Long‐term sediment yield from a small catchment in southern Brazil affected by land use and soil management changes

Sediments produced from eroding cultivated land can cause on‐site and off‐site effects that cause considerable economic and social impacts. Despite the importance of soil conservation practices (SCP) for the control of soil erosion and improvements in soil hydrological functions, limited information is available regarding the effects of SCP on sediment yield (SY) at the catchment scale. This study aimed to investigate the long‐term relationships between SY and land use, soil management, and rainfall in a small catchment. To determine the effects of anthropogenic and climatic factors on SY, rainfall, streamflow, and suspended sediment concentration were monitored at 10‐min intervals for 14 years (2002–2016), and the land use and soil management changes were surveyed annually. Using a statistical procedure to separate the SY effects of climate, land use, and soil management, we observed pronounced temporal effects of land use and soil management changes on SY. During the first 2 years (2002–2004), the land was predominantly cultivated with tobacco under a traditional tillage system (no cover crops and ploughed soil) using animal traction. In that period, the SY reached approximately 400 t·km^?2·year^?1. From 2005 to 2009, a soil conservation programme introduced conservation tillage and winter cover crops in the catchment area, which lowered the SY to 50 t·km^?2·year^?1. In the final period (2010–2016), the SCP were partially abandoned by farmers, and reforested areas increased, resulting in an SY of 150 t·km^?2·year^?1. This study also discusses the factors associated with the failure to continue using SCP, including structural support and farmer attitudes.     

Distribution and sources of aliphatic hydrocarbons in surface sediments of Sergipe River estuarine system

The assessment of aliphatic hydrocarbons was performed in the Sergipe River estuarine system, northeastern Brazil. Aliphatic hydrocarbons concentration ranged from 9.9 ug g?1 up to 30.8 ug g?1 of dry sediment. The carbon preference index (CPI, based on nC?? to nC?? range), indicated predominance of petrogenic input in two of the sites analyzed (P4 and P5). The unresolved complex mixture (UCM) was found to be present in seven of the nine sites sampled (except for P4 and P5). Overall, the results of this work suggest that there is a mix of organic matter sources to the sediment. Although the coast of Sergipe has an intense off shore petroleum exploration and the Sergipe River crosses the entire city of Aracaju, the capital city of Sergipe, non-significant anthropogenic fingerprint was assessed.     

Experimental testing, numerical modelling and seismic strengthening of traditional stone masonry: comprehensive study of a real Azorian pier

Stone masonry is one of the oldest building techniques used worldwide and it is known to exhibit poor behaviour under seismic excitations. In this context, this work aims at assessing the in-plane behaviour of an existing double-leaf stone masonry pier by experimental testing. Additionally, a detailed 3D finite element numerical analysis based on micro-modelling of the original pier is presented (fully describing the geometry and division of each individual elements, namely infill, blocks and joints) aiming at simulating the experimental test results. This numerical strategy can be seen as an alternative way of analysing this type of constructions, particularly useful for laboratory studies, and suitable for the calibration of simplified numerical models. As part of a wider research activity, this work is further complemented with the presentation of an effective retrofit/strengthening technique (reinforced connected plaster) to achieve a significant improvement of its in-plane cyclic response which is experimentally verified in the results presented herein.     

Range imaging: a new method for high‐resolution topographic measurements in small‐ and medium‐scale field sites

Topographic measurements are essential for the study of earth surface processes. Three‐dimensional data have been conventionally obtained through terrestrial laser scanning or photogrammetric methods. However, particularly in steep and rough terrain, high‐resolution field measurements remain challenging and often require new creative approaches. In this paper, range imaging is evaluated as an alternative method for obtaining surface data in such complex environments. Range imaging is an emerging time‐of‐flight technology, using phase shift measurements on a multi‐pixel sensor to generate a distance image of a surface. Its suitability for field measurements has yet not been tested. We found ambient light and surface reflectivity to be the main factors affecting error in distance measurements. Low‐reflectivity surfaces and strong illumination contrasts under direct exposure to sunlight lead to noisy distance measurements. However, regardless of lighting conditions, the accuracy of range imaging was markedly improved by averaging multiple images of the same scene. For medium ambient lighting (shade) and a light‐coloured surface the measurement uncertainty was approximately 9 mm. To further test the suitability of range imaging for field applications we measured a reach of a steep mountain stream with a horizontal resolution of approximately 1 cm (in the focal plane of the camera), allowing for the interpolation of a digital elevation model on a 2 cm grid. Comparison with an elevation model obtained from terrestrial laser scanning for the same site revealed that both models show similar degrees of topographic detail. Despite limitations in measurement range and accuracy, particularly at bright ambient lighting, range imaging offers three‐dimensional data in real time and video mode without the need of post‐processing. Therefore, range imaging is a useful complement or alternative to existing methods for high‐resolution measurements in small‐ to medium‐scale field sites. Copyright © 2012 John Wiley & Sons, Ltd.     

