The solubility of calcite and aragonite in seawater of 35%. salinity at 25°C and atmospheric pressure

The solubilities of synthetic, natural and biogenic aragonite and calcite, in natural seawater of 35%. salinity at 25°C and 1 atm pressure, were measured using a closed system technique. Equilibration times ranged up to several months. The apparent solubility constant determined for calcite of 4.39(±0.20) × 10^?7 mol² kg^?2 is in good agreement with other recent solubility measurements and is constant after 5 days equilibration. When we measured aragonite solubility we observed that it decreased with increasing time of equilibration. The value of 6.65(±0.12) × 10^?7 mol² kg^?2, determined for equilibration times in excess of 2 months, is significantly less than that found in other recent measurements, which employed equilibration times of only a few hours to days. No statistically significant difference was found among the synthetic, natural and biogenic material. Solid to solution ratio, contamination of aragonite with up to 10 wt% calcite and recycling of the aragonite made no statistically significant difference in solubility when long equilibration times were used.Measured apparent solubility constants of aragonite and calcite are respectively 22( ± 3)% and 20( ± 2)% less than apparent solubility constants calculated from thermodynamic equilibrium constants and seawater total activity coefficients. These large differences in measured and calculated apparent solubility constants may be the result of the formation of surface layers of lower solubility than the bulk solid.     

The Gulf of California: Review of ecosystem status and sustainability challenges

The Gulf of California is unique because of its geographical location and conformation. It hosts diverse ecosystems and important fisheries that support industry and provide livelihood to coastal settlements. It is also the site of interests and problems, and an intense interaction among managers, producers, and conservationists. In this report, we scrutinize the abiotic (hydrography, climate, ocean circulation, and chemistry) and biotic (phyto- and zooplankton, fish, invertebrates, marine mammals, birds, and turtles) components of the marine ecosystem, and some particular aspects of climate variability, endemisms, harmful algal blooms, oxygen minimum layer, and pollution. We also review the current conditions and conflicts around the main fisheries (shrimp, small and large pelagic fishes, squid, artisanal and sportfishing), the most important human activity in the Gulf of California. We cover some aspects of management and conservation of fisheries, especially the claimed overexploitation of fish resources and the ecosystems, and review proposals for creating networks of marine protected areas. We conclude by identifying main needs for information and research, particularly the integration of data bases, the implementation of models and paleoreconstructions, establishment of monitoring programs, and the evaluation of fishing impacts and management actions.     

Assessing Groundwater Depletion and Dynamics Using GRACE and InSAR: Potential and Limitations

In the last decade, remote sensing of the temporal variation of ground level and gravity has improved our understanding of groundwater dynamics and storage. Mass changes are measured by GRACE (Gravity Recovery and Climate Experiment) satellites, whereas ground deformation is measured by processing synthetic aperture radar satellites data using the InSAR (Interferometry of Synthetic Aperture Radar) techniques. Both methods are complementary and offer different sensitivities to aquifer system processes. GRACE is sensitive to mass changes over large spatial scales (more than 100,000 km²). As such, it fails in providing groundwater storage change estimates at local or regional scales relevant to most aquifer systems, and at which most groundwater management schemes are applied. However, InSAR measures ground displacement due to aquifer response to fluid‐pressure changes. InSAR applications to groundwater depletion assessments are limited to aquifer systems susceptible to measurable deformation. Furthermore, the inversion of InSAR‐derived displacement maps into volume of depleted groundwater storage (both reversible and largely irreversible) is confounded by vertical and horizontal variability of sediment compressibility. During the last decade, both techniques have shown increasing interest in the scientific community to complement available in situ observations where they are insufficient. In this review, we present the theoretical and conceptual bases of each method, and present idealized scenarios to highlight the potential benefits and challenges of combining these techniques to remotely assess groundwater storage changes and other aspects of the dynamics of aquifer systems.     

Development and Application of 2D and 3D GRASS Modules for Simulation of Thermally Driven Slope Winds

The ability to manage and process fully three‐dimensional information has only recently been made available for a few Geographical Information Systems (GIS). An example of integrated and complementary use of 2D and 3D GRASS modules for the evaluation and representation of thermally induced slope winds over complex terrain is presented. The analytic solution provided by Prandtl (1942) to evaluate wind velocity and (potential) temperature anomaly induced by either diurnal heating or nocturnal cooling on a constant angle slope is adopted to evaluate wind and temperature profiles at any point over both idealised and real complex terrain. As these quantities depend on the slope angle of the ground and on the distance from the slope surface suitable procedures are introduced to determine the coordinate n of a point in the 3D volume measured along the direction locally normal to the terrain surface. A new GRASS module has been developed to evaluate this quantity and to generate a 3D raster file where each cell is assigned the value of the cell on the surface belonging to the normal vector. The application of the algorithm implemented in GRASS to an ideal valley and to a real valley close to the city of Trento in the Alps provides results in accordance with data reported in the literature. An extension of Prandtl's (1942) model to take into account humidity and evaporation processes on the soil is also proposed and implemented.     

