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991.
The rate constants of the cyclisation reaction of 2,3-dimethylbiphenyl to give 1-methylfluorene under non-catalytic conditions have been obtained at five temperatures between 460 and 500°C. The activation energy, activation entropy and frequency factor for the reaction have been determined from the experimental data. These kinetic parameters were then used to calculate the temperature ranges where the reaction occurs under natural conditions in sedimentary sequences which have experienced different heating rates. The coincidence of the measured and calculated values has been taken as evidence that the cyclisation reaction occurs in sediments under non-catalytic conditions. 相似文献
992.
Alexander Zaporozec Arvi Valmari Hans-Georg Bohle G. Kunkel Rolf H. K?se et al. 《GeoJournal》1989,18(4):456-458
The International Geographical Union Reports
IGU Commission on Geographic Information SystemsGoegraphic information systems in higher education — A workshop — Columbus, Ohio, June 10–11, 1989 相似文献993.
994.
Alexander P. Anufriev Ivan Cupal Reviewer G. Siráň 《Studia Geophysica et Geodaetica》1987,31(1):37-42
Summary The behaviour of the poloidal and toroidal magnetic field at the core-mantle boundary is analysed in more detail, assuming that the conductive layer in the lowest mantle is thin. We can conclude that, in the case of the Z-model of the nearly symmetric hydromagnetic dynamo, the poloidal field may be considered potential everywhere in the mantle and that the azimuthal field depends on the geostrophic azimuthal velocity in the same manner as derived in[1] and[3].
aau ¶rt;-amu n¶rt;nuu m n¶rt; amuu aauum n¶rt;u nu¶rt;a u mu¶rt;a n. am ¶rt;, m Z-¶rt;u nmu umuu¶rt;aum ¶rt;ua aum nu¶rt;a n umam nmua ¶rt; amuu a n¶rt;u . ¶rt;m¶rt;am na [1] u [3] auum auma aum n m auma mu.相似文献
995.
Fractured carbonate or karst aquifers are highly susceptible to contamination. In Minnesota, the areas underlain by karst aquifers are often characterized by thin soil cover, poorly cased wells and/or collapse features. When coupled with improper land use decisions these aquifers have become extensively contaminated.
Evaluation of existing or potentially contaminated sites has required development of unique site evaluation techniques or combinations of techniques. Shallow geophysics have been used successfully to determine subsurface karst features, pinpoint locations for additional investigations and evaluate pump-test data. Soil texture, density and relative moisture content have been closely examined and criteria established to evaluate subsurface erosion susceptibility. Percent rock core recovery, mechanical response of drilling and drilling fluid loss have been used to characterize the secondary porosity and potential contamination susceptibility of the carbonate rock. Dye tracing via surface sinks and well injection have determined primary flow paths and have been useful in estimating flow times.
These techniques used solely or in conjunction have been very useful in evaluating contamination existing in the aquifers and as a predictive tool to evaluate the proposed land uses impacts. 相似文献
Evaluation of existing or potentially contaminated sites has required development of unique site evaluation techniques or combinations of techniques. Shallow geophysics have been used successfully to determine subsurface karst features, pinpoint locations for additional investigations and evaluate pump-test data. Soil texture, density and relative moisture content have been closely examined and criteria established to evaluate subsurface erosion susceptibility. Percent rock core recovery, mechanical response of drilling and drilling fluid loss have been used to characterize the secondary porosity and potential contamination susceptibility of the carbonate rock. Dye tracing via surface sinks and well injection have determined primary flow paths and have been useful in estimating flow times.
These techniques used solely or in conjunction have been very useful in evaluating contamination existing in the aquifers and as a predictive tool to evaluate the proposed land uses impacts. 相似文献
996.
Aromatic maturity indicators based upon dimethylnaphthalenes, trimethylnaphthalenes and methylphenanthrenes have been determined for two sedimentary sequences from northwest Western Australia. The rate of change of these indicators with depth has been modelled using a kinetic expression which accounts for the effects of continuously varying time and temperature. Activation energies and entropies of activation have been measured. Maturity indicators with similar and with very different kinetic parameters have been used to construct plots to illustrate their behaviours under a variety of thermal regimes. Maturity indicators with similar activation energies behave almost identically over a wide range of heating rates while those with substantial differences display more diverse behaviour. The former may be used to relate kerogen-based maturity indicators with those determined from crude oils, whereas the latter can provide information about the maximum palaeotemperatures and heating rates of sedimentary hydrocarbons. It was also observed that the kinetic parameters for particular aromatic maturity indicators differed between the two sedimentary sequences, suggesting that source and mineral matrix effects can influence their behaviour. 相似文献
997.
