Records of palaeo‐sea level and eruption duration in a coastal tuff ring,Jeju Island,Korea

Phreatomagmatic volcanoes and their sedimentary products can preserve high‐resolution records of earth surface processes because of their high deposition rate. Songaksan, Jeju Island, Korea, is a phreatomagmatic volcano, which erupted c. 3.7 ka BP in a coastal setting. Its tuff ring preserves a record of intertidal to supratidal facies transition in the basal part, which reveals the position of palaeo‐high‐tide level for at least 13 high‐tide events, and a record of a storm‐surge event in the middle part of the tuff ring, which lasted approximately three tidal cycles. Based on these features, the phreatomagmatic eruption of Songaksan is estimated to have taken place over a month. The sea level at the time was almost identical to that at present. This study shows that coastal phreatomagmatic volcanoes can preserve high‐resolution records of eruption duration and palaeo‐sea level, and can provide accurately levelled and dated data points to the Quaternary sea‐level curve.     

Spectroscopic constraints on growth of Siberian mixed-habit diamonds

Notable within-crystal variability of mineralogical and geochemical properties of single natural diamonds are commonly attributed to changing chemistry of parental fluids, sources of carbon and redox conditions of diamond precipitation. A distinct type of compositional heterogeneity (mixed-habit structure) is well-known to occur in diamonds as well as in many other minerals due to purely “structural” reasons that are unequal crystal chemistry of crystallographically different faces and selective absorption and fractionation of impurities between adjacent growth pyramids. Based on the combined cathodoluminescence, Fourier-transformed infrared spectroscopy and photoluminescence spectroscopy, study of nine diamond crystals with different growth histories and external morphology, but all showing mixed-habit patterns at different growth stages, we show that mixed-diamonds may grow in closed system conditions or with a slowly decreasing growth rate from a media with a much lower impurity content than previously thought. Intracrystal nitrogen distribution seems to be a function of growth rate even in the cases of unusual impurity partitioning between growth sectors. Generally poor with IR-active hydrogen at moderate nitrogen aggregation parameters, studied diamonds likely resemble the low hydrogen content from the growth medium that, for cubic diamonds, was typically suggested hydrogen-rich and a crucial factor for growth of cubic and mixed-habit diamonds. We also show that mixed-habit diamond growth may occur not only in peridotitic suite but also in an extended field of geochemical affinities from high-Ni to low-Ni or maybe even Ni-free environments, such as pyroxenitic or eclogitic.     

Seasonal controls on sediment transport and deposition in Lake Ohau,South Island,New Zealand: Implications for a high‐resolution Holocene palaeoclimate reconstruction

Laminated sediments in Lake Ohau, Mackenzie Basin, New Zealand, offer a potential high‐resolution climate record for the past 17 kyr. Such records are particularly important due to the relative paucity of detailed palaeoclimate data from the Southern Hemisphere mid‐latitudes. This paper presents outcomes of a study of the sedimentation processes of this temperate lake setting. Hydrometeorological, limnological and sedimentological data were collected over a 14 month period between 2011 and 2013. These data indicate that seasonality in the hydrometeorological system in combination with internal lake dynamics drives a distinct seasonal pattern of sediment dispersal and deposition on a basin‐wide scale. Sedimentary layers that accumulate proximal to the lake inflow at the northern end of the lake form in response to discrete inflow events throughout the year and display an event stratigraphy. In contrast, seasonal change in the lake system controls accumulation of light (winter) and dark (summer) laminations at the distal end of the lake, resulting in the preservation of varves. This study documents the key processes influencing sediment deposition throughout Lake Ohau and provides fundamental data for generating a high‐resolution palaeoclimate record from this temperate lake.     

