Sulfide oxidation—an environmental problem within colliery spoil dumps

Because of the high degree of automation in the coal mining industry in the Ruhr area, Germany, about 1 metric ton of crushed rock/colliery spoil is brought to the surface for every metric ton of coal. Most of the colliery spoil disposed of must be dumped. These colliery spoil dumps are anthropogenic geological sediment bodies, which have a characteristic facies resulting from geological, technical, and economical factors connected with the formation of the dumps. The relation between the facies of the dumps and these factors, for example, is examplified with the pyrite content within the colliery spoil. Pyrite content within the dumps is dependent both on the conditions during sedimentation and (early) diagenesis and the techniques used for mining and processing. Thus, this geologic-technical facies of the dumps controls the weathering processes on and in dumps. These humaninduced processes are mainly responsible for the environmental impact on soil and groundwater. Oxidation of pyrite as well as alteration of pyrite under anoxic conditions yields dissolution of carbonates, accompanied by gypsum formation, by acid attack and strong acidification takes place.     

Fluid inclusions in upper mantle xenoliths from Northern Patagonia,Argentina: Evidence for an upper mantle diapir

Summary Three generations of fluid inclusions can be recognized in upper mantle xenoliths from alkali basalts of the Somoncura Massif, Northern Patagonia, Argentina. The first (early, primary) one consists of dense CO₂ inclusions which were trapped in the mantle-crust boundary zone (22–36 km minimum trapping depth). Their co-genetic relationship with silicate melt inclusions enables us to constrain their minimum trapping temperature at 1200°C, indicating a high temperature event in a cooler environment. The late (pseudosecondary and secondary) generations of fluid inclusions were classified in accordance with their homogenization temperature to liquid CO₂ (L1) and vapor CO₂ (L2) phase. The minimum trapping depth for the first of the late inclusions (L1) is about 16 km. In spite of the uncertainties related to this value, L1 inclusions indicate that the upper mantle rocks, of which samples were delivered by the basalts, had some residence time in the middle crust where they experienced a metasomatic event. The fact that this event did not destroy the earlier inclusions, places severe constraints on its duration. The second late inclusions (L2) are low-pressure CO₂ inclusions with a minimum trapping depth of only 2 km, presumably a shallow magma chamber of the host basalts. The succession of fluid inclusions strongly points toward a fairly fast uprising upper mantle underneath Northern Patagonia. The petrology and mineral chemistry of the peridotitic xenoliths support this view. Extensive partial melting and loss of these melts is indicated by the preponderance of harzburgites in the upper mantle underneath Northern Patagonia, a fairly unusual feature for a continental upper mantle. That depletion event as well as several metasomatic events — including those which left traces of fluid inclusions — are possibly related to a high-speed diapiric uprise of the upper mantle in this area. The path can be traced from the garnet peridotite stability field into the middle crust, a journey which must have been unusually fast. Differences in rock, mineral, and fluid inclusion properties between geographic locations suggest a diffuse and differential type of diapirism. Future studies will hopefully help to map the full extent and the highs and lows of this diapir and elucidate questions related to its origin and future.

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Fluid-Einschlüsse in Erdmantel-Xenolithen von Nord-Patagonien: Evidenz für einen Diapir im oberen Erdmantel

