the southeast. After subduction of a large portion of oceanic lithosphere by about 26 Ma and collision of the SSZL with New Zealand, compression between the Australian Plate and the Pacific Plate was taken up along a new southwest-dipping subduction zone behind the SSZL. Renewed volcanism began in the oceanic forearc at 25 Ma producing boninitic-like, SSZ and within-plate alkalic and calc-alkaline rocks. Rocks of these types temporally overlap ophiolite emplacement and subsequent Miocene continental arc construction.     

Factors affecting seasonal patterns in epilimnion zooplankton community in one of the largest man-made lakes in Africa (Lake Nasser, Egypt)

The objective of the study was to determine which factors regulate zooplankton organisms along Lake Nasser. Temperature, pH, DO, conductivity, turbidity, nutrients, and zooplankton abundance were measured. Twenty-three species of zooplankton were recorded in Lake Nasser included in Copepoda, Cladocera and Rotifera. Copepoda represented the main bulk of the community. The lowest standing stock of zooplankton was noticed during spring due to the highest fish predation during this season associated with the lowest turbidity. Big difference in temperature in Lake Nasser along the year round is considered as a controlling factor related to range of tolerance of species. The oscillation of the lake water level and the different factors affect the standing stock of zooplankton in the lake. Thus, continuous monitoring of Lake Nasser biota should be undertaken to follow the changes in the ecosystem.     

Optimization of a Photo‐assisted Fenton Oxidation Process: A Statistical Model for MDF Effluent Treatment

In the present study, the effects of initial COD (chemical oxygen demand), initial pH, Fe²⁺/H₂O₂ molar ratio and UV contact time on COD removal from medium density fiberboard (MDF) wastewater using photo‐assisted Fenton oxidation treatment were investigated. In order to optimize the removal efficiency, batch operations were carried out. The influence of the aforementioned parameters on COD removal efficiency was studied using response surface methodology (RSM). The optimal conditions for maximum COD removal efficiency from MDF wastewater under experimental conditions were obtained at initial COD of 4000 mg/L, Fe²⁺/H₂O₂ molar ratio of 0.11, initial solution pH of 6.5 and UV contact time of 70 min. The obtained results for maximum COD removal efficiency of 96% revealed that photo‐assisted Fenton oxidation is very effective for treating MDF wastewater.     

Use of Chemotaxonomy To Study the Influence of Benzalkonium Chloride on Bacterial Populations in Biodegradation Testing

Contradictory results are reported for the behaviour of quaternary ammonium compounds (QACs) in sewage treatment plants (STPs). QACs may sorb onto activated sludge. Only little information is available with respect to effects of QACs against bacteria in STPs. Only 5 to 15 % of bacteria present in sewage sludge can be detected by means of culture dependent microbiological methods. The shift of the bacterial populations due to effects of test compounds have not been studied up to now with culture independent methods. The microbial populations shift was studied in situ using culture independent chemotaxonomy profiling ubiquinones and polyamines. Additionally, toxic effects of QACs against bacteria present in the test vessels of the Zahn‐Wellens test (OECD 302 B) were assessed with a toxicity control in the test. The ubiquinone profiles representing changes in Gram‐negative populations mainly showed that the activated sludge was affected only in test vessels containing benzalkonium chloride. According to chemotaxonomy Acinetobacter or/and some members of Pseudomonas spp. have been selected by benzalkonium chloride after some adaptation period (8 to 12 days).