Gem corundum deposits of Madagascar: A review

Madagascar is one of the most important gem-producing countries in the world, including ruby and sapphires. Gem corundum deposits formed at different stages in the geological evolution of the island and in contrasting environments. Four main settings are identified: (1) Gem corundum formed in the Precambrian basement within the Neoproterozoic terranes of southern Madagascar, and in the volcano-sedimentary series of Beforona, north of Antananarivo. In the south, high-temperature (700 to 800 °C) and low-pressure (4 to 5 kbar) granulites contain deposits formed during the Pan-African orogenesis between 565 and 490 Ma. They accompany mafic and ultramafic complexes (ruby deposits of the Vohibory group), skarns at the contact between Anosyan granites and the Proterozoic Tranomaro group (sapphire deposits of the Tranomaro–Andranondambo district), and shear-zone corridors cross-cutting feldspathic gneisses, cordieritites and clinopyroxenites in the Tranomaro, Vohimena and Androyan metamorphic series (biotite schist deposits of Sahambano and Zazafotsy, cordieritites of Iankaroka and Ambatomena). The circulation of fluids, especially along discontinuities, allowed in-situ alkaline metasomatism, forming corundum host rocks related to desilicified granites, biotitites, “sakenites” and “corundumites”. (2) Gem corundum also occurs in the Triassic detrital formations of the Isalo group, as giant palaeoplacers in the Ilakaka–Sakaraha area. Here, sapphires and rubies may come from the metamorphic granulitic terranes of southern Madagascar. (3) Gem corundum deposits occur within the Neogene-Quaternary alkali basalts from Ankaratra (Antsirabe–Antanifotsy area) and in the Ambohitra Province (Nosy Be, Ambato and Ambondromifehy districts). Primary deposits are rare, except at Soamiakatra where ruby in gabbroic and clinopyroxenite xenoliths within alkali-basalts probably derive from mantle garnet peridotites. The blue-green-yellow sapphires typical of basaltic fields are always recovered in palaeoplacer (in karst formed upon Jurassic limestones from the Montagne d'Ambre, Antsiranana Province) and alluvial and soil placers (Ankaratra volcanic massif). (4) Deposits occur within Quaternary eluvial, colluvial and alluvial concentrations, such as high-quality rubies from the Andilamena and Vatomandry deposits.     

Isothermal decompression history in the “Western Granulite” terrain, central Tanzania: Evidence from reaction textures and trapped fluids in metapelites

The Mozambique Belt (MB) of the East Africa Orogen contains large areas of granulite-facies migmatitic gneisses with Archaean and Palaeoproterozoic protolith ages and that were recycled during the Neoproterozoic Pan-African orogeny. The study area is situated along the Great Ruaha River and within the Mikumi National Park in central Tanzania where migmatitic gneisses and mafic to intermediate granulites are interlayered with Neoproterozoic granulite-facies migmatitic metapelites. Mineral textures suggest isothermal decompression, with the peak mineral assemblage comprising Grt–Bt–Ky–Kfs–Pl–Qtz ± Phn ± Ti-Oxide ± melt and amphibolite-facies retrograde assemblage Grt–Bt–Sil–Ms–Kfs–Pl–Qtz ± Fe–Ti-Oxide. The near isothermal retrograde overprint is seen in well-developed formation of pseudomorphs after garnet. The HP granulite-facies assemblages record P–T conditions of 13–14 kbar at 760–800 °C. Retrogression and the release of fluids from crystallizing melts occurred at 7 kbar and 650–700 °C. A fluid inclusion study shows three types of fluid inclusion consisting of nearly pure CO₂, as well as H₂O–NaCl and H₂O–CO₂ mixtures. We suggest that a immiscible CO₂-bearing brine represents the fluid composition during high-grade peak metamorphism, and that the fluid inclusions containing H₂O–NaCl or nearly pure CO₂ represent trapped fluids from in situ crystallised melt. The results suggest strong isothermal decompression, which is probably related to a fast exhumation after crustal thickening in the central part of the Mozambique Belt in Tanzania.     

How bioturbation obscured the Cretaceous–Palaeogene boundary record

The Cretaceous–Palaeogene (K/Pg) boundary interval is often penetrated by burrows, which may obscure stratigraphic and micropalaeontological records, leading to misinterpretations of the sequence of events spanning the K/Pg boundary. Here, we assess the role of burrowing organisms in the redistribution of benthic foraminifera across the boundary at Bidart (France), and report a strong relationship between the behaviour represented by pre‐ and post‐K/Pg trace fossils and their benthic foraminiferal content. We further infer a brief interval of eutrophic conditions at the seafloor, as reported from other locations, which disappeared from the lowermost Danian stratigraphic record and is represented only inside post‐K/Pg trace fossils hosted in Cretaceous strata. The combined study of trace fossils and microfossils is a powerful tool in eco‐stratigraphy and event‐stratigraphy, and can yield important insights into the completeness of the K/Pg record, especially at locations such as Bidart where this interval has traditionally been assumed to be complete.     

