Forced regressive deposits of a deglaciation sequence: Example from the Late Quaternary succession in the Lake Saint‐Jean basin (Québec,Canada)

Differentiating between forced regressive deposits from deglacial periods in high latitude domains and forced regressive deposits from the onset of glacial periods in low latitude domains is fundamental for the accurate interpretation of glacial cycles within the geological record and then for the reconstruction of palaeogeography and palaeo‐climate. A forced regressive deglacial sequence is documented from the Lake Saint‐Jean basin (Québec, Canada). In this area, the Late Pleistocene to Holocene sediments have recorded the Laurentide ice sheet retreat accompanied by the invasion of marine waters (Laflamme Gulf) from ca 12·9 cal kyr bp . Subsequently, fluvio‐deltaic and coastal prograding wedges were deposited; they followed the base‐level fall due to glacio‐isostatic rebound. This succession, representing a transition from glacial to post‐glacial periods within a previously glaciated area, was investigated through recent mapping, preserved landforms, facies analysis, and new optical stimulated luminescence and radiocarbon dates. Three basin‐scale geological sections share a common lower part made of isolated ice‐contact fan deposits overlying bedrock. Throughout the entire basin, ice‐contact fans are capped by glacimarine muds. Above, fluvial and coastal prograding systems were deposited and evolved through four steps: (i) deltaic systems progressively increased in width; (ii) coastal influence on sedimentation increased; (iii) hydrographic drainage systems became more organised; and (iv) deltas graded from steep (Gilbert delta) to low‐angle foresets (mouth‐bar delta). Deposited during the base‐level fall from glacio‐isostatic rebound, the complete succession has been designated as a single falling stage system tract referred to as a deglacial falling stage system tract. It is representative of a deglaciation sequence in areas previously covered by ice during glacial periods (i.e. medium to high latitude domains). Diagnostic criteria are provided to identify such a deglacial falling stage system tract in the geological record, which may aid identification of previously unknown glacial cycles.     

Formation and disruption of aquifers in southwestern Chryse Planitia, Mars

We present geologic evidence suggesting that after the development of Mars' cryolithosphere, the formation of aquifers in southwestern Chryse Planitia and their subsequent disruption led to extensive regional resurfacing during the Late Hesperian, and perhaps even during the Amazonian. In our model, these aquifers formed preferentially along thrust faults associated with wrinkle ridges, as well as along fault systems peripheral to impact craters. The characteristics of degraded wrinkle ridges and impact craters in southwestern Chryse Planitia indicate a profound role of subsurface volatiles and especially liquid water in the upper crust (the upper one hundred to a few thousands of meters). Like lunar wrinkle ridges, the martian ones are presumed to mark the surface extensions of thrust faults, but in our study area the wrinkle ridges are heavily modified. Wrinkle ridges and nearby plains have locally undergone collapse, and in other areas they are associated with domical intrusions we interpret as mud volcanoes and mud diapirs. In at least one instance, a sinuous valley emanates from a modified wrinkle ridge, further indicating hydrological influences on these thrust-fault-controlled features. A key must be the formation of volatile-rich crust. Primary crustal formation and differentiation incorporated juvenile volatiles into the global crust, but the crustal record here was then strongly modified by the giant Chryse impact. The decipherable rock record here begins with the Chryse impact and continues with the resulting basin's erosion and infilling, which includes outflow channel activity. We propose that in Simud Vallis surface flow dissection into the base of the cryolithosphere-produced zones where water infiltrated and migrated along SW-dipping strata deformed by the Chryse impact, thereby forming an extensive aquifer in southwestern Chryse Planitia. In this region, compressive stresses produced by the rise of Tharsis led to the formation of wrinkle ridges. Zones of high fracture density within the highly strained planes of the thrust faults underlying the wrinkle ridges formed regions of high permeability; thus, groundwater likely flowed and gathered along these tectonic structures to form zones of elevated permeability. Volatile depletion and migration within the upper crustal materials, predominantly along fault systems, led to structurally controlled episodic resurfacing in southwestern Chryse Planitia. The erosional modification of impact craters in this region is linked to these processes. This erosion is scale independent over a range of crater diameters from a few hundred meters to tens of kilometers. According to our model, pressurized water and sediment intruded and locally extruded and caused crustal subsidence and other degradational activity across this region. The modification of craters across this wide range of sizes, according to our model, implies that there was intensive mobilization of liquid water in the upper crust ranging from about one hundred to several thousand meters deep.     