Genesis of sulfide-rich chromite ores by the interaction between chromitite and pegmatitic olivine–norite dikes in the Potosí Mine (Moa-Baracoa ophiolitic massif, eastern Cuba)

The Potosí Mine is located in the Moa-Baracoa massif in the easternmost part of the Cuban Ophiolitic Belt. Chromite mineralization occurs within the mantle-crust transition zone. Two events of magma intrusion overprint the chromitite bodies: one gave rise to the crystallization of pegmatitic olivine-norite dikes, and the other produced pegmatitic gabbro dikes. Sulfide-poor chromite ores, brecciated chromite ores, and sulfide-rich chromite ores can be distinguished in the different chromitite bodies. Sulfide-poor ores represent more than 80 vol% of the chromitites. This type occurs far from the zones intruded by pegmatitic gabbro dikes and shows petrographic and chemical features similar to other chromitite bodies described in the Moa-Baracoa massif. Brecciated chromite ores occur within pegmatitic gabbro dikes. In this type, chromite crystals occur included within chromian diopside and plagioclase. These silicates often contain droplet-like sulfide aggregates. Sulfide-rich ores are spatially associated to the contacts between sulfide-poor chromite and pegmatitic olivine-norite dikes. These ores mainly consist of recrystallized (coarse) chromite with interstitial pyrrhotite, pentlandite, cubanite, and chalcopyrite. Chromite from sulfide-rich ores exhibits TiO₂, FeO, V₂O₃, MnO, and especially, Fe₂O₃ contents, higher than those of chromite from brecciated ores and much higher than those of chromite from sulfide-poor ores. The sulfide-rich ores are PGE-rich (up to 1,113 ppb of total PGE), and show nearly flat chondrite-normalized PGE patterns, slightly above 0.1 times chondritic values. Mineralogical and chemical data indicate that the chromite ores of the Potosí Mine were modified by the intrusions of olivine-norite and gabbro dikes. The interaction between pre-existing sulfide-poor chromite ores and the intruding volatile-rich silicate melts produced strong brecciation, partial dissolution, and recrystallization (coarsening) of chromite. The sulfide assemblage formed by fractionation of the immiscible sulfide melt segregated from the volatile-rich silicate melt that generated the pegmatitic olivine-norite. The segregation of the sulfide melt can be interpreted as the consequence of chemical interaction between intruding melts and the host chromite. The variable extent of this interaction produced chromite ores with variable sulfide ratios. The magmatic nature of the sulfide mineralization is supported by sulfur isotope data, which range from -0.4 to +0.9‰. Sulfide melt collected incompatible PGE (Rh, Pt, Pd) to produce the typical flat chondrite-normalized pattern of sulfide-rich chromite ores.     

Aptian bio-events—an integrated biostratigraphic analysis of the Almadich Formation, Inner Prebetic Domain, SE Spain

The Upper Barremian to Aptian Almadich Formation (Inner Prebetic Domain of the Betic Cordillera) is composed of hemipelagic sediments deposited on a distal carbonate ramp in the southern Iberian Palaeomargin. Within this facies we have found a thick interval of blue to black shales and marls that is interpreted as deposited under oxygen-depleted conditions. We think that this interval, dated as early Aptian, represents the local record of Ocean Anoxic Event 1a. The integrated biostratigraphic analysis of a section in the Almadich Formation, by means of planktonic foraminifera, calcareous nannofossils and ammonites, enables us to recognize most of the biostratigraphic units based on these three fossil groups and to correlate between them. The Sartousiana, Sarasini, Weissi, Deshayesi and Furcata (ammonite) Zones were identified for the Upper Barremian–Lower Aptian interval. By means of calcareous nannofossil biostratigraphy the Micrantholithus hoschulzii, Hayesites irregularis and Rhagodiscus angustus Zones, plus several additional biohorizons, were identified. A quantitative study performed on a set of 27 Lower Aptian samples has enabled the precise identification of the ‘nannoconid crisis’, the lower limit of which clearly precedes the main anoxic event, and its correlation with other bioevents. Planktonic foraminifera occur consistently throughout the Lower to Upper Aptian of the Cau section and are moderately well preserved. This fact allows us to use the most recent taxonomic framework, based on wall texture, to identify the Blowiella blowi, Schackoina cabri, Globigerinelloides ferreolensis, Globigerinelloides algerianus, Hedbergella trocoidea andTicinella bejaouaensis Zones. Coincident with the anoxic episode, the planktonic foraminiferal assemblages are composed of a significant number of forms with elongated chambers and/or tubulospines assigned to the genera Claviblowiella,Lilliputianella , Leupoldina and Schackoina. Most of the planktonic foraminiferal and nannofossil taxa are illustrated.     

