An improved lunar moment of inertia determination: a proposed strategy

The current error of 0.0025 on the lunar homogeneity parameterI/MR ² is dominated by the uncertainties in theC ₂₀ andC ₂₂ gravity harmonics. This error level is equivalent to a 4.20 gm cm^–3 density uncertainty for a lunar interior model having a core 300 km in radius. Covariance analyses are performed using Doppler data from the relay satellite of the proposed Lunar Polar Orbiter mission to determine an optimum reduction strategy which obtains an order of magnitude improvement in the gravity estimates. Error studies show the long-arc reduction method obtains results which are an order of magnitude more accurate than the short-arc technique. The nominal 4000 km circular orbit of the relay satellite is very sensitive to the unmodeled effects of gravity harmonics of degree 5 through 9. Results from this orbital geometry indicate that it may not be possible to achieve the desired order of magnitude accuracy improvement. A modified orbit having the identical orbital conditions as the nominal one, but with a larger semi-major axis of 7000 km is studied. Results show the desired order of magnitude improvement can be achieved when a complete fourth degree and order model and some fifth and sixth degree terms are estimated while considering the unmodeled effects of the remaining harmonics through degree and order eight. Studies also show a 50% additional improvement inC ₂₂ can be achieved if differential differenced Doppler is also processed with the direct Doppler. The improved uncertainty inI/MR ² reduces the core density error from 4.20 gm cm^–3 to 0.1 gm cm^–3 for the case of a lunar density model having a 300 km core radius.Contribution #2885 of the Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, U.S.A.     

Glassy orthopyroxene granodiorites of the Pannonian Basin: tracers of ultra-high-temperature deep-crustal anatexis triggered by Tertiary basaltic volcanism

Glassy orthopyroxene granodiorite-tonalite (named pincinite after type locality) was described from basaltic lapilli tuffs of the Pliocene maar near Pinciná village in the Slovakian part of the Pannonian Basin. Two pincinite types exhibit a qualitatively similar mineral composition (quartz, An_20–55 plagioclase, intergranular silicic glass with orthopyroxene and ilmenite, ±K-feldspar), but strongly different redox potential and formation PT conditions. Peraluminous pincinite is reduced (6–7% of total iron as Fe³⁺ in corundum-normative intergranular dacitic glass) and contains ilmenite with 8–10 mol% Fe₂O₃ and orthopyroxene dominated by ferrosilite. High-density (up to 0.85 g/cm³) primary CO₂ inclusions with minor H₂, CH₄, H₂S, CO and N₂ (<2 mol% total) are present in Qtz and Plg. Equilibrium PT conditions inferred from the intergranular Opx–Ilm–Glass assemblage and fluid density correspond to 1,170±50°C, 5.6±0.4 kbar, respectively. Metaluminous pincinite is more oxidised (25–27% of total iron as Fe³⁺ in diopside-normative intergranular glass of rhyolite–trachyte–dacite composition) and contains Fe₂O₃-rich ilmenite (17–29 mol%) associated with enstatite. Fluid inclusions are composed of CO₂–H₂O mixtures with up to 38 mol% H₂O. Raman spectroscopy revealed H₂S along with dominant CO₂ in the carbonic phase. Equilibrium PT parameters for the intergranular Opx–Ilm–Glass assemblage correspond to 740±15°C, 2.8±0.1 kbar, respectively. Reducing gas species (<2 mol% total) in the CO₂-inclusions of the peraluminous pincinite resulted from hydrogen diffusion due to fH₂ gradient imposed during decrease of redox potential from the log fO₂ values near QFM during Qtz + Plg growth, to QFM-2 incidental to the superimposed Opx + Ilm assemblage in the intergranular melt. The decrease in oxygen fugacity was recorded also in the metaluminous pincinite, where log fO₂ values changed from ~QFM + 2.6 to QFM + 0.4, but hydrogen diffusion did not occur. Absence of OH-bearing minerals, major and trace element abundances (e.g. REE 300–320, Nb 55–57, Th 4–31, Zr 240–300 ppm, FeO_tot/MgO up to 11), and Sr–O isotope ratios in the pincinites are diagnostic of high-temperature anorogenic magmas originated by dehydration melting of biotite in quartz-feldspathoid crust (⁸⁷Sr/⁸⁶Sr>0.705–0.706, ¹⁸O>9 V-SMOW) around alkali basalt reservoir in depths between 17 and 20 km, and around late stage derivatives of the basalt fractionation, intruding the crust up to depths of 10–11 km. Low water activity in the pincinite parental melt was caused by CO₂-flux from the Tertiary basaltic reservoirs and intrusions. The anatexis leads to generation of a melt-depleted granulitic crust beneath the Pannonian Basin, and the pincinites are interpreted as equivalents of igneous charnockites and enderbites quenched at temperatures above solidus and unaffected by sub-solidus re-equilibration and metamorphic overprint.     

