Chemical composition of spinel from Uralian-Alaskan-type Mafic–Ultramafic complexes and its petrogenetic significance

Uralian-Alaskan-type mafic–ultramafic complexes are recognized as a distinct class of intrusions regarding lithologic assemblage, mineral chemistry and petrogenetic setting. In the present study, we discuss new data on the distribution of major elements in minerals of the spinel group in rocks from Uralian-Alaskan-type complexes in the Ural Mountains, Russia. Cr-rich spinel (Cr₂O₃ = 20–53 wt%) in dunite with interstitial clinopyroxene and in wehrlite cumulates indicate that it reacted with interstitial liquid resulting in the progressive substitution of Al₂O₂ and Cr₂O₃ by Fe₂O₃ and TiO₂. A distinct change in the spinel chemistry in dunite (Cr₂O₃ = 47–53 wt%), towards Al₂O₃- and Cr₂O₃-poor but Fe₂O₃-rich compositions monitors the onset of clinopyroxene fractionation in wehrlite (Cr₂O₃ = 15–35 wt%, Al₂O₃ = 1–8 wt%, Fe₂O₃ = 25–55 wt%). In more fractionated mafic rocks, the calculated initial composition of exsolved spinel traces the sustained crystallization of clinopyroxene by decreasing Cr₂O₃ and increasing FeO, Fe₂O₃ and fO₂. Finally, the initiation of feldspar crystallization buffers the Al₂O₃ content in most of the spinels in mafic rocks at very low Cr₂O₃ contents (<5 wt%). The fractionation path all along and the reaction with interstitial liquid are accompanied by increasing Fe₂O₃ contents in the spinel. This likely is caused by a significant increase in the oxygen fugacity, which suggests closed system fractionation processes. Spinel with Cr₂O₃ < 27 wt% is exsolved into a Fe₂O₃-rich and an Al₂O₃-rich phase forming a variety of textures. Remarkably, exsolved spinel in different lithologies from complexes 200 km apart follows one distinct solvus line defining a temperature of ca. 600°C. This indicates that the parental magmas were emplaced and eventually cooled at similar levels in the lithosphere, likely near the crust–mantle boundary. Eventually, these 600°C hot bodies were rapidly transported into colder regions of the upper crust during a regional tectonic event, probably during the major active phase of the Main Uralian Fault.     

3-D assessment of peak-metamorphic conditions by Raman spectroscopy of carbonaceous material: an example from the margin of the Lepontine dome (Swiss Central Alps)

This study monitors regional changes in the crystallinity of carbonaceous matter (CM) by applying Micro-Raman spectroscopy to a total of 214 metasediment samples (largely so-called Bündnerschiefer) dominantly metamorphosed under blueschist- to amphibolite-facies conditions. They were collected within the northeastern margin of the Lepontine dome and easterly adjacent areas of the Swiss Central Alps. Three-dimensional mapping of isotemperature contours in map and profile views shows that the isotemperature contours associated with the Miocene Barrow-type Lepontine metamorphic event cut across refolded nappe contacts, both along and across strike within the northeastern margin of the Lepontine dome and adjacent areas. Further to the northeast, the isotemperature contours reflect temperatures reached during the Late Eocene subduction-related blueschist-facies event and/or during subsequent near-isothermal decompression; these contours appear folded by younger, large-scale post-nappe-stacking folds. A substantial jump in the recorded maximum temperatures across the tectonic contact between the frontal Adula nappe complex and surrounding metasediments indicates that this contact accommodated differential tectonic movement of the Adula nappe with respect to the enveloping Bündnerschiefer after maximum temperatures were reached within the northern Adula nappe, i.e. after Late Eocene time.     

