Diagnosis of trace metal contamination in sediments: the example of Ensenada and El Sauzal, two harbors in Baja California, Mexico

Total metal concentrations in sediments from within Ensenada and El Sauzal Harbors are generally higher than at the mouths. Grain-size analyses suggested that this enrichment could be due to the presence of fine-grained sediments in the inner part of the harbors rather than to anthropogenic perturbations. The (Me/Al)(sample) ratios for Pb, Co, Ni and Fe were significantly higher for Ensenada Harbor relative to El Sauzal Harbor, whereas the ratios for Cd, Mn, Zn and Cu were statistically equivalent for both harbors. Calculated enrichment factors [EF(Me)=(Me/Al)(sample)/(Me/Al)(shale)] indicated that the metals showing slight enrichment were those associated with anthropogenic contamination (Pb, Zn), or probably related to primary productivity in the water column (Cd, Co). The levels of most of the metals were not greatly enriched, a consideration that is of the utmost importance when contamination issues are at stake.     

Separate and interactive effects of eutrophication and climate variables on the ecosystem elements of the Gulf of Riga

There is currently a critical knowledge gap in how eutrophication and climate variables separately and interactively impact the dynamics of marine ecosystems. Based on long-term monitoring data we quantified the separate and combined impacts of nutrient loading, temperature, salinity, and wind conditions on zooplankton, zoobenthos and fish inhabiting a brackish water ecosystem in the Gulf of Riga. Changes in zoobenthos communities and herring stock were largely explained by climate variables. Zooplankton species were related to both eutrophication and climate variables, and models combining all environmental variables explained additional variation in zooplankton data compared to the separate models of climate and eutrophication. This suggests that zoobenthos communities and herring stock are largely driven by weather conditions, whereas the combined effect of weather and nutrient loads are likely the cause for dynamic zooplankton communities in the Gulf of Riga.     

Energy balance and evaporation loss of an agricultural reservoir in a semi‐arid climate (south‐eastern Spain)

A typical agricultural water reservoir (AWR) of 2400 m² area and 5 m depth, located in a semi‐arid area (southern Spain), was surveyed on a daily basis for 1 year. The annual evaporation flux was 102·7 W m^?2, equivalent to an evaporated water depth of 1310 mm year^?1. The heat storage rate G exhibited a clear annual cycle with a peak gain in April (G ～ 45 W m^?2) and a peak loss in November (G ～ 40 W m^?2), leading to a marked annual hysteretic trend when evaporation (λE) was related to net radiation (R_n). λE was strongly correlated with the available energy A, representing 91% of the annual AWR energy loss. The sensible heat flux H accounted for the remaining 9%, leading to an annual Bowen ratio in the order of 0·10. The equilibrium and advective evaporation terms of the Penman formula represented 76 and 24%, respectively, of the total evaporation, corresponding to a annual value of the Priestley–Taylor (P–T) coefficient (α) of 1·32. The P–T coefficient presented a clear seasonal pattern, with a minimum of 1·23 (July) and a maximum of 1·65 (December), indicating that, during periods of limited available energy, AWR evaporation increased above the potential evaporation as a result of the advection process. Overall, the results stressed that accurate prediction of monthly evaporation by means of the P–T formula requires accounting for both the annual cycle of storage and the advective component. Some alternative approaches to estimating R_n, G and α are proposed and discussed. Copyright © 2009 John Wiley & Sons, Ltd.     

Some elements of mathematical information theory and total inversion algorithm applied to travel time inversion

The total inversion algorithm and some elements of Mathematical Information Theory are used in the treatment of travel-time data belonging to a seismic refraction experiment from the southern segment (Sardinia Channel) of the European Geotraverse Project. The inversion algorithm allows us to improve a preliminary propagating model obtained by means of usual trial and error procedure and to quantify the resolution degree of parameters defining the crust and upper mantle of such a model. Concepts related to Mathematical Information Theory detect some seismic profiles of the refraction experiment which give the most homogeneous coverage of the model in terms of number of trajectories crossing it. Finally, the efficiency of the inversion procedure is quantified and the uncertainties regarding knowledge of different parts of the model are also evaluated.     