Calcium isotopes in fossil bones and teeth — Diagenetic versus biogenic origin

We present the first systematic study of Ca isotopes (δ^44/40Ca) in Late Triassic to Late Cretaceous dinosaur bones and teeth (enamel and dentin) from sympatric herbivorous and carnivorous dinosaurs. The samples derive from five different localities, and data from embedding sediments are also presented. Additional δ^44/40Ca in skeletal tissues from modern reptiles and birds (avian dinosaurs) were measured for comparison in order to examine whether the original Ca isotopic composition in dinosaur skeletal apatite was preserved or might have changed during the diagenesis and fossilization process.δ^44/40Ca of fossil skeletal tissues range from −1.62‰ (Tyrannosaurus rex enamel) to +1.08‰ (Brachiosaurus brancai bone), while values in modern archosaur bones and teeth range from −1.63‰ (caiman enamel) to −0.37‰ (ostrich bone). The average δ^44/40Ca of the three types of fossil skeletal tissue analyzed - bone, dentin and enamel - show some systematic differences: while δ^44/40Ca in bone exhibits the highest values, while δ^44/40Ca in enamel has the lowest values, and dentin δ^44/40Ca falls in between. Values of δ^44/40Ca in the remains of herbivorous dinosaurs (0.1-1.1‰) are generally higher than those of bones of modern mammalian herbivores (−2.6‰ to −0.8‰) and from modern herbivorous archosaurs, which exhibit intermediate δ^44/40Ca (−0.8‰ to −0.4‰). These systematic isotopic shifts may reflect physiological differences between dinosaurs, mammals and reptiles representing different taxonomic groups of vertebrates.Systematic offsets in skeletal apatite δ^44/40Ca between herbivorous and carnivorous dinosaurs are not obvious, indicating a lack of a clear-cut Trophic Level Effect (TLE) shift between herbivores and carnivores in dinosaurs. This observation can be explained if the carnivorous dinosaurs in this study fed mainly on soft tissues from their prey and did not ingest hard (calcified) tissue to much extent. The most striking indication that the primary δ^44/40Ca is actually preserved in most of the fossil teeth is a difference in δ^44/40Ca of about 0.35 ± 0.10‰ (1SD) between dentin and enamel, based upon 11 of 16 analyzed dentin-enamel pairs. This difference is close to that found in modern reptiles (0.28 ± 0.05‰), and strongly suggests that this tell-tale signature is a primary feature of the fossilized dinosaur material as well. Furthermore, simple mass balance calculations show that changes of the original δ^44/40Ca in bones and teeth by diagenetically-formed calcium-bearing minerals are either small or would require implausible high original δ^44/40Ca values in the skeletal apatite.     

Factors controlling fluoride contents of groundwater in north-central and northwestern Sri Lanka

Chemical characterization has been made of groundwater bodies at 294 locations in four village districts in north-central and northwestern Sri Lanka, with special focus on fluorine contamination. High fluoride contents in groundwater are becoming a major problem in the dry zone of Sri Lanka, and dental fluorosis and renal failures are widespread. Field measurements of temperature, pH, and electrical conductivity were made during sampling. Chemical analyses of the water samples were later made using atomic absorption spectroscopy, spectrophotometry, and titration. Fluoride concentrations in the study area vary from 0.01 to 4.34 mg/l, and depend on pH and the concentrations of Na, Ca, and HCO₃ ⁻. Basement rocks including hornblende biotite gneiss, biotite gneiss, and granitic gneiss seem to have contributed to the anomalous concentrations of fluoride in the groundwater. Longer residence time in aquifers within fractured crystalline bedrocks may enhance fluoride levels in the groundwater in these areas. In addition, elevated fluoride concentrations in shallow groundwater in intensive agricultural areas appear to be related to the leaching of fluoride from soils due to successive irrigation.     

Farewell to Wynand Kleingeld (1946 to 2020)

Mathematical Geosciences -     

Geochronological (U–Pb,U–Th–total Pb,Sm–Nd) and geochemical (REE, <Superscript>87</Superscript>Sr/<Superscript>86</Superscript>Sr, δ<Superscript>18</Superscript>O, δ<Superscript>13</Superscript>C) tracing of intraplate tectonism and associated fluid flow in the Warburton Basin,Australia

