Radial velocities in the open cluster IC 2602

We determined radial velocities for 25 probable members of the open cluster IC 2602. We identified the stars with variable radial velocity. We improved the orbit of HD 93030, and computed a preliminary orbit for another spectroscopic binary. We discussed with such data the average cluster radial velocity and we compare the incidence of short period binaries among the Main-Sequence members of IC 2602 with the incidence for other clusters with different values of the average axial rotation of their members.Cerro Tololo Interamerican Observatory operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.     

Water quality and presence of pesticides in a tropical coastal wetland in southern Mexico

The water quality of the Pozuelos-Murillo lagoon system in southern Mexico was evaluated during three periods between March and October 2002, with particular emphasis on the detection of organochlorine and organophosphorous pesticide residues in water and sediments. Physicochemical and microbiological parameters of water were also measured and integrated in a water quality index (WQI). Multivariate analysis was used to regionalise the lagoon system as a function of the behaviour of all measured parameters. Solid phase micro-extraction followed by gas chromatography (SPME-GC) was used for pesticide analysis. The concentration of phosphorous was found to be higher than that of nitrogenous compounds. This, besides a deficiency in dissolved oxygen and a high organic matter concentration (as COD), reflects eutrophication processes in some areas of the system. Measured levels of faecal coliforms and oils and greases were above the limits established by Mexican law and comparable to the concentrations reported for other highly polluted systems in Mexico. Residues of DDD (2.0 microg L(-1)) in water and DDE (247 ng g(-1)) and endosulfan I (814 ng g(-1)) sediments were detected by SPME-GC. The spatial distribution of these contaminants implies major potential risks because the most polluted sites were found to be those with the highest fishing activity. Although in general the WQI is on acceptable levels (65-80%), some contamination problems are evident.     

Kinetics of the reactions of Cl atoms with 2-buten-1-ol, 2-methyl-2-propen-1-ol, and 3-methyl-2-buten-1-ol as a function of temperature

The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221) and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data were used to derive the Arrhenius expressions , , (in units of cm³ molecule⁻¹ s⁻¹). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO₃, O₃ and Cl have been calculated.     

The STAGES view of red spirals and dusty red galaxies: mass-dependent quenching of star formation in cluster infall

We investigate the properties of optically passive spirals and dusty red galaxies in the A901/2 cluster complex at redshift ∼0.17 using rest-frame near-ultraviolet–optical spectral energy distributions, 24-μm infrared data and Hubble Space Telescope morphologies from the STAGES data set. The cluster sample is based on COMBO-17 redshifts with an rms precision of  σ _cz ≈ 2000 km s⁻¹  . We find that 'dusty red galaxies' and 'optically passive spirals' in A901/2 are largely the same phenomenon, and that they form stars at a substantial rate, which is only four times lower than that in blue spirals at fixed mass. This star formation is more obscured than in blue galaxies and its optical signatures are weak. They appear predominantly in the stellar mass range of  log  M _*/M_⊙=[10, 11]  where they constitute over half of the star-forming galaxies in the cluster; they are thus a vital ingredient for understanding the overall picture of star formation quenching in clusters. We find that the mean specific star formation rate (SFR) of star-forming galaxies in the cluster is clearly lower than in the field, in contrast to the specific SFR properties of blue galaxies alone, which appear similar in cluster and field. Such a rich red spiral population is best explained if quenching is a slow process and morphological transformation is delayed even more. At  log  M _*/M_⊙ < 10  , such galaxies are rare, suggesting that their quenching is fast and accompanied by morphological change. We note that edge-on spirals play a minor role; despite being dust reddened they form only a small fraction of spirals independent of environment.     

The El Teniente porphyry Cu–Mo deposit from a hydrothermal rutile perspective

Mineralogical, textural, and chemical analyses (EPMA and PIXE) of hydrothermal rutile in the El Teniente porphyry Cu–Mo deposit help to better constrain ore formation processes. Rutile formed from igneous Ti-rich phases (sphene, biotite, Ti-magnetite, and ilmenite) by re-equilibration and/or breakdown under hydrothermal conditions at temperatures ranging between 400°C and 700°C. Most rutile nucleate and grow at the original textural position of its Ti-rich igneous parent mineral phase. The distribution of Mo content in rutile indicates that low-temperature (∼400–550°C), Mo-poor rutile (5.4 ± 1.1 ppm) is dominantly in the Mo-rich mafic wallrocks (high-grade ore), while high-temperature (∼550-700°C), Mo-rich rutile (186 ± 20 ppm) is found in the Mo-poor felsic porphyries (low-grade ore). Rutile from late dacite ring dikes is a notable exception to this distribution pattern. The Sb content in rutile from the high-temperature potassic core of the deposit to its low-temperature propylitic fringe remains relatively constant (35 ± 3 ppm). Temperature and Mo content of the hydrothermal fluids in addition to Mo/Ti ratio, modal abundance and stability of Ti-rich parental phases are key factors constraining Mo content and provenance in high-temperature (≥550°C) rutile. The initial Mo content of parent mineral phases is controlled by melt composition and oxygen fugacity as well as timing and efficiency of fluid–melt separation. Enhanced reduction of SO₂-rich fluids and sulfide deposition in the Fe-rich mafic wallrocks influences the low-temperature (≤550°C) rutile chemistry. The data are consistent with a model of fluid circulation of hot (>550°C), oxidized (ƒO₂ ≥ NNO + 1.3), SO₂-rich and Mo-bearing fluids, likely exsolved from deeper crystallizing parts of the porphyry system and fluxed through the upper dacite porphyries and related structures, with metal deposition dominantly in the Fe-rich mafic wallrocks.     