12,000-Year, preliminary results of the stable nitrogen and carbon isotope record from the Empakai Crater lake sediments, Northern Tanzania

The stable isotope compositions of organic carbon and nitrogen, the contents of organic carbon and nitrogen and C/N ratios for two cores recovered from the Empakai Crater at water depths of 11 and 20 m are used to document climatic changes in northern Tanzania. Eight ¹⁴C AMS dates determined on total organic matter (OM) indicate that the sedimentation rate in this lake is about 30 cm/ka for the late Pleistocene to early Holocene period. There are differences in the δ¹³C values of organic carbon between the two cores, which may be a result of differences in location from the present shoreline and of different water depths. In the deeper-water core the δ¹³C values show a general downcore decrease to the base of the core with a sharp change to lower values of about 4‰ at a depth of 100 cm (8.7 ka). The general trend of downcore decrease in ¹³C values can be attributed either to a systematic decrease in the relative proportion of C₄ type of OM, owing to an increase in precipitation and change in vegetation cover from grassland to forest, or to utilization of isotopically enriched carbon during photosynthesis. The δ¹⁵N values show a general downcore increase with again a sharp change of about 5‰ to lower values at about 8.7 ka. A sharp change of about 5‰ and 4‰ to more depleted values at a depth of 100 cm of both ¹⁵N and ¹³C, respectively, suggests either hiatus or abrupt change in climatic condition from wetter conditions to drier conditions. There is enhanced preservation of OM in the lake as depicted by high mean values of organic carbon and nitrogen at both sites.     

Physical and biological properties of the late Miocene, long-lived Turiec Basin, Western Carpathians (Slovakia) and its paleobiotopes

The Turiec Basin (TB) of Slovakia formed in the Miocene when the West Carpathians escaped from the Alpine region. The 1,250-m-thick sedimentary Neogene fill of the basin preserved fossil leaves as well as endemic bivalves, gastropods, and ostracodes. The paleolimnologic changes recorded in the TB infill were derived from the most abundant fossils, the ostracodes. Five contemporaneous ostracode assemblages within the Late Miocene lacustrine system were distinguished through statistical analysis. These assemblages have low species similarity, between 2.1 and 24.1%, and are recognized by shape differences among the Candoninae. The ostracode assemblages, mollusca fossils, and Sr-isotope ratios suggest a low-salinity environment at the beginning of the Late Miocene, during a brief connection with the Central Paratethys. When the connection ceased, the basin became an isolated freshwater lake, with five zones differentiated ecologically and bathymetrically using the ostracode assemblages. Taxonomic comparison of the faunas of the TB and the freshwater to brackish Neogene basins of Europe demonstrates the endemic character of the TB ostracode fauna. The biologic characteristics of the ostracode families, along with the geology of the lake basin, suggest that the longevity of the Late Miocene lake probably exceeded 1 Ma.     