The Warburton Basin of central Australia has experienced a complex tectonic and fluid-flow history, resulting in the formation of various authigenic minerals. Geochemical and geochronological analyses were undertaken on vein carbonates from core samples of clastic sediments. Results were then integrated with zircon U–Pb dating and uraninite U–Th–total Pb dating from the underlying granite. Stable and radiogenic isotopes (δ¹⁸O, Sr and εNd), as well as trace element data of carbonate veins indicate that >200 °C basinal fluids of evolved meteoric origin circulated through the Warburton Basin. Almost coincidental ages of these carbonates (Sm–Nd; 432 ± 12 Ma) with primary zircon (421 ± 3.8 Ma) and uraninite (407 ± 16 Ma) ages from the granitic intrusion point towards a substantial period of active tectonism and an elevated thermal regime during the mid Silurian. We hypothesise that such a thermal regime may have resulted from extensional tectonism and concomitant magmatic activity following regional orogenesis. This study shows that the combined application of geochemical and geochronological analyses of both primary and secondary species may constrain the timing of tectonomagmatic events and associated fluid flow in intraplate sedimentary basins. Furthermore, this work suggests that the Sm–Nd-isotopic system is surprisingly robust and can record geologically meaningful age data from hydrothermal mineral species.     

Sources of Terrestrial Organic Carbon in the Mississippi Plume Region: Evidence for the Importance of Coastal Marsh Inputs

High sedimentation rates along river-dominated margins make these systems important repositories for organic carbon derived from both allochthonous and autochthonous sources. Using elemental carbon/nitrogen ratios, molecular biomarker (lignin phenol), and stable carbon isotopic (bulk and compound-specific) analyses, this study examined the sources of organic carbon to the Louisiana shelf within one of the primary dispersive pathways of the Mississippi River. Surface sediment samples were collected from stations across the inner, mid, and outer Louisiana shelf, within the Mississippi River plume region, during two cruises in the spring and fall of 2000. Lignin biomarker data showed spatial patterns in terrestrial source plant materials within the river plume, such that sediments near the mouth of the Mississippi River were comparatively less degraded and richer in C₄ plant carbon than those found at mid-depth regions of the shelf. A molecular and stable isotope-based mixing model defining riverine, marsh, and marine organic carbon suggested that the highest organic carbon inputs to the shelf in spring were from marine sources (55?C61% marine organic carbon), while riverine organic carbon was the highest (63%) in fall, likely due to lower inputs of marine organic carbon at this time compared with the spring season. This model also indicated that marsh inputs, ranging from 19 to 34% and 3?C15% of the organic carbon in spring and fall, respectively, were significantly more important sources of organic carbon on the inner Louisiana shelf than previously suggested. Finally, we propose that the decomposition of terrestrial-derived organic carbon (from the river and local wetlands sources) in mobile muds may serve as a largely unexplored additional source of oxygen-consuming organic carbon in hypoxic bottom waters of the Louisiana shelf.     

Early burial mud diapirism and its impact on stratigraphic architecture in the Carboniferous of the Shannon Basin,County Clare,Ireland

Delta fronts are often characterized by high rates of sediment supply that result in unstable slopes and a wide variety of soft‐sediment deformation, including the formation of overpressured and mobile muds that may flow plastically during early burial, potentially forming mud diapirs. The coastal cliffs of County Clare, western Ireland, expose Pennsylvanian (Namurian) delta‐front deposits of the Shannon Basin at large scale and in three dimensions. These deposits include decametre‐scale, internally chaotic mudstone masses that clearly impact the surrounding sedimentary strata. Evidence indicates that these were true mud (unlithified sediment) diapirs that pierced overlying strata. This study documents a well‐exposed ca 20 m tall mud diapir and its impact on the surrounding mouth‐bar deposits of the Tullig Cyclothem. A synsedimentary fault and associated rollover dome, evident from stratal thicknesses and the dip of the beds, define one edge of the diapir. These features are interpreted as recording the reactive rise of the mud diapir in response to extensional faulting along its margin. Above the diapir, heterolithic sandstones and siltstones contain evidence for the creation of localized accommodation, suggesting synsedimentary filling, tilting and erosion of a shallow sag basin accommodated by the progressive collapse of the diapir. Two other diapirs are investigated using three‐dimensional models built from ‘structure from motion’ drone imagery. Both diapirs are interpreted to have grown predominantly through passive rise (downbuilding). Stratal relationships for all three diapirs indicate that they were uncompacted and fluid‐rich mud beds that became mobilized through soft‐sediment deformation during early burial (i.e. <50 m, likely <10 m depth). Each diapir locally controlled the stratigraphic architecture in the shallow subsurface and potentially influenced local palaeocurrents on the delta. The mud diapirs studied herein are distinct from deeper ‘shale diapirs’ that have been inferred from seismic sections worldwide, now largely disputed.