Sigseg: a tool for the detection of position and velocity discontinuities in geodetic time-series

The detection of discontinuities in geodetic data is an ever more important topic due to both the influence of discontinuities on the results of models and analyses, and to the very meaning of discontinuities in physical phenomena. We consider and describe a mathematical model, originally formulated for the approximation of images by smooth functions, in one dimension (1D). The model had been designed to smooth the data while preserving and detecting its discontinuities following a variational approach. A second and more complex model for the approximation of images by functions with smooth first derivatives is also available. This second model had been designed to smooth the data while preserving and detecting the discontinuities of the data, but also those of the first derivative. Such interesting features suggest the chance to apply this second model to 1D geodetic data, in particular for the detection of discontinuities and velocity changes in position time-series rather than for signal smoothing. The sigseg (signal segmentation) program implements the two variational models in 1D and is presented with applications to geodetic data. The essential mathematical elements are sketched, and some details on the numerical implementation are given.     

A nocturnal atmospheric loss of CH<Subscript>2</Subscript>I<Subscript>2</Subscript> in the remote marine boundary layer

Ocean emissions of inorganic and organic iodine compounds drive the biogeochemical cycle of iodine and produce reactive ozone-destroying iodine radicals that influence the oxidizing capacity of the atmosphere. Di-iodomethane (CH₂I₂) and chloro-iodomethane (CH₂ICl) are the two most important organic iodine precursors in the marine boundary layer. Ship-borne measurements made during the TORERO (Tropical Ocean tRoposphere Exchange of Reactive halogens and Oxygenated VOC) field campaign in the east tropical Pacific Ocean in January/February 2012 revealed strong diurnal cycles of CH₂I₂ and CH₂ICl in air and of CH₂I₂ in seawater. Both compounds are known to undergo rapid photolysis during the day, but models assume no night-time atmospheric losses. Surprisingly, the diurnal cycle of CH₂I₂ was lower in amplitude than that of CH₂ICl, despite its faster photolysis rate. We speculate that night-time loss of CH₂I₂ occurs due to reaction with NO₃ radicals. Indirect results from a laboratory study under ambient atmospheric boundary layer conditions indicate a k _CH2I2+NO3 of ≤4 × 10^?13 cm³ molecule^?1 s^?1; a previous kinetic study carried out at ≤100 Torr found k _CH2I2+NO3 of 4 × 10^?13 cm³ molecule^?1 s^?1. Using the 1-dimensional atmospheric THAMO model driven by sea-air fluxes calculated from the seawater and air measurements (averaging 1.8 +/? 0.8 nmol m^?2 d^?1 for CH₂I₂ and 3.7 +/? 0.8 nmol m^?2 d^?1 for CH₂ICl), we show that the model overestimates night-time CH₂I₂ by >60 % but reaches good agreement with the measurements when the CH₂I₂ + NO₃ reaction is included at 2–4 × 10^?13 cm³ molecule^?1 s^?1. We conclude that the reaction has a significant effect on CH₂I₂ and helps reconcile observed and modeled concentrations. We recommend further direct measurements of this reaction under atmospheric conditions, including of product branching ratios.     

The evolution of disk galaxies in clusters

We are carrying out a programme to measure the evolution of the stellar and dynamical masses and M/L ratios for a sizeable sample of morphologically-classified disk galaxies in rich galaxy clusters at 0.2 < z < 0.9. Using FORS2 at the VLT we are obtaining rotation curves for the cluster spirals so that their Tully-Fisher relation can be studied as a function of redshift and compared with that of field spirals. We already have rotation curves for ∼ 10 cluster spirals at z = 0.83, and 25 field spirals at lower redshifts and we plan to increase this sample by one order of magnitude. We present here the first results of our study, and discuss the implications of our data in the context of current ideas and models of galaxy formation and evolution. This revised version was published online in September 2006 with corrections to the Cover Date.