Uncertainty estimation of the global temperature trends for multiple radiosondes, reanalyses, and CMIP3/IPCC climate model simulations

Based on three groups of datasets that include radiosondes, reanalyses, and climate model simulations (e.g., Coupled Model Intercomparison Project, CMIP3) from 1979 to 2008, the interannual variability, global temperature trends, and their uncertainty using ensemble spread among intra-group and inter-group datasets have been discussed. The results show that the interannual temperature variability increased from the troposphere to stratosphere, and the maximum occurs around 50?hPa. The CMIP3 climate models have the largest discrepancy in the stratosphere. The intra-group correlations at 500?hPa generally show high similarity within each data group while the inter-group correlations between reanalyses and the CMIP3 climate model simulations indicate lesser similarity. In contrast, the inter-group correlation at 50?hPa is improved except with the Japanese 25-year Reanalysis Project (JRA-25) dataset, and the Twentieth Century Reanalysis (20CR) reanalysis shows a weak cross correlation. The global temperature trends are highly dependent on the individual data sources. Compared to the radiosondes, the reanalyses show a large ensemble spread of trends in the stratosphere, and the CMIP3 climate model simulations have a large ensemble spread in the height of the crossover point where tropospheric warming changes into stratospheric cooling. The largest ensemble spread among the reanalyses in the stratosphere is mainly from the large discrepancy in the JRA-25 reanalysis after 1998 and a relatively weak anomaly in the 20CR before 1986. The largest ensemble spread among the CMIP3 climate models in the troposphere is related to the influence of both volcanic eruptions and El Ni?o/La Ni?a–Southern Oscillation events. The strong anomalies corresponding to the volcanic eruptions of El Chichon in 1982 and Mt Pinatubo in 1991 are clearly identified in the stratosphere. These volcanic eruptions reduced the warming in the troposphere and strengthened the cooling in the stratosphere during the most recent 30?years.     

Seasonality change and the third millennium BP rainforest crisis in southern Cameroon (Central Africa)

The third millennium BP crisis of the central African rainforest is not sufficiently understood. The low resolution of most pollen profiles and a large plateau of the calibration curve aggravate the exact dating of the event, and its causal climatic parameters are debated. We present a high-resolution pollen profile from the swamp site Nyabessan in the southern Cameroonian rainforest, covering the period 3100-2300 cal yr BP. Between 3100 and 2500 cal yr BP, the climate was favourable for a regional evergreen forest with Caesalpiniaceae and Lophira and a local Raphia swamp forest. Around 2500/2400 cal yr BP, a significant decrease of mature forest and swamp forest taxa and an increase of pioneers indicate that the rain forest was seriously disturbed and replaced by secondary formations. The dominance of Trema orientalis, a pioneer well adapted to seasonal desiccation, points to a much more accentuated seasonality after 2500 cal yr BP, which seems to be linked to a southwards shift of the ITCZ during the northern hemisphere winter months. We propose that the rain forest crisis between 2500 and 2200 cal BP created favourable conditions for farming and paved the way for a major expansion of Bantu speaking populations.     

The topography of Iapetus' leading side

We have used Cassini stereo images to study the topography of Iapetus' leading side. A terrain model derived at resolutions of 4-8 km reveals that Iapetus has substantial topography with heights in the range of −10 km to +13 km, much more than observed on the other middle-sized satellites of Saturn so far. Most of the topography is older than 4 Ga [Neukum, G., Wagner, R., Denk, T., Porco, C.C., 2005. Lunar Planet. Sci. XXXVI. Abstract 2034] which implies that Iapetus must have had a thick lithosphere early in its history to support this topography. Models of lithospheric deflection by topographic loads provide an estimate of the required elastic thickness in the range of 50-100 km. Iapetus' prominent equatorial ridge [Porco, C.C., and 34 colleagues, 2005. Science 307, 1237-1242] reaches widths of 70 km and heights of up to 13 km from their base within the modeled area. The morphology of the ridge suggests an endogenous origin rather than a formation by collisional accretion of a ring remnant [Ip, W.-H., 2006. Geophys. Res. Lett. 33, doi:10.1029/2005GL025386. L16203]. The transition from simple to complex central peak craters on Iapetus occurs at diameters of 11±3 km. The central peaks have pronounced conical shapes with flanking slopes of typically 11° and heights that can rise above the surrounding plains. Crater depths seem to be systematically lower on Iapetus than on similarly sized Rhea, which if true, may be related to more pronounced crater-wall slumping (which widens the craters) on Iapetus than on Rhea. There are seven large impact basins with complex morphologies including central peak massifs and terraced walls, the largest one reaches 800 km in diameter and has rim topography of up to 10 km. Generally, no rings are observed with the basins consistent with a thick lithosphere but still thin enough to allow for viscous relaxation of the basin floors, which is inferred from crater depth-to-diameter measurements. In particular, a 400-km basin shows up-domed floor topography which is suggestive of viscous relaxation. A model of complex crater formation with a viscoplastic (Bingham) rheology [Melosh, H.J., 1989. Impact Cratering. Oxford Univ. Press, New York] of the impact-shocked icy material provides an estimate of the effective cohesion/viscosity at . The local distribution of bright and dark material on the surface of Iapetus is largely controlled by topography and consistent with the dark material being a sublimation lag deposit originating from a bright icy substrate mixed with the dark components, but frost deposits are possible as well.     

