Palynofacies, coal petrographic facies and depositional environments: Amphitheatre formation (Eocene to Oligocene) and Ravenscrag Formation (Maastrichtian to Paleocene), Canada

Low rank coals from two disparate geological settings have been subjected to petrographic and palynological analysis. The stratigraphic units studied and their locations are the Amphitheatre Formation, St Elias Mountains, Yukon Territory, of Eocene to Oligocene age; and the base of the Ravenscrag Formation, south-central Saskatchewan, of latest Cretaceous to earliest Paleocene age.The depositional setting of the Amphitheatre Formation ranges from distal sand-dominated braided stream and lacustrine environments to proximal gravel-dominated fluvial environments. The coals are low in inertinite (< 6%) and mostly high in huminite (> 85%). In localities with a dominance of angiosperm pollen the relative abundance of eu-ulminite B and densinite is greatest whereas in the ones with a dominantly coniferous pollen assemblage eu-ulminite A is the most prominent maceral. These observations suggest as an immediate cause/effect relationship, an at least partial dependance of present maceral content on floral precursors. This in turn probably reflects a certain combination of depositional environment conditions (pH, Eh, temperature, etc.), that likely controlled the plant community and the preservation of vegetal matter.The depositional environment of coals from the basal part of the Ravenscrag Formation contrasts sharply with that of the Amphitheatre. The Ravenscrag coals formed within a low energy, stable, floodplain environment. Palynological and coal maceral profiles for the basal Ravenscrag Formation coal, which spans the Cretaceous-Tertiary boundary, indicates that the environment of deposition progressed from an open canopied swamp forest with areas of open water, through a phase of low-lying to open water swamps with herbaceous, pterophytic vegetation to, at least locally, raised bogs. The change in coal petrography across the Cretaceous-Tertiary boundary is shown to be relatively minor in comparison to subsequent changes in coal petrography in the earliest Paleocene and to changes that occur in the palynological assemblages across the boundary interval.     

The surface free energies of talc and pyrophyllite

The components of the interfacial surface tension of talc and pyrophyllite were determined by measuring the rate of the capillary rise of a number of liquids through thin, sedimented deposits of the powdered minerals. The rate of capillary rise of a liquid in a powder is related to the contact angle between the liquid and the solid by the Washburn equation. The contact angles thus derived were used to determine the apolar (Lifshitzvan der Waals) component, γ ^LW , and the polar, electronacceptor and electron-donor parameters, γ ^⊕ and γ ^? respectively, of the Lewis acid/base component of the total interfacial surface energy using the Young equation. The values of γ ^LW for talc and pyrophyllite (31.5 and 34.4 mJ/m²) are slightly smaller than for smectite clay minerals (e.g., the value for hectorite is 39.9 mJ/m²), the electron donor parameter values are roughly comparable for talc and pyrophyllite (γ ^⊕ = 2.4 and 1.7 mJ/m²) as are the values of the electron acceptor parameter (γ ^? = 2.7 and 3.2 mJ/m²). The well-known hydrophobicity of these two minerals is due to the remarkably small value (for silicate minerals) of γ ^?(γ^⊕ is normally small or zero for silicates and many other oxides). The small values of both γ ^⊕ and γ ^? mean that the Lewis acid/base interactions between talc or pyrophyllite and highly polar water molecules are very weak. In contrast, low-charge smectites, the minerals most similar chemically and structurally to talc and pyrophyllite, have much greater values of γ ^? (≥ 30 mJ/m²) and are hydrophyllic.     

Cokriging nonstationary data

Universal cokriging is used to obtain predictions when dealing with multivariate random functions. An important type of nonstationarity is defined in terms of multivariate random functions with increments which are stationary of orderk. The covariance between increments of different variables is modeled by means of the pseudo-cross-covariance function. Criteria are formulated to which the parameters of pseudo-cross-covariance functions must comply so as to ensure positive-definiteness. Cokriging equations and the induced cokriging equations are given. The study is illustrated by an example from soil science.     

Heavy metal distribution in sediments of Krishna River basin,India

Suspended and bed sediments collected from the entire region of the Krishna River and its major tributaries were analyzed for heavy metals (V, Cr, Mn, Fe, Co, Ni, Cu, Zn, and Pb) by the thin-film energy dispersive x-ray fluorescence technique. There is considerable variation in the concentration of elements towards downstream, which may be due to the variation in the subbasin geology and various degrees of human impact. Suspended particles are enriched in heavy metals throughout the basin relative to bed sediments. The heavy metals are enriched in coarse size fractions (10–90 µm) throughout the Krishna River except its tributary Bhima, where finer fractions (2 µm) dominate. Transition elements correlate very well with each other. There is a striking similarity between the bed sediments of Krishna River and the Indian average. When the annual heavy metal flux carried by the Krishna River was estimated, and viewed in relation to the other major riverine transport, the Krishna is seen to be a minor contributor of heavy metals to the Bay of Bengal.     