Sediment instability on the Portuguese continental margin under abrupt glacial climate changes (last 60 kyr)

It is well established that orbital scale sea-level changes generated larger transport of sediments into the deep-sea during the last glacial maximum than the Holocene. However, the response of sedimentary processes to abrupt millennial-scale climate variability is rather unknown. Frequency of distal turbidites and amounts of advected detrital carbonate are estimated off the Lisbon–Setúbal canyons (core MD03-2698, at 4602 mwd), within a chronostratigraphy based on radiometric ages, oxygen isotopes and paleomagnetic key global anomalies. We found that: 1) higher frequency of turbidites concurred with Northern Hemisphere coldest temperatures (Greenland Stadials [GS], including Heinrich [H] events). But more than that, an escalating frequency of turbidites starts with the onset of global sea-level rising (and warming in Antarctica) and culminates during H events, at the time when rising is still in its early-mid stage, and the Atlantic Meridional Overturning Circulation (AMOC) is re-starting. This short time span coincides with maximum gradients of ocean surface and bottom temperatures between GS and Antarctic warmings (Antarctic Isotope Maximum; AIM 17, 14, 12, 8, 4, 2) and rapid sea-level rises. 2) Trigger of turbidity currents is not the only sedimentary process responding to millennial variability; land-detrital carbonate (with a very negative bulk δ¹⁸O signature) enters the deep-sea by density-driven slope lateral advection, accordingly during GS. 3) Possible mechanisms to create slope instability on the Portuguese continental margin are sea-level variations as small as 20 m, and slope friction by rapid deep and intermediate re-accommodation of water masses circulation. 4) Common forcing mechanisms appear to drive slope instability at both millennial and orbital scales.     

Automatic revision of rules used to guide the generalisation process in systems based on a trial and error strategy

Automating the generalisation process, a major issue for national mapping agencies, is extremely complex. Several works have proposed to deal with this complexity using a trial and error strategy. The performance of systems based on such a strategy is directly dependent on the quality of the control knowledge (i.e. heuristics) used to guide the trials. Unfortunately, most of the time, the definition and updation of knowledge is a fastidious task. In this context, automatic knowledge revision can not only improve the performance of the generalisation, but also allow it to automatically adapt to various usages and evolve when new elements are introduced. In this article, an offline knowledge revision approach is proposed, based on a logging of the system and on the analysis of outcoming logs. This approach is dedicated to the revision of control knowledge expressed by production rules. We have implemented and tested this approach for the automated generalisation of groups of buildings within a generalisation model called AGENT, from initial data that reference a scale of approximately 1:15,000 compared with the target map's scale of 1:50,000. The results show that our approach improves the quality of the control knowledge and thus the performance of the system. Moreover, the approach proposed is generic and can be applied to other systems based on a trial and error strategy, dedicated to generalisation or not.     

Variable carbon isotope fractionation expressed by aerobic CH4-oxidizing bacteria

Carbon isotope fractionation factors reported for aerobic bacterial oxidation of CH₄(α_CH4-CO2) range from 1.003 to 1.039. In a series of experiments designed to monitor changes in the carbon isotopic fractionation of CH₄ by Type I and Type II methanotrophic bacteria, we found that the magnitude of fractionation was largely due to the first oxidation step catalyzed by methane monooxygenase (MMO). The most important factor that modulates the (α_CH4-CH3OH) is the fraction of the total CH₄ oxidized per unit time, which strongly correlates to the cell density of the growth cultures under constant flow conditions. At cell densities of less than 0.1 g/L, fractionation factors greater than 1.03 were observed, whereas at cell densities greater than 0.5 g/L the fractionation factors decreased to as low as 1.002. At low cell densities, low concentrations of MMO limit the amount of CH₄ oxidized, while at higher cell densities, the overall rates of CH₄ oxidation increase sufficiently that diffusion of CH₄ from the gaseous to dissolved state and into the cells is likely the rate-determining step. Thus, the residual CH₄ is more fractionated at low cell densities, when only a small fraction of the total CH₄ has been oxidized, than at high cell densities, when up to 40% of the influent CH₄ has been utilized. Therefore, since Rayleigh distillation behavior is not observed, δ¹³C values of the residual CH₄ cannot be used to infer the amount oxidized in either laboratory or field-studies. The measured (α_CH4-CH3OH) was the same for both Type I and Type II methanotrophs expressing particulate or soluble MMO. However, large differences in the δ¹³C values of biomass produced by the two types of methanotrophs were observed. Methylosinus trichosporium OB3b (Type II) produced biomass with δ¹³C values about 15‰ higher than the dissimilated CO₂, whereas Methylomonas methanica (Type I) produced biomass with δ¹³C values only about 6‰ higher than the CO₂. These effects were independent of the magnitude of the initial carbon isotope fractionation caused by MMO and were relatively constant despite changing ratios of assimilatory to dissimilatory carbon transformation by the organisms. This suggests that the difference in biomass carbon isotopes is primarily due to differences in the fractionation effect at the formaldehyde branch point in the metabolic pathway, rather than assimilation of CO₂ by Type II methanotrophs.     

