Oxygen and Al‐Mg isotopic compositions of grossite‐bearing refractory inclusions from CO3 chondrites

The distribution of the short‐lived radionuclide ²⁶Al in the early solar system remains a major topic of investigation in planetary science. Thousands of analyses are now available but grossite‐bearing Ca‐, Al‐rich inclusions (CAIs) are underrepresented in the database. Recently found grossite‐bearing inclusions in CO3 chondrites provide an opportunity to address this matter. We determined the oxygen and magnesium isotopic compositions of individual phases of 10 grossite‐bearing CAIs in the Dominion Range (DOM) 08006 (CO3.0) and DOM 08004 (CO3.1) chondrites. All minerals in DOM 08006 CAIs as well as hibonite, spinel, and pyroxene in DOM 08004 are uniformly ¹⁶O‐rich (Δ¹⁷O = ?25 to ?20‰) but grossite and melilite in DOM 08004 CAIs are not; Δ¹⁷O of grossite and melilite range from ~ ?11 to ~0‰ and from ~ ?23 up to ~0‰, respectively. Even within this small suite, in the two chondrites a bimodal distribution of the inferred initial ²⁶Al/²⁷Al ratios (²⁶Al/²⁷Al)₀ is seen, with four having (²⁶Al/²⁷Al)₀ ≤1.1 × 10^?5 and six having (²⁶Al/²⁷Al)₀ ≥3.7 × 10^?5. Five of the ²⁶Al‐rich CAIs have (²⁶Al/²⁷Al)₀ within error of 4.5 × 10^?5; these values can probably be considered indistinguishable from the “canonical” value of 5.2 × 10^?5 given the uncertainty in the relative sensitivity factor for grossite measured by secondary ion mass spectrometry. We infer that the ²⁶Al‐poor CAIs probably formed before the radionuclide was fully mixed into the solar nebula. All minerals in the DOM 08006 CAIs, as well as spinel, hibonite, and Al‐diopside in the DOM 08004 CAIs retained their initial oxygen isotopic compositions, indicating homogeneity of oxygen isotopic compositions in the nebular region where the CO grossite‐bearing CAIs originated. Oxygen isotopic heterogeneity in CAIs from DOM 08004 resulted from exchange between the initially ¹⁶O‐rich (Δ¹⁷O ~?24‰) melilite and grossite and ¹⁶O‐poor (Δ¹⁷O ~0‰) fluid during hydrothermal alteration on the CO chondrite parent body; hibonite, spinel, and Al‐diopside avoided oxygen isotopic exchange during the alteration. Grossite and melilite that underwent oxygen isotopic exchange avoided redistribution of radiogenic ²⁶Mg and preserved undisturbed internal Al‐Mg isochrons. The Δ¹⁷O of the fluid can be inferred from O‐isotopic compositions of aqueously formed fayalite and magnetite that precipitated from the fluid on the CO parent asteroid. This and previous studies suggest that O‐isotope exchange during fluid–rock interaction affected most CAIs in CO ≥3.1 chondrites.     

Establishing the link between the Chesapeake Bay impact structure and the North American tektite strewn field: The Sr‐Nd isotopic evidence

Abstract— The Chesapeake Bay impact structure, which is about 35 Ma old, has previously been proposed as the possible source crater of the North American tektites (NAT). Here we report major and trace element data as well as the first Sr‐Nd isotope data for drill core and outcrop samples of target lithologies, crater fill breccias, and post‐impact sediments of the Chesapeake Bay impact structure. The unconsolidated sediments, Cretaceous to middle Eocene in age, have ?_Sr^{t = 35.7 Ma} of +54 to +272, and ?_Nd^{t = 35.7 Ma} ranging from ?6.5 to ?10.8; one sample from the granitic basement with a T^Nd_CHUR model age of 1.36 Ga yielded an ?_Sr^{t = 35.7 Ma} of +188 and an ?_Nd^{t = 35.7 Ma} of ?5.7. The Exmore breccia (crater fill) can be explained as a mix of the measured target sediments and the granite, plus an as‐yet undetermined component. The post‐impact sediments of the Chickahominy formation have slightly higher T^Nd_CHUR model ages of about 1.55 Ga, indicating a contribution of some older materials. Newly analyzed bediasites have the following isotope parameters: +104 to +119 (?_Sr^{t = 35.7 Ma}), ?5.7 (?_Nd^{t = 35.7 Ma}), 0.47 Ga (T^Sr_UR), and 1.15 Ga (T^Nd_CHUR), which is in excellent agreement with previously published data for samples of the NAT strewn field. Target rocks with highly radiogenic Sr isotopic composition, as required for explaining the isotopic characteristics of Deep Sea Drilling Project (DSDP) site 612 tektites, were not among the analyzed sample suite. Based on the new isotope data, we exclude any relation between the NA tektites and the Popigai impact crater, although they have identical ages within 2s? errors. The Chesapeake Bay structure, however, is now clearly constrained as the source crater for the North American tektites, although the present data set obviously does not include all target lithologies that have contributed to the composition of the tektites.     