Limitations of the ferrozine method for quantitative assay of mineral systems for ferrous and total iron

The quantitative assay of clay minerals, soils, and sediments for Fe(II) and total Fe is fundamental to understanding biogeochemical cycles occurring therein. The commonly used ferrozine method was originally designed to assay extracted forms of Fe(II) from non-silicate aqueous systems. It is becoming, however, increasingly the method of choice to report the total reduced state of Fe in soils and sediments. Because Fe in soils and sediments commonly exists in the structural framework of silicates, extraction by HCl, as used in the ferrozine method, fails to dissolve all of the Fe. The phenanthroline (phen) method, on the other hand, was designed to assay silicate minerals for Fe(II) and total Fe and has been proven to be highly reliable. In the present study potential sources of error in the ferrozine method were evaluated by comparing its results to those obtained by the phen method. Both methods were used to analyze clay mineral and soil samples for Fe(II) and total Fe. Results revealed that the conventional ferrozine method under reports total Fe in samples containing Fe in silicates and gives erratic results for Fe(II). The sources of error in the ferrozine method are: (1) HCl fails to dissolve silicates and (2) if the analyte solution contains Fe³⁺, the analysis for Fe²⁺ will be photosensitive, and reported Fe(II) values will likely be greater than the actual amount in solution. Another difficulty with the ferrozine method is that it is tedious and much more labor intensive than the phen method. For these reasons, the phen method is preferred and recommended. Its procedure is simpler, takes less time, and avoids the errors found in the ferrozine method.     

Modelling in-situ upgrading of heavy oil using operator splitting method

The in-situ upgrading (ISU) of bitumen and oil shale is a very challenging process to model numerically because of the large number of components that need to be modelled using a system of equations that are both highly non-linear and strongly coupled. Operator splitting methods are one way of potentially improving computational performance. Each numerical operator in a process is modelled separately, allowing the best solution method to be used for the given numerical operator. A significant drawback to the approach is that decoupling the governing equations introduces an additional source of numerical error, known as the splitting error. The best splitting method for modelling a given process minimises the splitting error whilst improving computational performance compared to a fully implicit approach. Although operator splitting has been widely used for the modelling of reactive-transport problems, it has not yet been applied to the modelling of ISU. One reason is that it is not clear which operator splitting technique to use. Numerous such techniques are described in the literature and each leads to a different splitting error. While this error has been extensively analysed for linear operators for a wide range of methods, the results cannot be extended to general non-linear systems. It is therefore not clear which of these techniques is most appropriate for the modelling of ISU. In this paper, we investigate the application of various operator splitting techniques to the modelling of the ISU of bitumen and oil shale. The techniques were tested on a simplified model of the physical system in which a solid or heavy liquid component is decomposed by pyrolysis into lighter liquid and gas components. The operator splitting techniques examined include the sequential split operator (SSO), the Strang-Marchuk split operator (SMSO) and the iterative split operator (ISO). They were evaluated on various test cases by considering the evolution of the discretization error as a function of the time-step size compared with the results obtained from a fully implicit simulation. We observed that the error was least for a splitting scheme where the thermal conduction was performed first, followed by the chemical reaction step and finally the heat and mass convection operator (SSO-CKA). This method was then applied to a more realistic model of the ISU of bitumen with multiple components, and we were able to obtain a speed-up of between 3 and 5.     