Problems of pressure estimation in high temperature experiments using solid media apparatus with particular reference to piston-cylinder and anvil-with-hole apparatus (Part I)

The high albite (Ab)⇄jadeite (Jd)+quartz(Q) reaction (1) and the quartz(Q)⇄coesite (Cs) transformation (2) have been determined within the temperature range of 1000–1100°C and 1000–1400°C respectively under variable pressures using an anvil-with-hole apparatus. The equilibrium curves for the two reactions as a function ofP andT are as follows: P=−1·33+0·0296T (reaction 1);P=18·949+0·0111T(reaction 2). These two lines intersect at 31·1±0·5kb and 1096°C. The possibility of using an anvil-with-hole apparatus for conducting current investigations is discussed in this paper.     

Late Quaternary changes in surface water and deep water masses of the Nordic Seas and north-eastern North Atlantic: a review

Quantitative and semiquantitative proxy data based on more than 200 core-top samples and 100 deep-sea cores lead to important new insights about late Quaternary changes in paleo-oceanography, climate and microfaunal habitats in the north-eastern North Atlantic and Nordic Seas, insights resulting from a detailed investigation by the Kiel research project SFB 313/132 summarized in this paper. Planktonic foraminifera species provide reliable tracers of past sea surface temperatures and currents. The genus Beella in particular was found to trace subtropical water masses up to the far north. Benthic foraminifera species served as sensors of bottom currents and local flux rates of organic matter. New orders of time resolution are reached via stable isotope stratigraphy and accelerator mass spectrometry carbon-14 dating, allowing the identification of meltwater events lasting a few hundred years and shorter, a time range where, however, the yet unquantified role of bioturbation presents a growing problem. Based on this high-resolution stratigraphy a number of time slices (synoptic time intervals) are defined to reconstruct the incursion of Atlantic water masses, to map paleocurrent patterns within the Nordic Seas and the north-eastern North Atlantic and to test alternative circulation models — for example, for the last glacial maximum (LGM) and various meltwater episodes. These are clearly coeval with Dansgaard-Oeschger events found in Greenland ice cores, with the actual cause of the flickering climate as yet unknown. Likewise, there is ongoing controversy about the extent of past sea-ice cover and about possible changes from the present anti-estuarine to estuarine mode of deep water exchange between the North Atlantic and the Nordic Seas during the LGM. South of Iceland, however, the history of deep water renewal over the last glacial cycle covering the last 30000 years was largely deciphered.     

The Spectrum-UV Mission: an International Ultraviolet Observatory

The Spectrum-UV Mission is an ultraviolet space observatory, scheduled to be launched at the break of the century into a 7-day, highly excentric orbit aboard a Spectrum Series platform. The Observatory is endowed with a 170-cm aperture telescope and a focal plane instrument complement for spectroscopy and imaging in the 912 to 3600 range. The results of an advanced feasibility study, being carried out in the four partecipating Countries (Germany, Italy, Russia and Ukraine) are presented.     

The university as a local source of expertise

The relationship between the university and the city is expressed, amongst others, by the transfer of knowledge from the university to local actors. The universitys role as a local source of knowledge is studied by analyzing the outflow of the two main knowledge assets to the local area: graduates and research results. By comparing the results from universities in the Netherlands and the United Kingdom comparative evidence is discussed.     

COOL AND FRESHWATER SKIN OF THE OCEAN DURING RAINFALL

Rainfall over the sea modifies the molecular boundary layers of the upper ocean through a variety of different effects. These cover the freshwater flux stabilizing the near-surface layer, additional heat flux established due to rain versus surface temperature differences, modification of physical parameters by temperature and salinity changes, enhancement of the surface roughness, damping of short gravity waves, surface mixing by rain, and transfer of additional momentum from air to sea. They are separately described and included in our surface renewal model to investigate the rain's influence on the cool skin of the ocean and the creation of a haline molecular diffusion layer. Simulations with the upgraded model show that the most important effect on the conductive layer is that of reduced renewal periods followed by additional surface cooling due to rain on the order of 0.1 K. At rain rates below 50 mm h-1 rainfall is not able to completely destroy the mean temperature difference across the cool skin. A freshwater skin is created that exhibits a salinity difference exceeding 4 under strong rainfall. Comparisons with field data of the cool skin taken during the Coupled Ocean Atmosphere Response Experiment confirm the upgraded renewal model. Surface salinity measurements taken during the same field campaign are consistent with the calculated salinity differences across the freshwater skin. The enhancement of surface roughness by natural rain is less pronounced than described in earlier laboratory studies of rain with large drop sizes only.