Performance evaluation of artificial neural networks for planimetric coordinate transformation—a case study,Ghana

Two national horizontal geodetic datums, namely, the Accra and Leigon datum, have been the only available datum used in Ghana. These two datums are non-geocentric and were established based on astro-geodetic observations. Relating these different geodetic datums mostly involves the use of conformal transformation techniques which could produce results that are not very often satisfactory for certain geodetic, surveying and mapping purposes. This has been ascribed to the incapability of the conformal models to absorb more of the heterogeneous and local character of deformations existing within the local geodetic networks. Presently, application of new approaches such as artificial neural network (ANN) is highly recommended. Whereas the ANN has been gaining much popularity to solving coordinate transformation-related problems in recent times, the existing researches carried out in Ghana have shown that only three-dimensional conformal transformation methods have been utilized. To the best of our knowledge, plane coordinate transformation between the two local geodetic datums in Ghana has not been investigated. In this paper, an attempt has been made to explore the plane coordinate transformation performance of two different ANN approaches (backpropagation neural network (BPNN) and radial basis function neural network (RBFNN)) compared with two different traditional techniques (six- and four-parameter models) in the Ghana national geodetic reference network. The results revealed that transforming plane coordinates from Leigon to Accra datum, the RBFNN was better than the BPNN and traditional techniques. Transforming from Accra to Leigon datum, both the BPNN and RBFNN produced closely related results and were better than the traditional methods. Therefore, this study will create the opportunity for Ghana to recognize the significance and strength of the ANN technology in solving coordinate transformation problems.     

Evidence for Hesperian impact-induced hydrothermalism on Mars

Several hydrated silicate deposits on Mars are observed within craters and are interpreted as excavated Noachian material. Toro crater (71.8°E, 17.0°N), located on the northern edge of the Syrtis Major Volcanic Plains, shows spectral and morphologic evidence of impact-induced hydrothermal activity. Spectroscopic observations were used to identify extensive hydrated silicate deposits, including prehnite, chlorites, smectites, and opaline material, a suite of phases that frequently results from hydrothermal alteration in terrestrial craters and also expected on Mars from geochemical modeling of hydrothermal environments. When combined with altimetry and high-resolution imaging data, these deposits appear associated predominantly with the central uplift and with portions of the northern part of the crater floor. Detailed geologic mapping of these deposits reveals geomorphic features that are consistent with hydrothermal activity that followed the impact event, including vent-like and conical mound structures, and a complex network of tectonic structures caused by fluid interactions such as fractures and joints. The crater age has been calculated from the cumulative crater size-frequency distributions and is found to be Early Hesperian. The evidence presented here provides support for impact-induced hydrothermal activity in Toro crater, that extends phyllosilicate formation processes beyond the Noachian era.     

Seeable universe and its accelerated expansion: an observational test

From the equivalence principle, one gets the strength of the gravitational effect of a mass M on the metric at position r from it. It is proportional to the dimensionless parameter β ²=2GM/rc ², which normally is ?1. Here G is the gravitational constant, M the mass of the gravitating body, r the position of the metric from the gravitating body and c the speed of light. The seeable universe is the sphere, with center at the observer, having a size such that it shall contain all light emitted within it. For this to occur one can impose that the gravitational effect on the velocity of light at r is zero for the radial component, and non zero for the tangential one. Light is then trapped. The condition is given by the equality R _g =2GM/c ², where R _g represents the radius of the seeable universe. It is the gravitational radius of the mass M. The result has been presented elsewhere as the condition for the universe to be treated as a black hole. According to present observations, for the case of our universe taken as flat (k=0), and the equation of state as p=?ρc ², we prove here from the Einstein’s cosmological equations that the universe is expanding in an accelerated way as t ², a constant acceleration as has been observed. This implies that the gravitational radius of the universe (at the event horizon) expands as t ². Taking c as constant, observing the galaxies deep in space this means deep in time as ct, linear. Then, far away galaxies from the observer that we see today will disappear in time as they get out of the distance ct that is <R _g . The accelerated expanding vacuum will drag them out of sight. This may be a valid test for the present ideas in cosmology. Previous calculations are here halved by our results.     

