Arsenic within the secondary environment resulting from geogenic inputs,Harlech Dome,United Kingdom

There has been a growing awareness of As in the environment due to both anthropogenic and geogenic loading. This study quantifies the presence of As in river water, river sediment and groundwater within the Harlech Dome region of the UK, an area underlain by Cambro–Ordovician aged mineralization. Published data regarding As levels in UK groundwater are relatively rare compared to elsewhere. Arsenic levels in groundwater (0.1–18 µg l^?1) and river sediment (1.5–142 mg kg^?1) exceed environmental quality guidelines and indicate the release of As into the secondary environment from predominantly geogenic sources. Modelling of dissolved As speciation using ORP–pH diagrams predicts the presence of As in both arsenate (As⁵⁺) and arsenous acid (As³⁺) species, which possess differing solubilities and mobilities. Calculation of enrichment factors (EFs) for As in river sediments, using Al as a reference element, indicates highest EFs, and therefore As release, occurs in streams draining the Coed-y-Brenin region in the south-east of the Harlech Dome. This area is underlain by an as yet unexploited porphyry copper deposit. Data indicate that the presence of potentially harmful elements within the environment may occur with or without the presence of major anthropogenic activity.     

Exploring Mobility Indoors: an Application of Sensor‐based and GIS Systems

The popularization of tracking devices, such as GPS, accelerometers and smartphones, have made it possible to detect, record, and analyze new patterns of human movement and behavior. However, employing GPS alone for indoor localization is not always possible due to the system's inability to determine location inside buildings or in places of signal occlusion. In this context, the application of local wireless networks for determining position is a promising alternative solution, although they still suffer from a number of limitations due to energy and IT‐resources. Our research outlines the potential for employing indoor wireless network positioning and sensor‐based systems to improve the collection of tracking data indoors. By applying various methods of GIScience we developed a methodology that can be applicable for diverse human indoor mobility analysis. To show the advantage of the proposed method, we present the result of an experiment that included mobility analysis of 37 participants. We tracked their movements on a university campus over the course of 41 days and demonstrated that their movement behavior can be successfully studied with our proposed method.     

Pliocene and late Pleistocene (MIS 5e) decapod crustaceans from Santa Maria Island (Azores Archipelago: Central Atlantic): systematics,palaeoecology and palaeobiogeography

The presence of decapod crustaceans in the Pliocene and Pleistocene (MIS 5e) fossil record of Santa Maria Island (Azores Archipelago) is herein reviewed. Our study raises the number of fossil decapods from this island from one species to 10 taxa (three for the Pliocene and seven for the Last Interglacial). Four of these 10 taxa are reported for the first time in the fossil record, worldwide. A new species of a mud shrimp is also described (Upogebia azorensis n. sp.). Our study suggests that the Plio–Pleistocene decapod assemblages of the Azores did not differ significantly from modern ones, being dominated by species that are today widespread across the Webbnesia ecoregion, the Mediterranean Sea, and the eastern Atlantic shores, including the Azores. As far as can be judged from the limited fossil record, apparently no tropical crab species with a Cabo Verdean/Senegalese provenance reached the Azores during windows of opportunity associated with Glacial Termination 2 or with the initial setting of the Last Interglacial period. This contribution increases the total number of marine taxa reported for the Pliocene and Pleistocene outcrops of Santa Maria Island to 218 and 155, respectively, highlighting the scientific relevance of its palaeontological heritage.     

Hubble Space Telescope imaging polarimetry of Mars during the 2003 opposition

We report results of polarimetric imaging observations of Mars with the Hubble Space Telescope during the 2003 opposition. Through careful calibration, the observations with the ACS camera allow measurements of the polarization degree with an absolute accuracy better than 0.5% and detection of features with polarization degree contrast as small as 0.2%. The general distribution of linear polarization parameters over the Mars disk and their dependence on phase angle and wavelength are well explained qualitatively by a combination of scattering separately by the martian surface and atmosphere. We have discovered transient polarization phenomena interpreted as clouds that are best observed in ultraviolet light. These clouds are optically thin but strongly polarizing, and their origin may be related to atmospheric ice condensation processes.     

Layering stratigraphy of eastern Coprates and northern Capri Chasmata, Mars

Distinct competent layers are observed in the slopes of eastern Coprates Chasma, part of the Valles Marineris system on Mars. Our observations indicate that the stratigraphy of Coprates Chasma consists of alternating thin strong layers and thicker sequences of relatively weak layers. The strong, competent layers maintain steeper slopes and play a major role in controlling the overall shape and geomorphology of the chasmata slopes. The topmost competent layer in this area is well preserved and easy to identify in outcrops on the northern rim of Coprates Chasma less than 100 m below the southern Ophir Planum surface. The volume of the topmost emplaced layer is at least 70 km³ and may be greater than 2100 km³ if the unit underlies most of Ophir Planum. The broad extent of this layer allows us to measure elevation offsets within the north rim of the chasma and in a freestanding massif within Coprates Chasma where the layer is also observed. Rim outcrop morphology and elevation differences between Ophir and Aurorae Plana may be indicative of the easternmost extent of the topmost competent layer. These observations allow an insight into the depositional processes that formed the stratigraphic stack into which this portion of the Valles Marineris is carved, and they present a picture of some of the last volcanic activity in this area. Furthermore, the elevation offsets within the layer are evidence of significant subsidence of the massif and surrounding material.