Melt inclusions and crystal-liquid separation in rhyolitic magma of the Bishop Tuff

Melt inclusions in quartz phenocrysts from a single clast of pumice near the base of the plinian pumice fall of the Bishop Tuff were studied to test ideas concerning separation of melt and crystals in silicic magmas. Ten analyzed inclusions from the pumice clast are of high silica rhyolite composition with very low contents of the highly compatible elements Ba, Sr, and Eu, consistent with extensive fractionation. The concentrations of U, La, Ce, Mg, and Ca of these ten melt inclusions vary considerably as determined by ion microprobe. Petrologic considerations indicate that uranium is an incompatible element with a maximum bulk partition coefficient D of about 0.2 and that the evolution of the uranium content of the melt was controlled by crystallization of the magma. A minimum of 33 wt% perfect fractional crystallization is required to explain the observed range in uranium. However, only 17 wt% crystals occurred in the pumice clast. The greater calculated fraction of crystals requires significant separation of crystals and melt before the eruption of the plinian pumice fall in spite of the fact that crystal mixing (settling, etc.) did not occur in the Bishop magma.     

Multiphase chemistry and acidity of clouds at Kleiner Feldberg

The chemistry of cloud multiphase systems was studied within the Kleiner Feldberg Cloud Experiment 1990. The clouds encountered during this experimental campaign could be divided into two categories according to the origin of air masses in which the clouds formed. From the chemical point of view, clouds passing the sampling site during the first period of the campaign (26 October-4 November) were characterized by lower pollutant loading and higher pH, as compared to clouds during the final period of the experimental campaign (10–13 November). The study of multiphase partitioning of the main chemical constituents of the cloud systems and of atmospheric acidity within the multiphase systems themselves (gas + interstitial aerosol + liquid droplets) are presented in this paper. A general lack of gaseous NH₃ was found in these cloud systems, which caused a lack of buffer capacity toward acid addition. Evidence supports the hypothesis that the higher acidity of the cloud systems during this final period of the campaign was due to input of HNO₃. Our measurements, however, could not determine whether the observed input was due to scavenging of gaseous HNO₃ from the air feeding into the cloud, or to heterogeneous HNO₃ formation via NO₂ oxidation by O₃ to NO₃ and N₂O₅. Sulfate in cloud droplets mainly originated from aerosol SO ₄ ^2– scavenging, since S(IV) to S(VI) liquid phase conversion was inhibited due to both lack of H₂O₂ and low pH of cloud droplets, which made O₃ and metal catalyzed S(IV) oxidation inefficient.     

An examination of internally generated variability in long climate simulations

General circulation model experiments designed to estimate the magnitude and structure of internally generated variability and to help understand the mechanisms underlying this variability are described. The experiments consist of three multi-century integrations of a rhomboidal 15, 9 level, version of the Center for Ocean-Land-Atmosphere Studies atmospheric general circulation model: a run with fixed sea surface temperatures and equinox solar radiation, a run with seasonally varying climatological sea surface temperatures and seasonally varying solar forcing, and a run with seasonally varying solar forcing in which the state of the ocean is predicted by a 3° by 3°, 16 vertical level, nearly global domain version of the Geophysical Fluid Dynamics Laboratory Modular Ocean Model. No flux correction is used in the coupled model integration. Selected surface fields of the three runs are compared to each other as well as to the observed climate. Statistical properties of variability on interannual time scales are compared between the runs. Evidence is presented that climate time scale variability in the simulations is produced by random weather time scale forcing due to the integrating effect of elements of the system with long memories. The importance of ocean variability for land climate variability is demonstrated and attributed to both the memory effect and coupled atmosphere-ocean instability.     

Editorial

The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

A harmonic analysis of lunar topography

A global lunar topographic map has been derived from existing Earth-based and orbital observations supplemented in areas without data by a linear autocovariance predictor. Of 2592 bins, each 5° square, 1380 (64.7% by area) contain at least one measurement. A spherical harmonic analysis to degree 12 yields a mean radius of 1737.53 ± 0.03 km (formal standard error) and an offset of the center of figure of 1.98±0.06 km toward (19±2)°S, (194±1)°E. A Bouguer gravity map, derived from a 12-degree free-air gravity model and the present topography data, is presented for an elevation of 100 km above the mean surface. It is confirmed that the low-degree gravity harmonics are determined primarily by surface height variations and only secondarily by lateral density variations.     

On the hemispheric correlations of vertical and meridional wind components

Summary Using the values of vertical velocities computed byJensen (1960) and the values of the meridional component of the wind for the months of January and April 1958, the covariances of both quantities were evaluated at different levels at various latitudes. These covariances are tabulated and the terms associated with transient eddies are compared to the standing eddy terms, the relative magnitudes of both contributions being finally investigated.

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Résumé En employant les valeurs du mouvement vertical calculées parJensen (1960) et les valeurs des composantes méridionales des vents pour les mois de Janvier et Avril 1958, les covariances des deux quantités ont été evaluées aux différents niveaux dans différentes latitudes. Ces covariances sont tabulées et les valeurs associées aux perturbations transientes et stationnaires sont comparées afin de donner un aperçu sur l'importance relative des deux procès.