Alfons V. Larcher Robert Alexander Steven J. Rowland Robert I. Kagi 《Organic Geochemistry》1986,10(4-6)
Acid-catalysed alkyl hydrogen exchange and configurational isomerisation has been studied in a series of acyclic isoprenoid acids when they were heated at 160°C in the presence of a montmorillonite. Hydrogen exchange occurred between the adsorbed water of the clay surface and the a position of the isoprenoid acids. In cases where this position was chiral, exchange was accompanied by configurational isomerisation. Configurational isomerisation occurred more slowly in experiments conducted without a clay matrix in the presence of water. These results have been rationalized in terms of a reaction mechanism involving protonation of the carbonyl oxygen causing enolization and consequent hydrogen exchange at the a position of the acids. This mechanism was used to account for the relatively fast rate of isomerisation of C-2 chiral centres in sedimentary acyclic isoprenoid acids during maturation. 相似文献
998.
19-Norisopimarane and isopimarane have been synthesized from isopimara-9(11), 15-diene-3β, 19-diol. Analysis of the alkane fractions of an Australian crude oil by GC-MS showed the presence of nine diterpenoid hydrocarbons (diterpanes), of which one was bicyclic two were tricyclic and six were tetracyclic.19-Norisopimarane and isopimarane were identified by comparison of their mass spectra and GC retention times with those of the synthetic standards. ent-Beyerane, 16a(H)-phyllocladane, 16)β(H)-phyllocladane, ent-16α(H)-kaurane and labdane were also identified by comparison with authentic reference compounds. The remaining two compounds were tentatively identified as rimuane and as a 17-nortetracyclic diterpane on the basis of mass spectral evidence. The diterpanes are probably derived from conifer resins. 相似文献
999.
Analysis of landslide susceptibility in the Suusamyr region, Tien Shan: statistical and geotechnical approach 总被引:2,自引:0,他引:2
The Suusamyr region is located in the northern part of the Tien Shan Range in Central Asia. In 1992, this region was hit by
the Ms = 7.3 Suusamyr earthquake triggering several large landslides along the Suusamyr Valley and on the southern slopes
of the adjacent Suusamyr Range. One of these landslides had been investigated by geophysical and geotechnical methods in order
to determine local trigger factors. The present paper focuses on the influence of geological and morphological factors upon
landslide occurrence on a regional scale. The analysis is based on a digital data set including landslides triggered in 1992
and several older landslides as well as various types of digital elevation models (DEMs), ASTER image data, and geological
and active fault maps. These data were combined to compute landslide susceptibility (LS) maps using statistical methods, Landslide
Factor and Conditional Analyses (LFA, CA), as well as a geotechnical one, the Newmark's Method (NM). The landslide data set
was also analyzed with respect to the size–frequency relationship.
An erratum to this article can be found at 相似文献
1000.
Geodetic observations of ice flow velocities over the southern part of subglacial Lake Vostok, Antarctica, and their glaciological implications 总被引:1,自引:0,他引:1
Jens Wendt Reinhard Dietrich Mathias Fritsche Anja Wendt Alexander Yuskevich rey Kokhanov Anton Senatorov Valery Lukin Kazuo Shibuya Koichiro Doi 《Geophysical Journal International》2006,166(3):991-998
In the austral summer seasons 2001/02 and 2002/03, Global Positioning System (GPS) data were collected in the vicinity of Vostok Station to determine ice flow velocities over Lake Vostok. Ten GPS sites are located within a radius of 30 km around Vostok Station on floating ice as well as on grounded ice to the east and to the west of the lake. Additionally, a local deformation network around the ice core drilling site 5G-1 was installed.
The derived ice flow velocity for Vostok Station is 2.00 m a−1 ± 0.01 m a−1 . Along the flowline of Vostok Station an extension rate of about 10−5 a−1 (equivalent to 1 cm km−1 a−1 ) was determined. This significant velocity gradient results in a new estimate of 28 700 years for the transit time of an ice particle along the Vostok flowline from the bedrock ridge in the southwest of the lake to the eastern shoreline. With these lower velocities compared to earlier studies and, hence, larger transit times the basal accretion rate is estimated to be 4 mm a−1 along a portion of the Vostok flowline. An assessment of the local accretion rate at Vostok Station using the observed geodetic quantities yields an accretion rate in the same order of magnitude. Furthermore, the comparison of our geodetic observations with results inferred from ice-penetrating radar data indicates that the ice flow may not have changed significantly for several thousand years. 相似文献
The derived ice flow velocity for Vostok Station is 2.00 m a