Coarse carbonate breccias as a result of water-wave cyclic loading (uppermost Jurassic – South-East Basin, France)

In the uppermost Jurassic of the central part of the South-East Basin of France, an association of lime mudstone beds, calcarenite beds and coarse carbonate breccia bodies form an informal stratigraphical unit called the 'Barre Tithonique'. In the 'Barre Tithonique', gradual transitions from lime mudstone or calcarenite to breccia show different stages of deformation leading to progressive brecciation of the original lithologies. The study of the breccia facies, and the observed gradual transitions as a whole, document a new early diagenetic process in carbonate environments, resulting from water-wave and seabed interaction. Water-wave induced brecciation and its abundance in the 'Barre Tithonique' indicate that sea–seabed interaction was significant. Comparison with modern studies of the mechanics of wave–seabed interaction suggests that water depth was less than 200 m. It is demonstrated that sedimentary features such as channel-like structures, previously interpreted as being the result of erosion and deposition of mud-flows, were in fact produced by wave-induced, in situ reworking of lime mud, without any significant unidirectional flow or gravity induced displacement.     

Selenium speciation and partitioning within Burkholderia cepacia biofilms formed on α-Al2O3 surfaces

The distribution and speciation of Se within aerobic Burkholderia cepacia biofilms formed on α-Al₂O₃ (1-102) surfaces have been examined using grazing-angle X-ray spectroscopic techniques. We present quantitative information on the partitioning of 10⁻⁶ M to 10⁻³ M selenate and selenite between the biofilms and underlying alumina surfaces derived from long-period X-ray standing wave (XSW) data. Changes in the Se partitioning behavior over time are correlated with microbially induced reduction of Se(VI) and Se(IV) to Se(0), as observed from X-ray absorption near edge structure (XANES) spectroscopy.Selenite preferentially binds to the alumina surfaces, particularly at low [Se], and is increasingly partitioned into the biofilms at higher [Se]. When B. cepacia is metabolically active, B. cepacia rapidly reduces a fraction of the SeO₃²⁻ to red elemental Se(0). In contrast, selenate is preferentially partitioned into the B. cepacia biofilms at all [Se] tested due to a lower affinity for binding to the alumina surface. Rapid reduction of SeO₄²⁻ by B. cepacia to Se(IV) and Se(0) subsequently results in a vertical segregation of Se species at the B. cepacia/α-Al₂O₃ interface. Elemental Se(0) accumulates within the biofilm with Se(VI), whereas Se(IV) intermediates preferentially sorb to the alumina surface.B. cepacia/α-Al₂O₃ samples incubated with SeO₄²⁻ and SeO₃²⁻ when the bacteria were metabolically active result in a significant reduction in the mobility of Se vs. X-ray treated biofilms. Remobilization experiments show that a large fraction of the insoluble Se(0) produced within the biofilm is retained during exchange with Se-free solutions. In addition, Se(IV) intermediates generated during Se(VI) reduction are preferentially bound to the alumina surface and do not fully desorb. In contrast, Se(VI) is rapidly and extensively remobilized.     

Earthquake mechanisms of the Adriatic Sea and Western Greece: implications for the oceanic subduction-continental collision transition

We present 21 focal solutions (magnitude > 5.5) reliably computed by body-wave modelling for the western Hellenic arc from Yugoslavia to the southern Peloponnese. Mechanisms located within the Aegean show normal faulting, the T-axis trending N-S in the centre and parallel to the active boundary in the external part. Mechanisms associated with the Keffalinia fault are consistent with dextral strike-slip motion. Reverse mechanisms located along the active boundary are remarkably consistent and do not depend on the nature of the active boundary (continental collision or oceanic subduction). The consistency in azimuth of the slip vectors and of the GPS velocity relative to Africa, all along the active boundary, suggests that the deformation is related to the same motion. The discrepancy between seismic-energy release and the amount of shortening confirms that the continental collision is achieved by seismic slip on faults but the oceanic subduction is partially aseismic. The northward decrease in velocity between continental collision and oceanic subduction suggests the continental collision to be a recent evolution of the active subduction.