A Parametric Approach for Dealing with Compositional Rounded Zeros

In this work, a parametric approach for replacing data below the detection limit, also known as rounded zeros, in compositional data sets is proposed. Compositional rounded zeros correspond to small proportions of some whole that cannot be reliably detected by the analytical instruments under given operating conditions. This kind of zeros appear frequently in the data collection process in geosciences. They must be treated in an adequate way before some multivariate analysis can be applied. Our procedure results from a modification of the Expectation-Maximization (EM) algorithm and is based on the additive log-ratio transformation. Its coherence with the nature of compositional data and with basic operations in the simplex sample space is checked. Using real data sets, we find that this approach improves other parametric and non-parametric techniques for compositional rounded zeros.     

Heavy metals pollution of aquatic ecosystems in the vicinity of a recently closed underground lead-zinc mine (Basque Country, Spain)

A presentation is made of the study of an underground polymetallic sulphide mine and the pollution caused by this in the adjoining aquatic ecosystems. Troya Mine is in the Basque Cantabrian region (northern Spain). The annual production of the ore deposit of over 3.7 million tons of Pb (0.9%), Zn (11.2%) and Cu (0.2%) was 300,000 t. It was open and producing from 1986-1993. The mineralization was made up of pyrite, marcasite, sphalerite, galena, chalcopyrite and arsenopyrite. Only the Zn and the Pb were mined. We studied the distribution and behaviour of the heavy metals Zn, Pb, Fe, Mn, Cu, Cr and Cd in the water column, dissolved and suspended fractions, and in the sediments of Estanda Stream and of Gezala Creek. Zn, Cd and Mn tend to be found in the water; Fe, Pb, Cu and Cr appear as an adsorbed fractionin the solid phases. Those of the second group are significantly linked to the fluvial sediments and present very high levels. The concentrations of the metals are conditioned by the waters from the mine galleries, by the leached waste, by the surface runoff, and by overflow from the spillway of the tailings pond. Our observations provide knowledge on the extent of the polluting power of the metals, the physico-chemical effects in play and the subsequent chances of recovering these highly affected environments.     

Groundwater contamination: risk management and assessment for landfills in Mar del Plata, Argentina

 This study presents a program for risk management in the contamination of groundwater resulting from leachate in landfills at Mar del Plata (Argentina). The program includes prediction, prevention, monitory observation and mitigation as actions that must be taken prior to, during, and after contamination occurs. This routine aids in the identification of weak points and failures of the program for those who are in charge of making decisions, and will allow better use of limited financial and technical resources based on planning, thus minimizing disconnected determinations. Results of the prediction stage were confirmed through monitoring. The presence of a plume of contamination more than 100 m from the landfill was shown, thus proving that implementation of a monitoring plan to follow the development of the contaminated plume must be implemented, particularly in populated areas which depend on residential wells for their water supply. Received: 8 May 2000 · Accepted: 14 August 2000     

The Middle Jurassic radiolarites and pelagic limestones of the Nieves unit (Rondaide Complex, Betic Cordillera): basin starvation in a rifted marginal slope of the western Tethys

Middle Jurassic radiolarites and associated pelagic limestones occur in the Rondaide Nieves unit of the Betic Cordillera, southern Spain. The Rondaide Mesozoic includes: (a) a thick succession of Triassic platform carbonates, comparable to the Alpine Hauptdolomit and Kössen facies; (b) Lower Jurassic pelagic limestones comparable to the Alpine Hierlatz and Adnet facies; (c) the Middle Jurassic Parauta Radiolarite Formation, described herein; and (d) a thin Upper Jurassic-Cretaceous condensed limestone succession. The Parauta Radiolarite Formation and associated limestones were studied with respect to stratigraphy, petrography, micropalaeontology (radiolarians, calcareous nanno- and microfossils) and facies. Radiolarite sedimentation occurred in the Middle Bathonian in a restricted and dysoxic deep Nieves basin, perched in the distal zone of a continental margin fringing the Tethyan ocean. This margin was adjacent to a young narrow oceanic basin between the South-Iberian margin and a continental block called Mesomediterranean Terrane. The Nieves basin was part of a marine corridor between the Proto-Atlantic and Piedmont-Ligurian basins of the Alpine Tethys. The regional tectonic position, the stratigraphical evolution since the Triassic, the age and the nature of the Mesozoic facies and the palaeogeographic relations to adjacent domains show striking analogies between the Betic Rondaide margin and coeval units of the Alps.