Late Pleistocene climate of the northern Iberian Peninsula: New insights from palaeoglaciers at Fuentes Carrionas (Cantabrian Mountains)

New ¹⁰Be dates for glacial landforms in the Fuentes Carrionas area (Cantabrian Mountains, nothern Spain) are presented. Mapped and dated landforms in Fuentes Carrionas made possible a palaeoglacier reconstruction for four glacial stages. Results were compared to other nearby palaeoenvironmental proxies, so a final approximation on the mean annual temperature and annual precipitation that caused the four glacial advance stages is proposed. Glaciers reached their maximum extension at 36 ka, in a cold and dry environment. A second advance stage took place between 18.5 and 19.5 ka, during the Last Glacial Maximum (LGM), when glaciers advanced in a wet environment, with positive rainfall anomalies. A third glacial advance was dated during the Oldest Dryas, in which climate shifted to extremely cold and dry conditions. Finally, a last stage has been identified and proposed to the Younger Dryas, in which precipitation anomalies are negligible. Our results confirm some of the previously made palaeoglacial and palaeoenvironmental inferences for the Iberian Peninsula, as well as provide valuable and accurate anomalies, which are useful for climate modelling.     

Benthos of a perennially-astatic, saline, soda lake in Mexico

The effects of multiple stressors on the benthic macroinvertebrate community were monitored in Tecuitlapa Norte, a shallow, perennially-astatic, warm, mesosaline, sodaalkaline lake in Mexico. Physico-chemical and biological variables were determined monthly for one year. Tecuitlapa Norte displayed a clear seasonal environmental pattern (dry and rainy seasons). The benthic macroinvertebrate community consisted of five species:Culicoides occidentalis sonorensis Jorgensen,Ephydra hians Say,Stratiomys sp.,Eristalis sp., andLimnophora sp. of which the first two were dominant and the rest scarce.C. occidentalis was the most important species numerically (76 percent of the total), whileE. hians dominated the biomass (73 percent of the total). Primarily salinity and secondarily pH appear to be the most important environmental factors controlling dominance of benthic organisms in Tecuitlapa Norte. Seasonal abundance dynamics of the dominant organisms was associated with phases in their reproductive cycles: environmentally-triggered (i.e., temperature rise, water-level descent) pupation and emergence periods. We concluded that whereas physical and chemical factors (i.e., salinity, pH) exerted the primary control on benthic macroinvertebrate community composition in Tecuitlapa Norte, another assembly of variables (e.g., water-level, temperature) influenced species distribution and abundance.     

The Almadén mercury mining district, Spain

The Almadén district is the largest mercury concentration in the world, with a total content of about 250 000 t of mercury, nearly one third of the known total mercury resources of the Earth. Mercury has been exploited since the Celtic and Roman times, with peak production during the Renaissance and between 1939–1945. The district is hosted by a Paleozoic synclinorium overlying Precambrian rocks. The Paleozoic sequence comprises epicontinental quartz arenite rocks, including black shales and quartzites. Diatremes, alkaline lavas of different composition, and late tholeiitic diabases account for the Ordovician to Devonian magmatism. The tectonic setting of this complex suite corresponds to the intraplate type. The mercury deposits of Almadén can be classified into two main types: type 1, early stratiform type ores characterized by cinnabar deposition on the lower Silurian quartzites (Criadero quartzite; e.g. the Almadén and El Entredicho deposits), and type 2, late discordant orebodies (e.g. Las Cuevas), largely hosted or related to diatremes (the `frailesca rocks') of alkaline basaltic composition. In type 1 cinnabar was deposited during diagenesis, in relation to hydrothermal circulation driven by magmatic activity. Type 2 include a variety of deposits having in common the discordant character of the orebodies (e.g. veins, stockworks, massive replacements), and their wide dispersion along the stratigraphic column, i.e. from Lower Silurian (e.g. Nueva Concepción) to Upper Devonian (e.g. Corchuelo). Received: 23 October 1998 / Accepted: 4 January 1999