Ferrous phosphate surface precipitates resulting from the reduction of intragrain 6-line ferrihydrite by Shewanella oneidensis MR-1

The reductive biotransformation of 6-line ferrihydrite located within porous silica (intragrain ferrihydrite) by Shewanella oneidensis MR-1 was investigated and compared to the behavior of 6-line ferrihydrite in suspension (free ferrihydrite). The effect of buffer type (PIPES and NaHCO₃), phosphate (P), and an electron shuttle (AQDS) on the extent of reduction and formation of Fe(II) secondary phases was investigated under anoxic conditions. Electron microscopy and micro X-ray diffraction were applied to evaluate the morphology and mineralogy of the biogenic precipitates and to study the distribution of microorganisms on the surface of porous silica after bioreduction. Kinetic reduction experiments with free and intragrain ferrihydrite revealed contrasting behavior with respect to the buffer and presence of P. The overall amount of intragrain ferrihydrite reduction was less than that of free ferrihydrite [at 5 mmol L⁻¹ Fe(III)_T]. Reductive mineralization was not observed in the intragrain ferrihydrite incubations without P, and all biogenic Fe(II) concentrated in the aqueous phase. Irrespective of buffer and AQDS addition, rosettes of Fe(II) phosphate of approximate 20-30 μm size were observed on porous silica when P was present. The rosettes grew not only on the silica surface but also within it, forming a coherent spherical structure. These precipitates were well colonized by microorganisms and contained extracellular materials at the end of incubation. Microbial extracellular polymeric substances may have adsorbed Fe(II) promoting Fe(II) phosphate nucleation with subsequent crystal growth proceeding in different directions from a common center.     

Challenges of an integrated water resource management for the Distrito Federal, Western Central Brazil: climate, land-use and water resources

Land-use/cover change (LUCC) and climate change are major controlling factors for water resources in the Distrito Federal in Western Central Brazil. Dynamic LUCC in the region has severe impacts on water resources, while climate changes during the last three decades is thought to have only moderate effects. LUCC affects water quantity mostly during base flow conditions. River basins with substantial expansion of agriculture since the end 1970s show a dramatic decrease of base flow discharge by 40?C70%, presumably due to irrigation. In contrast, the effects of urbanization on runoff are less distinct, since factors controlling runoff generation might be more variable. For water quality, we found urban areas to have a strong influence on the parameters CSB, NH₄ ⁺, and suspended solids. In addition, we assume emerging pollutants, e.g. organic (micro)pollutants, might play a major role in the future. The project IWAS-áGUA DF focuses on creating the scientific base to face these problems in frame of an IWRM concept for the region. Results of our study will be a contribution to an IRWM concept for the Distrito Federal and will help to maintain high standards in water supply for the region.     

Assessment of cement’s dust impact on the soil using principal component analysis and GIS

To evaluate the impact of the cement’s dust emitted by the eastern Moroccan cement factory (Oujda Holcim) and deposited on the soil of the Ain Lahjar commune, 58 samples of soil were collected around the factory on a radius of 3 km approximately. The physicochemical analyses of the upper 3 cm of the soil surface samples correspond to the pH, electrical conductivity, the chlorides and the oxides of Ca, Al, Fe, K, Mn, S and Si which were analyzed by the fluorescence of X-rays. The preliminary results demonstrate that this dust are especially basic and contain a high free lime (43% CaO). The principal component analysis (applied on the 58 samples of soil) allows deducting that the free lime and the sulfur oxide are the tracer elements of this form of pollution. Furthermore, the spatial projection of the factor scores of the principal component analysis using the geographical information system permits to determine the spatial distribution of more polluted areas of soils as well as to estimate their surface (63.3% of the survey zone).     

Recent Progress and Future Prospects in Solar Physics, and Their Relevance for Planet Earth

Understanding our star, the Sun, is of fundamental interest for life on Earth. In this paper, the status of knowledge in solar physics of roughly two decades ago is summarised, and the most recent developments in this very active field are shown, many of them achieved by means of space based missions. The Sun–Earth connection is described and, finally, an outlook on future solar research is given.     

Optimal design of pumping tests in leaky aquifers for stream depletion analysis

We analyze the optimal design of a pumping test for estimating hydrogeologic parameters that are subsequently used to predict stream depletion caused by groundwater pumping in a leaky aquifer. A global optimization method is used to identify the test’s optimal duration and the number and locations of observation wells. The objective is to minimize predictive uncertainty (variance) of the estimated stream depletion, which depends on the sensitivities of depletion and drawdown to relevant hydrogeologic parameters. The sensitivities are computed analytically from the solutions of Zlotnik and Tartakovsky [Zlotnik, V.A., Tartakovsky, D.M., 2008. Stream depletion by groundwater pumping in leaky aquifers. ASCE Journal of Hydrologic Engineering 13, 43–50] and the results are presented in a dimensionless form, facilitating their use for planning of pumping test at a variety of sites with similar hydrogeological settings. We show that stream depletion is generally very sensitive to aquitard’s leakage coefficient and stream-bed’s conductance. The optimal number of observation wells is two, their optimal locations are one close to the stream and the other close to the pumping well. We also provide guidelines on the test’s optimal duration and demonstrate that under certain conditions estimation of aquitard’s leakage coefficient and stream-bed’s conductance requires unrealistic test duration and/or signal-to-noise ratio.     