The GEOMON network of Czech catchments provides long-term insights into altered forest biogeochemistry: From acid atmospheric deposition to climate change

In 1994, a network of small catchments (GEOMON) was established in the Czech Republic to determine input–output element fluxes in semi-natural forest ecosystems recovering from anthropogenic acidification. The network consists from 16 catchments and the primary observations of elements fluxes were complemented by monitoring of biomass stock, element pools in soil and vegetation, and the main water balance components. Over last three decades, reductions of SO₂, NO_x and NH₃ emissions were followed by sulphur (S) and nitrogen (N) deposition reductions of 75% and 30%, respectively. Steeper declines of strong acid anion concentrations compared to cations (Ca, Mg, Na, K, NH₄) in precipitation resulted in precipitation pH increase from 4.5 to 5.2 in bulk precipitation and from 4.0 to 5.1 in spruce throughfall. Stream chemistry responded to changes in deposition: S leaching declined. However at majority of catchments soils acted as a net source of S to runoff, delaying recovery. Stream pH increased at acidic streams (pH < 6) and aluminium concentration decreased. Stream nitrate (NO₃) concentration declined by 60%, considerably more than N deposition. Stream NO₃ concentration was tightly positively related to stream total dissolved nitrogen to total phosphorus (P) ratio, suggesting the role of P availability on N retention. Trends in dissolved organic carbon fluxes responded to both acidification recovery and to runoff temporal variation. An exceptional drought occurred between 2014 and 2019. Over this recent period, streamflow decreased by ≈ 40% on average compared to 1990s, due to the increases of soil evaporation and vegetation transpiration by ≈ 30% and declines in precipitation by ≈ 15% on average across the elevational gradient. Sharp decreases of stream runoff at catchments <650 m a.s.l. corresponded to areas of recent forest decline caused by bark beetle infestation on drought stressed spruce forests. Understanding of the interactions among legacies of acidification and eutrophication, drought effects on the water cycle and forest disturbance dynamics is requisite for effective management of forested ecosystems under anthropogenic influence.     

Influence of subdaily polar motion model on nutation offsets estimated by very long baseline interferometry

This paper studies the connection between the subdaily model for polar motion used in the processing of very long baseline interferometry (VLBI) observations and the estimated nutation offsets. By convention accepted by the International Earth Rotation Service, the subdaily model for polar motion recommended for routine processing of geodetic observations does not contain any daily retrograde terms due to their one-to-one correlation with the nutation. Nevertheless, for a 24-h VLBI solution a part of the signal contained in the polar motion given by the used subdaily model is numerically mistaken for a retrograde daily sidereal signal. This fictitious retrograde daily signal contributes to the estimated nutation, leading to systematic differences between the nutation offsets from VLBI solutions computed with different subdaily polar motion models. We demonstrate this effect using solutions for all suitable 24-h VLBI sessions over a time span of 11 years (2000–2011). By changing the amplitudes of one tidal term in the underlying subdaily model for polar motion and comparing the estimated parameters to the solutions computed with the unchanged subdaily model, the paper shows and explains theoretically the effects produced by the individual subdaily terms on the VLBI nutation estimates.