Mineral dissolution in the Cape Cod aquifer, Massachusetts, USA: I . Reaction stoichiometry and impact of accessory feldspar and glauconite on strontium isotopes, solute concentrations, and REY distribution

To compare relative reaction rates of mineral dissolution in a mineralogically simple groundwater aquifer, we studied the controls on solute concentrations, Sr isotopes, and rare earth element and yttrium (REY) systematics in the Cape Cod aquifer. This aquifer comprises mostly carbonate-free Pleistocene sediments that are about 90% quartz with minor K-feldspar, plagioclase, glauconite, and Fe-oxides. Silica concentrations and pH in the groundwater increase systematically with increasing depth, while Sr isotopic ratios decrease. No clear relationship between ⁸⁷Sr/⁸⁶Sr and Sr concentration is observed. At all depths, the ⁸⁷Sr/⁸⁶Sr ratio of the groundwater is considerably lower than the Sr isotopic ratio of the bulk sediment or its K-feldspar component, but similar to that of a plagioclase-rich accessory separate obtained from the sediment. The Si-⁸⁷Sr/⁸⁶Sr-depth relationships are consistent with dissolution of accessory plagioclase. In addition, solutes such as Sr, Ca, and particularly K show concentration spikes superimposed on their respective general trends. The K-Sr-⁸⁷Sr/⁸⁶Sr systematics suggests that accessory glauconite is another major solute source to Cape Cod groundwater. Although the authigenic glauconite in the Cape Cod sediment is rich in Rb, it is low in in-grown radiogenic ⁸⁷Sr because of its young Pleistocene age. The low ⁸⁷Sr/⁸⁶Sr ratios are consistent with equilibration of glauconite with seawater. The impact of glauconite is inferred to vary due to its variable abundance in the sediments. In the Cape Cod groundwater, the variation of REY concentrations with sampling depth resembles that of K and Rb, but differs from that of Ca and Sr. Shale-normalized REY patterns are light REY depleted, show negative Ce anomalies and super-chondritic Y/Ho ratios, but no Eu anomalies. REY input from feldspar, therefore, is insignificant compared to input from a K-Rb-bearing phase, inferred to be glauconite. These results emphasize that interpretation of groundwater chemistry, even in relatively simple aquifers, may be complicated by solute contributions from “exotic” accessory minerals such as glauconite. To detect such peculiarities, groundwater studies should combine the study of elemental concentration and isotopic composition of several solutes that show different geochemical behavior.     

强抗干扰电磁感应新方法

在城市中进行地球物理勘探,传统的勘探方法是很难做到的,它受到强电磁、地下管线、管道等诸多方面的干扰.无线电频率电磁波法是利用无线电波频率信号进行勘探的一种地球物理勘探新方法,它通过不接地电极和磁道探头接收高频无线电波信号,有效的压制城市中复杂交错的人文电磁干扰,利用相应软件,经过OCCAM算法实现矢量、标量计算,可以得...     

Stability of phlogopite in ultrapotassic kimberlite-like systems at 5.5–7.5 GPa

Hydrous K-rich kimberlite-like systems are studied experimentally at 5.5–7.5 GPa and 1200–1450?°C in terms of phase relations and conditions for formation and stability of phlogopite. The starting samples are phlogopite–carbonatite–phlogopite sandwiches and harzburgite–carbonatite mixtures consisting of Ol?+?Grt?+?Cpx?+?L (±Opx), according to the previous experimental results obtained at the same P–T parameters but in water-free systems. Carbonatite is represented by a K- and Ca-rich composition that may form at the top of a slab. In the presence of carbonatitic melt, phlogopite can partly melt in a peritectic reaction at 5.5 GPa and 1200–1350?°C, as well as at 6.3–7.0 GPa and 1200?°C: 2Phl?+?CaCO₃ (L)?Cpx?+?Ol?+?Grt?+?K₂CO₃ (L)?+?2H₂O (L). Synthesis of phlogopite at 5.5 GPa and 1200–1350?°C, with an initial mixture of H₂O-bearing harzburgite and carbonatite, demonstrates experimentally that equilibrium in this reaction can be shifted from right to left. Therefore, phlogopite can equilibrate with ultrapotassic carbonate–silicate melts in a?≥?150?°C region between 1200 and 1350?°C at 5.5 GPa. On the other hand, it can exist but cannot nucleate spontaneously and crystallize in the presence of such melts in quite a large pressure range in experiments at 6.3–7.0 GPa and 1200?°C. Thus, phlogopite can result from metasomatism of peridotite at the base of continental lithospheric mantle (CLM) by ultrapotassic carbonatite agents at depths shallower than 180–195 km, which creates a mechanism of water retaining in CLM. Kimberlite formation can begin at 5.5 GPa and 1350?°C in a phlogopite-bearing peridotite source generating a hydrous carbonate–silicate melt with 10–15 wt% SiO₂, Ca# from 45 to 60, and high K enrichment. Upon further heating to 1450?°C due to the effect of a mantle plume at the CLM base, phlogopite disappears and a kimberlite-like melt forms with SiO₂ to 20 wt% and Ca#?=?35–40.     