Application of the Clean Development Mechanism in the Sanitation Sector: “Proof of Concept”

Greenhouse gas emissions from the waste sector account for only 4% of the total production, with wastewater management accounting for accurately 8 to 10% of this contribution. Wastewater disposal and treatment activities, mainly contributes to non‐CO₂ gases such as methane (CH₄) and nitrous oxide (N₂O). Capturing or avoiding these emissions is thus both a concern and an opportunity. The clean development mechanism (CDM) offers an instrument to internalize global climate concerns into the design of wastewater treatment facilities. Properly designed facilities could improve effluent quality and optimize the abatement of greenhouse gas emissions, thus ensuring additional revenues to pay for capital, operation and maintenance costs and possibly justify higher levels of wastewater treatment. This document summarizes the experience of the “Rio Frio CDM project” in Colombia, as an example of what is achievable through the CDM application in wastewater treatment upgrade in developing countries. This document summarizes the scope of the project, the methodology used to establish current greenhouse emissions and future reductions, and the estimated financial results.     

Arbeit deutscher Geologen im Ausland seit Kriegsende

Ohne Zusammenfassung     

Multiple-satellite-aided capture trajectories at Jupiter using the Laplace resonance

Satellite-aided capture is a mission design concept used to reduce the delta-v required to capture into a planetary orbit. The technique employs close flybys of a massive moon to reduce the energy of the planet-centered orbit. A sequence of close flybys of two or more of the Galilean moons of Jupiter may further decrease the delta-v cost of Jupiter orbit insertion. A Ganymede-Io sequence can save 207 m/s of delta-v over a single Io flyby. A phase angle analysis based on the Laplace resonance is used to find triple-satellite-aided capture sequences involving Io, Europa, and Ganymede. Additionally, the near-resonance of Callisto and Ganymede is used to find triple-satellite-aided capture sequences involving Callisto, Ganymede, and another moon. A combination of these techniques is used to find quadruple-satellite-aided capture sequences that involve gravity-assists of all four Galilean moons. These sequences can save a significant amount of delta-v and have the potential to benefit both NASA’s Jupiter Europa orbiter mission and ESA’s Jupiter Ganymede orbiter mission.     

http://www.sciencedirect.com/science/article/pii/S1674987114000322

The Central Hebei Basin （CHB） is one of the largest sedimentary basins in the North China Craton, extending in a northeast-southwest direction with an area of 〉350 km2. We carried out SHRIMP zircon dating, Hf-in-zircon isotopic analysis and a whole-rock geochemical study on igneous and metasedi- mentary rocks recovered from drill holes that penetrated into the basement of the CHB, Two samples of gneissic granodiorite （XG1-1） and gneissic quartz diorite 048-1） have magmatic ages of 2500 and 2496 Ma, respectively. Their zircons also record metamorphic ages of 2.41-2.51 and ～2.5 Ga, respec- tively. Compared with the gneissic granodiorite, the gneissic quartz diorite has higher REE contents and lower Eu/Eu＊ and （La/Yb）n values. Two metasedimentary samples （MG1, H5） mainly contain ～2,5 Ga detrital zircons as well as late Paleoproterozoic metamorphic grains. The zircons of different origins have eHf （2.5 Ga） values and Hf crustal model ages ranging from 0 to 5 and 2.7 to 2,9 Ga, respectively, Therefore, ～2.5 Ga magmatic and Paleoproterozoic metasedimentary rocks and late Neoarchean to early Paleoproterozoic and late Paleoproterozoic tectono-thermal events have been identified in the basement beneath the CHB. Based on regional comparisons, we conclude that the early Precambrian basement beneath the CHB is part of the North China Craton.     