Retrieving volume FeO and TiO_2 abundances of lunar regolith with CE-2 CELMS data using BPNN method

The volume FeO and TiO_2 abundances(FTAs) of lunar regolith can be more important for understanding the geological evolution of the Moon compared to the optical and gamma-ray results. In this paper, the volume FTAs are retrieved with microwave sounder(CELMS) data from the Chang'E-2 satellite using the back propagation neural network(BPNN) method. Firstly, a three-layered BPNN network with five-dimensional input is constructed by taking nonlinearity into account. Then, the brightness temperature(TB) and surface slope are set as the inputs and the volume FTAs are set as the outputs of the BPNN network.Thereafter, the BPNN network is trained with the corresponding parameters collected from Apollo, Luna,and Surveyor missions. Finally, the volume FTAs are retrieved with the trained BPNN network using the four-channel TBderived from the CELMS data and the surface slope estimated from Lunar Orbiter Laser Altimeter(LOLA) data. The rationality of the retrieved FTAs is verified by comparing with the Clementine UV-VIS results and Lunar Prospector(LP) GRS results. The retrieved volume FTAs enable us to re-evaluate the geological features of the lunar surface. Several important results are as follows. Firstly, very-low-Ti(<1.5 wt.%) basalts are the most spatially abundant, and the surfaces with TiO_2> 5 wt.% constitute less than 10% of the maria. Also, two linear relationships occur between the FeO abundance(FA) and the TiO_2 abundance before and after the threshold, 16 wt.% for FA. Secondly, a new perspective on mare volcanism is derived with the volume FTAs in several important mare basins, although this conclusion should be verified with more sources of data. Thirdly, FTAs in the lunar regolith change with depth to the uppermost surface,and the change is complex over the lunar surface. Finally, the distribution of volume FTAs hints that the highlands crust is probably homogeneous, at least in terms of the microwave thermophysical parameters.     

A refractory inclusion with solar oxygen isotopes and the rarity of such objects in the meteorite record

NASA's Genesis mission revealed that the Sun is enriched in ¹⁶O compared to the Earth and Mars (the Sun's Δ¹⁷O, defined as δ¹⁷O–0.52×δ¹⁸O, is –28.4 ± 3.6‰; McKeegan et al. 2011). Materials as ¹⁶O‐rich as the Sun are extremely rare in the meteorite record. Here, we describe a Ca‐Al‐rich inclusion (CAI) from a CM chondrite that is as ¹⁶O‐enriched as the Sun (Δ¹⁷O = –29.1 ± 0.7‰). This CAI also has large nucleosynthetic anomalies in ⁴⁸Ca and ⁵⁰Ti (δ‐values are –8.1 ± 3.3 and –11.7 ± 2.4‰, respectively) and shows no clear evidence for incorporation of live ²⁶Al; (²⁶Al/²⁷Al)₀ = (0.03 ± 0.11) × 10^–5. Due to their anomalous isotopic characteristics, the rare CAIs consistent with the Genesis value could be among the first materials that formed in the solar system. In contrast to the CAI studied here, the majority of CAIs formed in or interacted with a reservoir characterized by a Δ¹⁷O value near –23.5‰. Combined with ²⁶Al‐²⁶Mg systematics, the oxygen isotopic compositions of FUN (fractionation and unidentified nuclear effects), UN, and normal CAIs suggest that nebular conditions were favorable for solids to inherit this value for an extended period of time. Many later‐formed materials, such as chondrules, planetesimals, and terrestrial planets, formed in reservoirs with Δ¹⁷O near 0‰. The distribution could be easier to explain if the common CAI value of –23.5‰, which is consistent with the Genesis value within 3σ, represented the average composition of the protoplanetary disk.     

Origin and transportation history of lunar breccia 14311

In this paper, we compare the U‐Pb zircon age distribution pattern of sample 14311 from the Apollo 14 landing site with those from other breccias collected at the same landing site. Zircons in breccia 14311 show major age peaks at 4340 and 4240 Ma and small peaks at 4110, 4030, and 3960 Ma. The zircon age patterns of breccia 14311 and other Apollo 14 breccias are statistically different suggesting a separate provenance and transportation history for these breccias. This interpretation is supported by different U‐Pb Ca‐phosphate and exposure ages for breccia 14311 (Ca‐phosphate age: 3938 ± 4 Ma, exposure age: ~550–660 Ma) from the other Apollo 14 breccias (Ca‐phosphate age: 3927 ± 2 Ma, compatible with the Imbrium impact, exposure age: ~25–30 Ma). Based on these observations, we consider two hypotheses for the origin and transportation history of sample 14311. (1) Breccia 14311 was formed in the Procellarum KREEP terrane by a 3938 Ma‐old impact and deposited near the future site of the Imbrium basin. The breccia was integrated into the Fra Mauro Formation during the deposition of the Imbrium impact ejecta at 3927 Ma. The zircons were annealed by mare basalt flooding at 3400 Ma at Apollo 14 landing site. Eventually, at approximately 660 Ma, a small and local impact event excavated this sample and it has been at the surface of the Moon since this time. (2) Breccia 14311 was formed by a 3938 Ma‐old impact. The location of the sample is not known at that time but at 3400 Ma, it was located nearby or buried by hot basaltic flows. It was transported from where it was deposited to the Apollo 14 landing site by an impact at approximately 660 Ma, possibly related to the formation of the Copernicus crater and has remained at the surface of the Moon since this event. This latter hypothesis is the simplest scenario for the formation and transportation history of the 14311 breccia.     

GETEMME—a mission to explore the Martian satellites and the fundamentals of solar system physics

GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.     

Possible formation scenarios for the giant H i envelope around the NGC 4490/4485 system

We present observations of H i in the nearby interacting galaxies NGC 4490 and 4485 made with the VLA in both C and D arrays. The galaxies are embedded in an extensive envelope of neutral hydrogen which is elongated in a direction approximately perpendicular to the plane of NGC 4490, with an extent of about 56 kpc. We argue that this distribution of neutral hydrogen can best be explained by a galactic-scale bipolar outflow of H  i driven by supernovae in NGC 4490. The flow from the disc appears to be reasonably well collimated and has probably persisted for approximately 6 × 10⁸ yr. The implications for galaxy evolution when such mass loss occurs are briefly discussed.