Resource partitioning by two large planktivorous fishes Micromesistius australis and Macruronus magellanicus in the Southwest Atlantic

The ontogenetic, seasonal, bathymetric and regional variations in the feeding spectrum of 922 specimens of southern blue whiting Micromesistius australis and 512 specimens of hoki Macruronus magellanicus were studied on the Falkland Islands’ shelf (Southwest Atlantic) between November 1999 and April 2003. A total of 49 different prey items were found in the stomach contents of the two species, with the hyperiid Themisto gaudichaudii and Euphausiacea being amongst the most important prey. Although the species composition did not change over fish size, the proportions of individual prey items in their diets did, with an increase in T. gaudichaudii and Euphausiacea with increasing fish size in southern blue whiting. The opposite occurred in hoki. Seasonal variations in the diet were found to mirror the seasonal abundance of prey around the Falkland Islands for the two species. Intra-specific differences in the diet of both predators reflected the distribution of prey, which in turn was determined by the water structure in the two regions sampled, leading to very different diets. In the limited time that the two species occupied the same space there was little or no competition resulting in almost total segregation of their trophic niches in space and time.     

Atlas of Japan (East) Sea hydrographic properties in summer, 1999

Hydrographic properties from CTD and discrete bottle sample profiles covering the Japan (East) Sea in summer, 1999, are presented in vertical sections, maps at standard depths, maps on isopycnal surfaces, and as property–property distributions. This data set covers most of the Sea with the exception of the western boundary region and northern Tatar Strait, and includes nutrients, pH, alkalinity, and chlorofluorocarbons, as well as the usual temperature, salinity, and oxygen observations.     

THz photometers for solar flare observations from space

The search for the still unrevealed spectral shape of the mysterious THz solar flare emissions is one of the current most challenging research issues. The concept, fabrication and performance of a double THz photometer system, named SOLAR-T, is presented. Its innovative optical setup allows observations of the full solar disk and the detection of small burst transients at the same time. The detecting system was constructed to observe solar flare THz emissions on board of stratospheric balloons. The system has been integrated to data acquisition and telemetry modules for this application. SOLAR-T uses two Golay cell detectors preceded by low-pass filters made of rough surface primary mirrors and membranes, 3 and 7 THz band-pass filters, and choppers. Its photometers can detect small solar bursts (tens of solar flux units) with sub second time resolution. Tests have been conducted to confirm the entire system performance, on ambient and low pressure and temperature conditions. An artificial Sun setup was developed to simulate performance on actual observations. The experiment is planned to be on board of two long-duration stratospheric balloon flights over Antarctica and Russia in 2014–2016.     

Can the unresolved X-ray background be explained by the emission from the optically-detected faint galaxies of the GOODS project?

The emission from individual X-ray sources in the Chandra Deep Fields and XMM – Newton Lockman Hole shows that almost half of the hard X-ray background above 6 keV is unresolved and implies the existence of a missing population of heavily obscured active galactic nuclei (AGN). We have stacked the 0.5–8 keV X-ray emission from optical sources in the Great Observatories Origins Deep Survey (GOODS; which covers the Chandra Deep Fields) to determine whether these galaxies, which are individually undetected in X-rays, are hosting the hypothesized missing AGN. In the 0.5–6 keV energy range, the stacked-source emission corresponds to the remaining 10–20 per cent of the total background – the fraction that has not been resolved by Chandra . The spectrum of the stacked emission is consistent with starburst activity or weak AGN emission. In the 6–8 keV band, we find that upper limits to the stacked X-ray intensity from the GOODS galaxies are consistent with the ∼40 per cent of the total background that remains unresolved, but further selection refinement is required to identify the X-ray sources and confirm their contribution.