Space weathering and the low sulfur abundance of Eros

The surprisingly low S/Si ratio of Asteroid 433 Eros measured by the NEAR Shoemaker spacecraft probably reflects a surface depletion rather than a bulk property of the asteroid. The sulfur X-ray signal originates at a depth <10 μm in the regolith. The most efficient process for vaporizing minerals at the heliocentric distance of Eros are sputtering by solar wind ions and hypervelocity impacts. These are the same processes that account for the changes in optical properties of asteroids attributed to “space weathering” of lunar surface materials, although the relative importance of sputtering and impacts need not be the same for the Moon and asteroids. Troilite, FeS, which is the most important sulfide mineral in meteorites, and presumably on S-type asteroids like Eros, can be vaporized by much less energy than other major minerals, and will therefore be preferentially lost. Within 10⁶ years either process can remove sulfide from the top 10-100 μm of regolith. Sulfur will be lost into space and some sulfur will migrate to deeper regolith layers. We also consider other possible mechanisms of surficial sulfur depletion, such as mineral segregation in the regolith and perhaps even incipient melting. Although we consider solar wind sputtering the most likely cause of the sulfur depletion on Eros, we cannot entirely rule out other processes as causes of the sulfur deficiency. Laboratory simulations of the relevant processes can address some of the open questions. Simulations will have to be carried out in such a way that potential sulfur loss processes as well as resurfacing can be studied simultaneously, requiring a large and complex environmental chamber.     

Cassini observations of Io's visible aurorae

More than 500 images of Io in eclipse were acquired by the Cassini spacecraft in late 2000 and early 2001 as it passed through the jovian system en route to Saturn (Porco et al., 2003, Science 299, 1541-1547). Io's bright equatorial glows were detected in Cassini's near-ultraviolet filters, supporting the interpretation that the visible emissions are predominantly due to molecular SO₂. Detailed comparisons of laboratory SO₂ spectra with the Cassini observations indicate that a mixture of gases contribute to the equatorial emissions. Potassium is suggested by new detections of the equatorial glows at near-infrared wavelengths from 730 to 800 nm. Neutral atomic oxygen and sodium are required to explain the brightness of the glows at visible wavelengths. The molecule S₂ is postulated to emit most of the glow intensity in the wavelength interval from 390 to 500 nm. The locations of the visible emissions vary in response to the changing orientation of the external magnetic field, tracking the tangent points of the jovian magnetic field lines. Limb glows distinct from the equatorial emissions were observed at visible to near-infrared wavelengths from 500 to 850 nm, indicating that atomic O, Na, and K are distributed across Io's surface. Stratification of the atmosphere is demonstrated by differences in the altitudes of emissions at various wavelengths: SO₂ emissions are confined to a region close to Io's surface, whereas neutral oxygen emissions are seen at altitudes that reach up to 900 km, or half the radius of the satellite. Pre-egress brightening demonstrates that light scattered into Jupiter's shadow by gases or aerosols in the giant planet's upper atmosphere contaminates images of Io taken within 13 minutes of entry into or emergence from Jupiter's umbra. Although partial atmospheric collapse is suggested by the longer timescale for post-ingress dimming than pre-egress brightening, Io's atmosphere must be substantially supported by volcanism to retain auroral emissions throughout the duration of eclipse.     

Analysing the interaction between emission trading and renewable electricity support in TIMES

As the number of instruments applied in the area of energy and climate policy is rising, the issue of policy interaction needs to be explored further. This article analyses the interdependencies between the EU Emissions Trading Scheme (EU ETS) and the German feed-in tariffs (FITs) for renewable electricity in a quantitative manner using a bottom-up energy system model. Flexible modelling approaches are presented for both instruments, with which all impacts on the energy system can be evaluated endogenously. It is shown that national climate policy measures can have an effect on the supranational emissions trading system by increasing emission reduction in the German electricity sector by up to 79 MtCO₂ in 2030. As a result, emission certificate prices decline by between 1.9 €/tCO₂ and 6.1 €/tCO₂ and the burden sharing between participating countries changes, but no additional emission reduction is achieved at the European level. This also implies, however, that the cost efficiency of such a cap-and-trade system is distorted, with additional costs of the FIT system of up to €320 billion compared with lower costs for ETS emission certificates of between €44 billion and €57 billion (cumulated over the period 2013–2020).

Policy relevance

In order to fulfil ambitious emission reduction targets a large variety of climate policy instruments are being implemented in Europe. While some, like the EU ETS, directly address CO₂ emissions, others aim to promote specific low-carbon technologies. The quantitative analysis of the interactions between the EU ETS and the German FIT scheme for renewable sources in electricity generation presented in this article helps to understand the importance of such interaction effects. Even though justifications can be found for the implementation of both types of instrument, the impact of the widespread use of support mechanisms for renewable electricity in Europe needs to be taken into account when fixing the reduction targets for the EU ETS in order to ensure a credible long-term investment signal.