Topic 2: Movement and interaction of nitrates and pesticides in the vegetation cover—soil groundwater-rock system

Organic and inorganic materials brought into the soil by intensive agricultural activities are decomposed in the soil zone by chemical and biochemical effects and redox processes and will enter into the infiltration process in the form of dissolved ions. Water movement in the unsaturated and saturated infiltration zone is subject to the laws of hydrology, but the changes of dissolved material content are controlled by chemical and biochemical effects also subject to changes in the transport processes.     

Monazite begets monazite: evidence for dissolution of detrital monazite and reprecipitation of syntectonic monazite during low-grade regional metamorphism

Back-scattered electron (BSE) imaging and X-ray element mapping of monazite in low-grade metasedimentary rocks from the Paleoproterozoic Stirling Range Formation, southwestern Australia, reveal the presence of distinct, high-Th cores surrounded by low-Th, inclusion-rich rims. Previous geochronology has shown that the monazite cores are older than 1.9 Ga and overlap with the ages of detrital zircon grains (∼3.5–2.0 Ga), consistent with a detrital origin. Many cores have scalloped and embayed surfaces indicating partial dissolution of former detrital grains. Textural evidence links the growth of the monazite rims (∼1.2 Ga) to deformation and regional metamorphism during the Mesoproterozoic Albany-Fraser orogeny. These results indicate that high-Th detrital monazite is unstable under low-grade metamorphic conditions (<400°C) and was partially or completely dissolved. Dissolution was followed by near-instantaneous reprecipitation and the formation of low-Th monazite and ThSiO₄. This reaction is likely to operate in other low-grade metasedimentary rocks, resulting in the progressive replacement of detrital monazite by metamorphic monazite during regional prograde metamorphism.     

Attenuation of seismic waves and the universal rheological model of the Earth’s mantle

Analysis of results of laboratory studies on creep of mantle rocks, data on seismic wave attenuation in the mantle, and rheological micromechanisms shows that the universal, i.e., relevant to all time scales, rheological model of the mantle can be represented as four rheological elements connected in series. These elements account for elasticity, diffusion rheology, high temperature dislocation rheology, and low temperature dislocation rheology. The diffusion rheology element is described in terms of a Newtonian viscous fluid. The high temperature dislocation rheology element is described by the rheological model previously proposed by the author. This model is a combination of a power-law non-Newtonian fluid model for stationary flows and the linear hereditary Andrade model for flows associated with small strains. The low temperature dislocation rheology element is described by the linear hereditary Lomnitz model.     

Andrade Creep at the Isostasy Recovering Flows in the Mantle

The laboratory experiments with rock samples show that creep under small strains is transient and can be described by the linear hereditary rheological Andrade model. The flows that recover isostasy (including the postglacial rebound flows) cause the strains in the crust and mantle, which are as low as at most 10^–3 and, hence, demonstrate transient creep. The effective viscosity characterizing the transient creep is lower than that at the steady creep and depends on the characteristic time of the considered process. The characteristic time of restoration of isostatic equilibrium (isostatic rebound) after the initial perturbation of the Earth’s surface topography is at most 10 kyr and, therefore, the distribution of the rheological properties along the depth of the mantle and the crust differs from the distribution that corresponds to the slow geological processes. When considering the process of isostatic rebound, the upper crust can be modeled by a thin elastic plate, whereas the underlying crust and the mantle can be modeled by the halfspace with transient creep in which the rheological parameter is inhomogeneous with depth. For this system, the continuum mechanics equations are solved by means of the Fourier and Laplace transforms. The vertical displacements that violate the isostasy propagate from the area of the initial perturbation along the Earth’s surface and can be considered as the mechanism of the present-day vertical movements of the crust. Comparing the obtained results with the observation data allows estimating the Andrade parameter. The use of the Andrade rheological model makes it possible to quantify the relationship between the effective viscosity of the asthenosphere corresponding to the postglacial flows and the seismic Q-factor of this layer.     