Sulfate reduction in deep coastal marine sediments

Sulfate reduction rates in sediments of four deep stations in the Saguenay Fjord and the Laurentian Trough, Gulf of St. Lawrence, are among the lowest reported for the coastal environment. Maximum rates were 0.4–7.0 nmol cm⁻³ day⁻¹. The low rates are due to relatively low sedimentation rates and continuously low temperatures. Regional differences in both integrated and maximum sulfate reduction rates in the sediment correlate with sediment trap measurements of sedimentation rate and organic carbon flux.Sulfate reduction accounts for the degradation of 5–26% of the estimated downward flux of organic matter to these sediments. Unlike the absolute rate of sulfate reduction, the relative proportion of the carbon flux that is degraded via sulfate reduction is not directly correlated with the sedimentation rate but is a function of organic matter composition, intensity of bioturbation, and the abundance of sub-oxic electron acceptors. Thus, the lowest proportion of carbon degradation via sulfate reduction occurred at a Gulf site, where a combination of low sedimentation and bioturbation rates allowed a long residence time for organic matter near the sediment surface and, in consequence, a low flux of labile carbon into the sulfate reduction zone. The highest proportion was observed at a station with a similar organic carbon flux but with higher rates of sedimentation and bioturbation. At a third site, with the highest rates of sulfate reduction as well as the highest rates of sedimentation and bioturbation, the contribution of sulfate reduction to organic matter degradation was only intermediate. This is attributable to the exhaustion of the supply of porewater sulfate. In deep coastal environments the proportion of organic matter degraded via sulfate reduction can be highly variable both spatially and temporally.     

Mechanistic and Kinetic Study of the Gas-Phase Reaction of Atomic Chlorine with Cyclohexanone using an Absolute and a Relative Technique; Influence of Temperature

The reaction of Cl with cyclohexanone (1) was investigated, for the first time, as a function of temperature (273–333 K) and at a low total pressure (1 Torr) with helium as a carrier gas using a discharge flow-mass spectrometry technique (DF-MS). The resulting Arrhenius expression is proposed, k ₁= (7.7 ± 4.1) × 10^–10 exp[–(540 ± 169)/T]. We also report a mechanistic study with the quantitative determination of the products of the reaction of Cl with cyclohexanone. The absolute rate constant derived from this study at 1 Torr of total pressure and room temperature is (1.3 ± 0.2) × 10^–10 cm³ molecule^–1 s^–1. A yield of 0.94 ± 0.10 was found for the H-abstraction channel giving HCl. In relative studies, using a newly constructed relative rate system, the decay of cyclohexanone was followed by gas chromatography coupled with flame-ionisation detection. These relative measurements were performed at atmospheric pressure with synthetic air and room temperature. Rate constant measured using the relative method for reaction (1) is: (1.7 ± 0.3) × 10^–10 cm³ molecule^–1 s^–1. Finally, results and atmospheric implications are discussed and compared with the reactivity with OH radicals.     

Mineral assemblages of the Francisco I. Madero Zn–Cu–Pb–(Ag) deposit, Zacatecas, Mexico: Implications for ore deposit genesis

The Francisco I. Madero deposit, central Mexico, occurs in the Mesozoic Guerrero Terrane, which hosts many ore deposits, both Cretaceous (volcanogenic massive sulfides) and Tertiary (epithermal and skarn deposits). It is hosted by a 600 m-thick calcareous-pelitic unit, of Lower Cretaceous age, crosscut by porphyritic dikes that strike NW–SE. A thick felsic volcanic Tertiary sequence, consisting of andesites and rhyolitic ignimbrites, unconformably overlies the Cretaceous series. At the base, the mineralization consists of several mantos developed within calcareous beds. They are dominantly composed of sphalerite, pyrrhotite and pyrite with minor chalcopyrite, arsenopyrite and galena. At the top of the orebody, there are calcic skarns formed through prograde and retrograde stages. The resulting mineral assemblages are rich in manganoan hedenbergite (Hd_75–28Di_40–4Jh_40–20), andraditic garnets (Adr_100–62Grs_38–0), epidote (Ep_95–36Czo_60–5Pie_8–0), chamosite, calcite and quartz. The temperature of ore deposition, estimated by chlorite and arsenopyrite geothermometry, ranges from 243° to 277 °C and from 300° to 340 °C, respectively. The pressure estimated from sphalerite geobarometry averages 2.1 kbar. This value corresponds to a moderately deep skarn and agrees with the high Cu content of the deposit. Paragenesis, P–T conditions and geological characteristics are compatible with a distal, dike-related, Zn skarn deposit. Its style of mineralization is similar to that of many high-temperature carbonate replacement skarn deposits in the Southern Cordillera.     

Triassic stretching directions in Iberia and North Africa inferred from magnetic fabrics

During the Triassic, Iberia and western North Africa displayed a unique situation in relation with the Central and North Atlantic opening and westward expansion of the Tethys. Unravelling the stretching direction in Triassic deposits of the studied area can help in our understanding of this scenario. The tectonic setting is characterized by localized basins with strong thickness variations greatly influenced by previous post‐Variscan mechanical discontinuities. In this work, we revise and compile magnetic fabric data from eight Triassic depocentres in terms of defining the stretching direction (i.e. magnetic lineation), resulting from extensional deformation of this period. Data show the importance of the opening of the Atlantic rift as the leading process during the Triassic. Dextral transtension can explain the deflection of the extensional direction observed in most studied depocentres that is caused by the activity of previous major oblique faults.