Zur Dynamotheorie stellarer und planetarer Magnetfelder I. Berechnung sonnenähnlicher Wechselfeldgeneratoren

Non-reflectionsymmetric turbulent motions in an electrically conducting fluid provide for an average electromotoric force α parallel to the average magnetic field . This effect – furthermore called α-effect – can lead to a self-excited built-up of magnetic fields by dynamo action. Since by actions of Coriolis forces turbulent motions in rotating systems generally are non-reflectionsymmetric, the explanation of stellar and planetary magnetic fields becomes possible. – In this first part spherical alternating field dynamos are calculated on conditions similar to those at the sun; α-effect and differential rotation provide for dynamo action. – The basic equations, which form a system of partial differential equations, are treated by a separation method; in this way our problem is transformed into a two-parametric eigenvalue problem for an infinite system of ordinary differential equations. The two eigenvalues determine the frequency and the amount of the induction actions necessary for the field maintenance. The solution of this problem was made by an electronic computer. – The results give evidence for the possibility of magnetohydrodynamic alternating field dynamos. Furthermore the magnitude of the calculated eigenvalues and the similarities between the calculated field and the observed solar magnetic field are showing that the sun realizes a dynamo of this kind.     

Differences in grain growth of calcite: a field-based modeling approach

Normal grain growth of calcite was investigated by combining grain size analysis of calcite across the contact aureole of the Adamello pluton, and grain growth modeling based on a thermal model of the surroundings of the pluton. In an unbiased model system, i.e., location dependent variations in temperature-time path, 2/3 and 1/3 of grain growth occurs during pro- and retrograde metamorphism at all locations, respectively. In contrast to this idealized situation, in the field example three groups can be distinguished, which are characterized by variations in their grain size versus temperature relationships: Group I occurs at low temperatures and the grain size remains constant because nano-scale second phase particles of organic origin inhibit grain growth in the calcite aggregates under these conditions. In the presence of an aqueous fluid, these second phases decay at a temperature of about 350 °C enabling the onset of grain growth in calcite. In the following growth period, fluid-enhanced group II and slower group III growth occurs. For group II a continuous and intense grain size increase with T is typical while the grain growth decreases with T for group III. None of the observed trends correlate with experimentally based grain growth kinetics, probably due to differences between nature and experiment which have not yet been investigated (e.g., porosity, second phases). Therefore, grain growth modeling was used to iteratively improve the correlation between measured and modeled grain sizes by optimizing activation energy (Q), pre-exponential factor (k₀) and grain size exponent (n). For n=2, Q of 350 kJ/mol, k₀ of 1.7×10²¹ mⁿs^–1 and Q of 35 kJ/mol, k₀ of 2.5×10^-5 mⁿs^–1 were obtained for group II and III, respectively. With respect to future work, field-data based grain growth modeling might be a promising tool for investigating the influences of secondary effects like porosity and second phases on grain growth in nature, and to unravel differences between nature and experiment.Editorial responsibility: J. Hoefs     

On different time scales of suspended matter dynamics in the Weser estuary

Long-term observations in the Weser estuary (Germany) between 1983 and 1997 provide insight into the response of the estuarine turbidity maximum (ETM) under a wide range of conditions. In this estuary the turbidity zone is closely tied to the mixing zone, and the positions of the ETM and the mixing zone vary with runoff. The intratidal suspended particulate matter (SPM) concentrations vary due to deposition during slack water periods, subsequent resubsequent and depletion of temporarily-formed and spatially-limited deposits during the following ebb or flood, and subsequent transport by tidal currents. The corresponding time history of SPM concentrations is remarkably constant over the years. Spring tide SPM concentrations can be twice the neap tide concentrations or even larger. A hysteresis in SPM levels between the falling and rising spring-neap cycle is attributed to enhanced resuspension by the stronger spring tidal currents. There is evidence that the ETM is pushed up-estuary during times of higher mean water levels due to storms. During river floods the ETM is flushed towards the outer estuary. If river floods and their decreasing parts occur during times of relatively high mean water levels, the ETM seems to be maintained in the outer estuary. If river floods and their decreasing parts occur during times of relatively low mean water levels, the ETM seems to loose inventory and may need up to half a year of non-event conditions to gain its former magnitude. During this time seasonal effects may be involved. Analyses of storm events and river floods have revealed that the conditions in the seaward boundary region play an equally important role for the SPM dynamics as those arising from the river.     