Geochemistry and mineralogy of arsenic in (natural) anaerobic groundwaters

Here new data from field bioremediation experiments and geochemical modeling are reported to illustrate the principal geochemical behavior of As in anaerobic groundwaters. In the field bioremediation experiments, groundwater in Holocene alluvial aquifers in Bangladesh was amended with labile water-soluble organic C (molasses) and MgSO₄ to stimulate metabolism of indigenous SO₄-reducing bacteria (SRB). In the USA, the groundwater was contaminated by Zn, Cd and SO₄, and contained <10 μg/L As under oxidized conditions, and a mixture of sucrose and methanol were injected to stimulate SRB metabolism. In Bangladesh, groundwater was under moderately reducing conditions and contained ∼10 mg/L Fe and ∼100 μg/L As. In the USA experiment, groundwater rapidly became anaerobic, and dissolved Fe and As increased dramatically (As > 1000 μg/L) under geochemical conditions consistent with bacterial Fe-reducing conditions. With time, groundwater became more reducing and biogenic SO₄ reduction began, and Cd and Zn were virtually completely removed due to precipitation of sphalerite (ZnS) and other metal sulfide mineral(s). Following precipitation of chalcophile elements Zn and Cd, the concentrations of Fe and As both began to decrease in groundwater, presumably due to formation of As-bearing FeS/FeS₂. By the end of the six-month experiment, dissolved As had returned to below background levels. In the initial Bangladesh experiment, As decreased to virtually zero once biogenic SO₄ reduction commenced but increased to pre-experiment level once SO₄ reduction ended. In the ongoing experiment, both SO₄ and Fe(II) were amended to groundwater to evaluate if FeS/FeS₂ formation causes longer-lived As removal. Because As-bearing pyrite is the common product of SRB metabolism in Holocene alluvial aquifers in both the USA and Southeast Asia, it was endeavored to derive thermodynamic data for arsenian pyrite to better predict geochemical processes in naturally reducing groundwaters. Including the new data for arsenian pyrite into Geochemist’s Workbench, its stability field completely dominates in reducing Eh–pH space and “displaces” other As-sulfides (orpiment, realgar) that have been implied to be important in previous modeling exercises and reported in rare field conditions.     

能源与全球环境

目前,“可再生能源”这个词已进入技术发展的阶段。我们目前利用的能源是不可再生的。我们生活在都市中。由于太阳光照射1小时的能量即可满足我们一年的能源需要,今后的能源利用必定要考虑太阳能。利用地球内部的热量梯度即地热能在今后亦是诱人的。原子能尤其是聚变能的潜力极大,但尚没有迹象表明,人类非得将精力消耗在利用裂变能上不可,尽管目前这方面的技术有被滥用的趋势。     

Seismic Hazard Studies in the U.K.: Source Specification Problems of Intraplate Seismicity

Although the U.K. is in an area of only low to moderate seismicity, the seismic hazard is sufficient to pose a threat to sensitive structures such as chemical plants and nuclear facilities. In quantifying the level of hazard by conventional probabilistic methodology, however, some problems arise in attempting to interpret earthquake data in terms of geological structure and faults. In the U.K., not only is it impossible to identify any demonstrably active faults, but also it is extremely difficult to discern any relationship between the pattern of seismicity and local or regional geological structure.This study discusses the use of two zonation approaches which complement each other in such a way that the general character and trend of seismicity is preserved. In one approach, the zonation is informed by the structural geology, where possible; geological zonation is avoided if it produces sources with heterogeneous seismicity. In the other approach, the record of past earthquakes is divided up into very small zones around individual epicentres or groups of epicentres, the size of each zone usually being proportional to the uncertainty in the epicentral determination of the appropriate event. This zonation preserves an observed tendency of some British earthquakes to repeat themselves. It is suggested that, in intraplate areas such as the U.K., it is often inappropriate to attempt to model individual fault sources. No faults in the U.K. are provably active. Because an earthquake of moderate size can occur on a very short fault segment, it is impractical to restrict fault modelling to major features. Even the two largest U.K. faults, suspected to be active, pose problems in attributing historical seismicity to them as distinct features.     

Weathering of phlogopite in simulated bioleaching solutions

The purpose of this study was to examine structural alterations of finely ground phlogopite, a trioctahedral mica, when exposed to acid, iron- and sulfate-rich solutions typical of bioleaching systems. Phlogopite suspensions were supplemented with ferrous sulfate and incubated with iron- and sulfur-oxidizing bacteria (Acidithiobacillus ferrooxidans) at 22 °C. As bacteria oxidized ferrous iron, ferric iron thus formed partially precipitated as K-jarosite. K-jarosite precipitation was contingent on the preceding ferrous iron oxidation by bacteria and the release of interlayer-K from phlogopite. This chemically and microbially induced weathering involved alteration of phlogopite to a mixed layer structure that included expansible vermiculite. The extent of phlogopite weathering and structure expansion varied with duration of the contact, concentration of ferrous iron and phlogopite, and the presence of monovalent cations (NH₄⁺, K⁺, or Na⁺) in the culture solution. NH₄⁺ and K⁺ ions (100 mM) added to culture suspensions precipitated as jarosite and thereby effectively prevented the loss of interlayer-K and structural alteration of phlogopite. Additional Na⁺ (100 mM) was insufficient to precipitate ferric iron as natrojarosite and therefore the precipitation was coupled with interlayer-K released from phlogopite. When ferrous iron was replaced with elemental sulfur as the substrate for A. ferrooxidans, the weathering of phlogopite was based on chemical dissolution without structural interstratification. The results demonstrate that iron oxidation and the concentration and composition of monovalent ions can have an effect on mineral weathering in leaching systems that involve contact of phlogopite and other mica minerals with acid leach solutions.