Non‐subduction origin for 3.2 Ga high‐pressure metamorphic rocks in the Barberton granitoid‐greenstone terrane,South Africa

The occurrence of high‐pressure (HP) garnet‐bearing metamorphic rocks in the southern Barberton granitoid–greenstone terrane (BGGT), South Africa, has been proposed as a key indicator of the onset of modern plate tectonics at ca. 3.2 Ga. Here, we report new zircon/titanite U–Pb ages of garnet‐bearing HP metamorphic rocks and associated granitoids in the BGGT that argue against such an interpretation. The results show that HP metamorphism occurred synchronously with granitoid magmatism in the Stolzburg domain, the supposed subducted plate, during two episodes at 3.4 and 3.2 Ga, and that these two episodes of magmatism occurred on both sides of the assumed suture zone, a feature that cannot easily be explained by the subduction model. In contrast, the coupled magmatism and metamorphism probably resulted from partial convective overturn (PCO), another viable mechanism for production and differentiation of continental crust during early Archean.     

An assessment of evidence for pingos on Mars using HiRISE

Pingos are small hills with cores of ice, formed by injection and freezing of pressurized water. The possibility of pingos on Mars is of particular interest because of the associated implications for liquid water. We have systematically searched for candidate pingos using images from the High Resolution Imaging Science Experiment (HiRISE) camera. Since pingos are expected to develop surface fractures due to extension of the frozen ground over the ice core, we have searched for fractured features and identified a variety of mounds. These features are confined to the martian mid-latitudes, in the bands where gullies are also most common. The observed fractured mounds have a variety of morphologies and are likely of multiple origins. Isolated fractured mounds found on the floors of gullied craters in the southern hemisphere match the general morphologic characteristics of terrestrial pingos and are the best candidates for martian pingos, but there is currently no direct evidence for presence of ice cores and it is difficult to produce the necessary water volumes, so these features should still be interpreted with caution. Other fractured mounds appear more likely to be erosional remnants of an unusual mantling layer or possibly thermokarst structures. Flat-topped mounds in Utopia have some characteristics (fracture pattern and latitudinal distribution) consistent with pingos but differ in other aspects such as shape and setting. While we do not rule out a pingo origin, we prefer an erosional model for these enigmatic features.     

A shallow subsurface controlled release facility in Bozeman, Montana, USA, for testing near surface CO2 detection techniques and transport models

A controlled field pilot has been developed in Bozeman, Montana, USA, to study near surface CO₂ transport and detection technologies. A slotted horizontal well divided into six zones was installed in the shallow subsurface. The scale and CO₂ release rates were chosen to be relevant to developing monitoring strategies for geological carbon storage. The field site was characterized before injection, and CO₂ transport and concentrations in saturated soil and the vadose zone were modeled. Controlled releases of CO₂ from the horizontal well were performed in the summers of 2007 and 2008, and collaborators from six national labs, three universities, and the U.S. Geological Survey investigated movement of CO₂ through the soil, water, plants, and air with a wide range of near surface detection techniques. An overview of these results will be presented.     

Spatial heterogeneity and temporal stability of throughfall under individual Quercus brantii trees

Spatio‐temporal patterns of throughfall (TF) have often been studied under forest canopies. Few reports, however, have been made on small‐scale TF variability in deciduous forest stands. In the present research, the spatial heterogeneity and temporal stability of TF under five individual persian oak trees (Quercus brantii var. Persica) was quantified. The research site was in the Zagros forests in western Iran, where mean annual precipitation and temperature are equal to 587.2 mm and 16.9 °C, respectively. Data from 23 rainfall events were aggregated to assess the spatial correlation of TF. Variograms for TF beneath two of the five trees reached a stable sill at the range of 5–6 m. The redistribution of TF within the canopy was highly variable in time, attributable to seasonal variation in canopy foliation and meteorological factors. As the length of the sampling period increased, the spatial variability of TF decreased and the temporal stability of the TF pattern increased. Time stability plots of TF normalized with respect to mean and variance showed a moderate general persistence for all individual trees. We conclude that single trees modify the spatial distribution of TF reaching the forest floors. Copyright © 2012 John Wiley & Sons, Ltd.     

Investigating the effectiveness of the surfactant dioctyl sodium sulfosuccinate to disperse oil in a changing marine environment

We investigated the surfactant dioctyl sodium sulfosuccinate (DOSS) and its delivery system Corexit 9500A, used to disperse oil released during the Gulf of Mexico spill during the summer of 2010. DOSS is an organic sulfonic acid salt that acts as a synthetic detergent and disrupts the interfacial tension between the salt water and crude oil phases. The disruption reaches a maximum at or above the critical micelle concentration (CMC). The CMC for the surfactant was determined to be 0.17% solution in deionized water at a pH of 7.2 and a temperature of 21.1 °C (70°F). The CMC is lower in salt water, at 0.125% solution. This has been identified as a “salting out” effect (Somasundaran, 2006). The CMC of DOSS in both saline and deionized water occurred at lower-percent solutions at higher temperatures. The surface tension versus concentration plots can be modeled using a power equation, with correlation coefficients consistently over 0.94. Surface tension versus concentration plots are scalable to fit the desired temperature by the function f(x) = (1/1+X^α), where α =T₁/T₂. Tests measured the stability of the DOSS micelles when exposed to a continuous UVA radiation. This photodegradation is directly related to the duration of exposure.     

Age and Origin of Paleogene Granitoids from Western Yunnan Province, China: Geochemistry, SHRIMP Zircon Ages, and Hf-in-Zircon Isotopic Compositions

We report geochemical data, SHRIMP zircon ages and Hf-in-zircon isotopic compositions for Cenozoic granitoids from major fault systems in the Tethyan belt in western Yunnan Province, southwestern China.Four magmatic pulses occurred in the Paleogene, namely at ca.57 Ma, ca.50 Ma, 45–40 Ma, and 38–34 Ma.Early magmatism of this episode(57–50 Ma) produced S-type granites whose zircons yielded εHf(t) values of-5.0 to-0.3.In contrast, late magmatism of this episode reflects heterogeneous sources.Zircons from a granite porphyry along the Ailaoshan-Red River fault system have slightly positive εHf(t) values suggesting derivation from relatively young crust and/or a juvenile source.However, zircons from a granite along the Gaoligong fault system have strongly negative εHf(t) values and suggest derivation from a Paleoproterozoic crustal source.The composition of the granitoids varies with age(from ca.57 Ma to ca.34 Ma) from peraluminous to metaluminous and also suggests a change from syn-collisional to late-orogenic tectonic setting.A new tectonic model, impacting lithospheric wedge(ILW) is shown for the origin of Paleogene granitoids in this paper.