Deformation of a pervasively molten middle crust: insights from the neoproterozoic Ribeira‐Araçuaí orogen (SE Brazil)

Pervasive melting of the middle crust, as inferred in Tibet and the Altiplano, probably influences the deformation of the lithosphere. To constrain strain distribution in a pervasively molten crust, we analysed the deformation in an eroded analogue of these orogens. The Ribeira‐Araçuaí orogen (SE Brazil) comprises a stack of allochthons containing large volumes of anatectic and magmatic rocks. The upper allochton (∼300 km long, 50–100 km wide and >10 km thick) involves peraluminous diatexites and leucogranites resulting from partial melting of the middle crust. It overlies another allochthon containing huge early‐ to syn‐collisional plutons intruding metasediments. Both anatexites and magmatic intrusions display a pervasive strain‐induced magmatic fabric. Homogeneous strain distribution suggests inefficient localization. U–Pb ages of ∼575 Ma imply that anatexite melting was synchronous to the early‐ to syn‐collisional magmatism. Similarity in ages magmatic and solid‐state fabrics indicates that intrusions and anatexites deformed coherently with solid‐state rocks while still molten, in response to a combination of gravity‐driven and collision‐driven deformation.     

Global climate models as forcing for regional ocean modeling: a sensitivity study in the Iberian Basin (Eastern North Atlantic)

This work evaluates the performance of several global climate models (GCMs) as forcing of a regional ocean model configuration centered in the Iberian Basin. The study is divided in two parts. First, the output of nine GCMs is analyzed based on the fields needed to force the ocean model (Regional Ocean Modelling System—ROMS). GCMs differ greatly between them and their performance depends on the field. In the second part, the two GCMs with the worst performances in both extremes of the ensemble are used as forcing for two ROMS simulations, with the purpose of assessing the range of uncertainty comprised in this set of GCMs. Two other ROMS runs are setup: one climatologically forced control run, and one forced with the average of all the nine GCMs—the ensemble mean. Results show that the tendency of overestimation/underestimation of the forcings is reflected in the modeled hydrography, both at the surface and deeper layers down to 500 m. Nevertheless, in terms of circulation, all four runs reproduce the Azores Current, as well as the coastal transition zone seasonality (winter poleward flow and summer upwelling-associated equatorward flow). The CGCMs output performance as forcing depends on the forcing variable: one performs well for one or more variables, but badly for others, and which field is well or badly reproduced varies for each CGCM. Therefore, there is not a single CGCM having the best forcing for all variables. Hence, our results indicate that the most adequate approach consists of using the ensemble mean as forcing rather than using an individual model. This is supported by the general low overall (i.e. for all forcing variables) errors of the ensemble mean regarding the control climatological dataset, and the good comparison of the ensemble-forced ROMS run with the control run.     

Acoustic, Electromagnetic, and Photon Emission from Dynamically Fracturing Granite

Laboratory samples of Westerly granite were impacted by a falling striker, and the time series of acoustic and electromagnetic emission (AE and EME) from fracturing rock were recorded with the time resolution of 10?ns. In order to determine precisely the actual instants of beginning and termination of fracturing, the fractoluminescence (FL) signal related to chemical bond ruptures on the sample surface was recorded in parallel to both AE and EME signals. Energy distributions in all three series were characterized by the function N(E?>?E′), where N is the number of emitted signals characterized with the energy release E exceeding a threshold value E′. The fracture dynamics was studied using both the scaling analysis and the non-extensive Tsallis statistics. The energy distributions were approximated with both the empirical Gutenberg–Richter-type relation N(E?>?E′) ∝ E′^?b , and the analytical function N _q (E?>?E′) that includes the Tsallis’ parameter of non-extensivity, q, and the released energy density. A comparative consideration of information taken from the data of EME, AE and FL emission techniques was carried out in the context of the physical sense of the parameters b and q. The AE time series reflected adequately the cracking process both at microscopic and laboratory scale levels, while the photon emission did not show a direct response on the split-off formation. Time resolution of the EME method was found to be insufficient for studying the dynamic fracture of the given kind.     

Measurement and Uncertainty of the Long-Term Total Solar Irradiance Trend

A possible long-term trend of the total solar irradiance could be a natural cause for climate variations on Earth. Measurement of the total solar irradiance with space radiometers started in 1978. We present a new total solar irradiance composite, with an uncertainty of ± 0.35 W m⁻². From the minimum in 1995 to the maximum in 2002 the total solar irradiance increased by 1.6 W m⁻². In between the minima of 1987 and 1995 the total solar irradiance increased by 0.15 W m⁻².