Excitation of thermoconvective waves in the continental lithosphere

For flows associated with small strains, the rheology of rocks is described by the linear integral (having a memory) law, which reduces to the Andrade law in the case of constant stress. A continental lithosphere with such a rheology is overstable. Thermoconvective waves that propagate through the lithosphere with minimal attenuation have a period of about 200  Myr and a wavelength of the order of 400  km. An initial temperature point-concentrated perturbation in the lithosphere excites amplitude-modulated thermoconvective waves (wave packets). When the initial perturbation occurs in a finite area, thermoconvective waves propagate outwards from this area, and thermoconvective oscillations (standing waves) are established inside the area. Thermoconvective waves induce oscillations of the Earth' surface, accompanied by sedimentation and erosion, and can be considered as a mechanism for the distribution of sediments on continental cratons.     

Sedimentology and sequence stratigraphy of the middle Jurassic Tarbert Formation, Oseberg South area (northern North Sea)

This paper describes the development of a regressive-to-transgressive shoreline wedge within the Middle Jurassic Tarbert Formation in the Oseberg South area (northern North Sea), as interpreted from core and log data from more than hundred wells. The wedge is described in terms of four facies associations (FA1–FA4). The lower, regressive portion of the wedge (FA1–FA2) contains both coarsening upward wave/storm-dominated shoreline deposits as well as coal-bearing paralic deposits, and was deposited during ascending regression. The upper, transgressive portion of the wedge (FA3–FA4) is characterised by wave-dominated estuarine deposits, exhibiting an upward change from inner to central to outer estuarine deposits. In contrast to some earlier studies, it is argued that this part was deposited during accretionary transgression. The present study documents an estuarine system that developed without any preceding fall of relative sea level and valley incision. It is argued that differential fault-induced subsidence created a broad gentle sag wherein one or several estuarine systems developed as the depositional system became transgressive. The subtle fault-induced subsidence is related to the tectonic evolution in the North Sea Basin.     

An approach to the intercalibration of benthic ecological status assessment in the North Atlantic ecoregion, according to the European Water Framework Directive

The European Water Framework Directive (WFD) establishes a framework for the protection and improvement of transitional and coastal waters; its final objective is to achieve at least 'good water status' for all waters, by 2015. The WFD requires Member States (MSs) to assess the Ecological Status (ES) of water bodies. This assessment will be based upon the status of the biological, hydromorphological and physico-chemical quality elements, by comparing data obtained from monitoring networks to reference (undisturbed) conditions, and then deriving an Ecological Quality Ratio (EQR). One of the biological quality elements to be considered is the benthic invertebrate component and some structural parameters (composition, diversity and disturbance-sensitive taxa) must be included in the ES assessment. Following these criteria, several approaches to benthic invertebrate assessment have been proposed by MSs. The WFD requires that these approaches are intercalibrated. This contribution describes the comparison of the different methodologies proposed by United Kingdom, Spain, Denmark and Norway. Results show a high consistency between the approaches, both with regard to determining the EQR and boundary settings for the ES.     

Shock history of the fossil ungrouped achondrite Österplana 065: Raman spectroscopy and TEM of relict chrome-spinel grains

Chrome-spinel grains from the fossil ungrouped achondrite Österplana 065 (Öst 065) recovered from Middle Ordovician limestone in Sweden were studied using Raman spectroscopy and TEM. All the studied chrome-spinel grains have a high density of planar fractures and planar features, not seen in chromites from the other L chondritic Ordovician fossil meteorites. Raman spectra of the host chrome-spinel grain and its planar features are similar and no signatures of high-pressure phases of chromite were found. The planar features occur along planar fractures, are enriched in ZnO, and are most probably produced due to enhanced leaching during terrestrial weathering in the marine sediment. Dislocation densities within two FIB sections prepared from two chrome-spinel grains from Öst 065 are similar to the dislocation densities found within chromite grains from the matrix of Tenham L6 chondrite. Using this observation and taking into account the presence of significant fracturing in all the grains, we conclude that the Öst 065 chrome-spinel grains were subjected to moderate to very strong shock corresponding to shock stages of S4–S6. This makes Öst 065 fossil achondrite the highest shocked fossil meteorite studied so far. This is consistent with the hypothesis that Öst 065 is a piece of the impactor that led to the L chondrite parent body breakup.