Crop yield response to economic, site and climatic variables

This paper examines the effects of climatic and non-climatic factors on the mean and variance of corn, soybean and winter wheat yield in southwestern Ontario, Canada over a period of 26 years. Average crop yields increase at a decreasing rate with the quantity of inputs used, and decrease with the area planted to the crop. Climate variables have a major impact on mean yield with the length of the growing season being the primary determinant across all three crops. Increases in the variability of temperature and precipitation decrease mean yield and increase its variance. Yield variance is poorly explained by both seasonal and monthly climate variable models. Projections of future climate change suggest that average crop yield will increase with warmer temperatures and a longer growing season which is only partially offset by forecast increases in the variability of temperature and rainfall. The projections would also depend on future technological developments, which have generated significant increases in yield over time despite changing annual weather conditions.     

Climate change and human activities: a case study in Xinjiang, China

We examined both long-term climate variability and anthropogenic contributions to current climate change for Xinjiang province of northwest China. Xinjiang encompasses several mountain ranges and inter-mountain basins and is comprised of a northern semiarid region and a more arid southern region. Climate over the last three centuries was reconstructed from tree rings and temperature series were calculated for the past 50 years using weather station data. Three major conclusions from these analyses are: (1) Although temperature varied considerably in Xinjiang over the last 200 years, it was non-directional until the last 50 years when a substantial warming trend occurred; (2) The semiarid North Xinjiang was representative of the northern hemisphere climate, while the more arid South Xinjiang resembled the southern hemisphere climate, meanwhile, (3) The entire Xinjiang province captured the global-scale climate signal. We also compared human contributions to global change between North and South Xinjiang, including land cover/land use, population, and greenhouse gas production. For both regions, urban areas acted as heat islands; and large areas of grassland and forest were converted to barren land, especially in North Xinjiang. Additionally, North Xinjiang also showed larger increase in population and greenhouse gas emissions mainly associated with animal production than those in South Xinjiang. Although Xinjiang province is a geographically coupled mountain–basin system, the two regions have distinct climate patterns and anthropogenic activities related to land cover conversion and greenhouse gas production.     

Móron fault zone,north-central Venezuelan borderland: Identification,definition, and neotectonic character

Location of the southern Caribbean plate boundary has been hindered mainly because it is in large part submerged. Analysis of 28 acoustic reflection profiles along the north-central Venezuelan borderland, and a review of published data, suggest that this borderland is the site of a complex fault zone, formally defined as the Morón fault zone, which encompasses the nodal region of the Boconó-Oca-El Pilar fault system. The Morón fault zone consists of: (1) an eastward extension of the Oca-Chirinos fault zone at about 10° 50′ N latitude; (2) a probable eastward continuation of the Boconó-Morón faults along the Venezuelan coast, which splits into the Avila and Macuto faults, north and east of Caracas; (3) the Tacagua fault, which is a southeastward trending splinter fault of the Oca-Chirinos fault zone; (4) and the westward extension of the Cariaco pull-apart basin and the El Pilar fault zone. All of these faults and fault zones are active, as shown by offset sea bottom, offset Pleistocene-Holocene features, and seismicity. It is suggested that the Oca-Chirinos fault zone represents a formerly more active part of the plate boundary. Since the Late Tertiary (?) or Quaternary, the Boconó fault zone was incorporated into the plate boundary, and the northwestern block (Bonaire block) was thrust northeastward over the Caribbean crust.     

A method to measure suspended load transports in estuaries

It is shown that an optical beam-attenuance meter integrated into an Aanderaa current meter is a suitable device for measuring time series of fluxes of suspended material in turbid estuarine water. Some typical applications are presented.