Hydrological and geomorphological criteria to evaluate the dispersion risk of waste sludge generated by the Aznalcollar mine spill (SW Spain)

Following the Aznalcóllar pyrite mine disaster (Seville, Spain) which caused the spilling of some 4.5?hm³ of acid water, the floodplains of the rivers Agrio and Guadiamar were rapidly cleaned of waste sludge. However, despite the efficiency of cleaning activities, there is still evidence of a fine superficial layer of sludge and some soil contamination, with the consequent risk of remobilisation of the pollutants by water erosion. There is much concern that these contaminated sediments may affect the precious ecosystems of the Doñana National Park and the Guadalquivir marshlands. This report describes the evaluation of the risk of mobilisation of the waste sludge through (1) detailed geomorphological analysis, indicating potential areas of erosion-sedimentation on the floodplains of the rivers Agrio and Guadiamar, and predicted dynamics of the waste sludge, and (2) evaluation of the potential dispersion of the waste sludge provoked by future flood events, including hydraulic calculations to model channel flow and the analysis of the texture of the sludge to obtain critical transport and sedimentation values. Findings suggest that the waste sludge is likely to be transported and deposited within the Doñana National Park during future flood events.     

DFT study of the cation arrangements in the octahedral and tetrahedral sheets of dioctahedral 2:1 phyllosilicates

Quantum mechanical calculations based on the density functional theory (DFT) are used to study the crystal structures of dioctahedral 2:1 phyllosilicates. The isomorphous cation substitution is investigated by exploring different substitutions of octahedral Al³⁺ by Mg²⁺ or Fe³⁺, tetrahedral substitution of Si⁴⁺ by Al³⁺, and different interlayer cations (IC) (Na⁺, K⁺, Ca²⁺, and Mg²⁺). Samples with different kinds of layer charges are studied: only tetrahedrally charged, only octahedrally charged, or mixed octahedral/tetrahedral charged. The effect of the relative arrangements of these substitutions on the lattice parameters and total energy is studied. The experimental observation of segregation tendency of Fe³⁺ and dispersion tendency of Mg²⁺ in the octahedral sheet is reproduced and explained with reference to the relative energies of the octahedral cation arrangements. These energies are higher than those due to the IC/tetrahedral and IC/octahedral relative arrangements. The tetrahedral and octahedral substitutions that generate charged layers also tend to be dispersed. The octahedral cation exchange potentials change with the IC-charge/ionic radius value.     

Waiting Time Distribution of Emissions in Complex Coronal Mass Ejections

The waiting time distribution of emissions in Coronal Mass Ejections (CMEs) with several emissions is examined. We define the waiting time as the time interval between the commencement of an emission and the commencement of the next emission considered as parts of a unique CME. The distribution seems to follow a power-law. Two classes of CMEs several emissions are considered: “close” and “separate” depending on angular distance between emissions.     

On gravitational instability of the interstellar gas

In the galaxy, Jeans' critical length for the interstellar gas is appreciably smaller than the critical length for the stars, a necessary condition for the gravitational instability of the former to have a local character. An accurate discussion of the orders of magnitude involved leads to the establishment of a well defined limiting procedure and to simplified equations in which the effect of stars occurs only through the equilibrium, but disappears from the perturbations. The equations are spatially local, but their coefficients are time-dependent, in that they describe the evolution of a small wave packet dragged along by the supersonic gas motion. They have been solved in several interesting cases by the introduction of an effective, time-dependent wave vector, which describes the deformation of a wave profile due to the velocity gradients. The ordinary Jeans' instability is recovered only when the velocity gradient is a skew tensor; otherwise we find a stabilizing effect in accelerated and sheared flows, a destabilizing effect in a decelerated flow. Possible connections of this model with the observed turbulent structure of the interstellar gas are discussed.     

The density of Red Sea brines

The densities of artificial and real Red Sea brines have been measured at 25°C with a vibrating tube densimeter. Measurements were also made on mixtures of Red Sea brines with seawater and pure water. The results have been used to characterize the density—composition relations of waters across the interface of brine and average Red Sea waters. The results for the real and artificial brines are in reasonable agreement.The composition of the brines and mixtures with seawater have been characterized by conductivity measurements of weight diluted samples. The conductivity salinities were found to be conservative to within $\text{±0.07‰}$ for the mixtures.The densities of brines and mixtures of brines and seawater were estimated from apparent molal volume data using Young's rule. The calculated densities for all of the solutions were found to be in good agreement with the measured values, demonstrating the applicability of Young's rule to concentrated natural waters.     

Diffuse Baryons in Cosmic Structures

I review the processes that govern the amount and the thermal state of the hot plasma pervading clusters and groups of galaxies: the gravitational heating driven by the DM merging histories, the radiative cooling of baryons, and the energy fed back by SNe and by AGNs or quasars. I argue that the X-ray emissions and the entropy levels now observed from clusters to groups require the AGNs to contribute substantially to preheat the gas before it falls into clusters, and the quasars to blow some plasma out of groups and galaxies.