Zusammenfassung Erdmantel - Xenolithe in Alkali-Basalten des Somoncure Massivs, Nord-Patagonien, Argentinien, führen drei Generationen von Fluid-Einschlüssen. Die erste (frühe, primäre) Generation besteht aus dichten CO₂-Einschlüssen, welche offenbar in der Mantel-Kruste Grenzzone (22–36 km Minimum-Tiefe) eingeschlossen wurden. CO₂-Einschlüsse sind kogenetisch mit Silikat-Schmelzeinschlüssen. Dies erlaubt die Abschätzung der Einschließ-Temperatur mit minimal 1200°C, was auf ein Hochtemperatur-Ereignis in einer deutlich kühleren Umgebung hinweist. Die späten (pseudosekundäre und sekundäre) CO₂- Fluid-Einschlüsse bilden zwei Generationen von denen die eine in die flüssige (L1), die andere in die Dampfphase (L2) homogenisieren. Die minimale Einschließ-Tiefe für die L1 Generation ist etwa 16 km. Dies bedeutet - auch bei Berücksichtigung der mit diesem Wert verbundenen Ungenauigkeit - daß diese Erdmantel-Gesteine einige Zeit in der mittleren Erdkruste verbrachten und ein metasomatisches Ereignis erlebten, bevor sie von den Basalten zur Erdoberfläche gebracht wurden. Die Tatsache, daß dieses Ereignis die frühen Einschlüsse nicht zerstörte, kann nur bedeuten, daß es von kurzer Dauer war. Die L2-Generation besteht aus Niedrigdruck CO₂-Einschlüssen mit einer Minimum-Einschließtiefe von nur 2 km. Dies könnte in einer seichten Magmakammer des Wirt Basaltes geschehen sein.Die Abfolge von Fluid-Einschlüssen deutet auf einen relativ schnell aufsteigenden oberen Erdmantel unterhalb von Patagonien hin. Die Petrologie und Mineralchemie der peridotitischen Xenolithe unterstützen das. Die Vorherrschaft von Harzburgiten im Erdmantel unterhalb von Nord-Patagonien deutet auf umfangreiche Bildung partieller Schmelzen und deren Abfuhr hin — eine für einen kontinentalen Mantel ungewöhnliche Situation. Sowohl die Verarmungsereignisse, als auch die metasomatischen Veränderungen (einschließlich jene, welche Spuren in Form von Fluid Einschlüssen hinterließen) machen das Vorhandensein eines schnell aufsteigenden Daipirs im oberen Erdmantel dieser Gegend wahrscheinlich. Der Aufstieg kann vom Stabilitätsbereich der Granat-Peridotite bis in die mittlere Kruste verfolgt werden und muß daher relativ schnell erfolgt sein. Unterschiede in Gesteins-, Mineral und Fluid-Eigenschaften zwischen verschiedenen Lokalitäten legen einen diffusen und differenziellen Diapirismus nahe. Zukünftige Studien sollten es ermöglichen, das Gesamtausmaß und die unterschiedlichen Aufstiegshöhen des Diapirs zu kartieren und Hinweise auf seine Entstehung und zukünftige Entwicklung zu erhalten.

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With 5 Figures     

Powder- and single crystal Mössbauer spectroscopy on synthetic fayalite

Mössbauer measurements on synthetic iron orthosilicate Fe₂SiO₄ (fayalite) were carried out in the antiferromagnetic spin state below T _N 65 K. The Mössbauer parameters isomer shift , inner magnetic field H(0), angle between H(0) and the z-component of the electric field gradient (efg), quadrupole splitting QS and asymmetry parameter were determined as a function of temperature. These parameters could be attributed to the two crystallographic sites M1 and M2.The smaller isomer shift on M1 with respect to M2 displays the more covalent character of the Fe-O bond on M1, which is supported by previous neutron diffraction experiments. H(0) shows a Brillouin-type behaviour with different fields on the two crystallographic sites (stronger on M1) and a small discontinuity at T = 23 K which corresponds with previous magnetic measurements. The quadrupole splitting is equal on both sites within error bars, in agreement with previous theoretical results and in contradiction to previous Mössbauer refinements published elsewhere.     

TheROSAT survey of extreme UV sources: a new window on the universe

This paper discusses the first all-sky suvey of cosmic extreme ultra-violet sources, discovered by theROSAT Wide Field Camera. Details of the instrument and the survey are presented, with comparisons made to previous selected surveys in the X-ray regime. The subsequent optical identification program is described, and the major results summarized. I then discuss the main classes of EUV emitters: active chromosphere stars and hot white dwarfs, and describe the importance of EUV obserevations in understanding the astrophysics of these objects. Many bright, and relatively nearby, sources have been identified with hitherto unrecognized active stars, representing the extremes in chromospheric and coronal activity, be it binary or age related. Many new hot DA white dwarfs have also been indentified, and the most exciting result in this area is the discovery that significant traces of heavier elements (e.g. C, N, O, Si, Fe & Al) exist in their atmospheres, substantially increasing their EUV opacities. The importance of hot white dwarfs as standard candles in probing the local interstellar medium is also discussed. Miscellaneous counterparts (AGN, PNN, O-B stars and CVs) that make up the rest of the sample of EUV sources are also briefly mentioned. I conclude the paper with a discussion of the new magnetic cataclysmic variables discovered at SAAO, which have been the subject of intensive follow-up observations.     

Power spectrum of geomagneticK p-index detected at Misallat magnetic station

TheK _p-indices measured at Misallat station [ø = 29°45 N; = 30°54 E] during the period 1958–1989, have been compared with the data of two geomagnetic stations; one of them has similar longitude as Misallat and the second has almost similar latitude. The spectra of daily and hourly data of the three stations are compared together to define the latitude and longitude-effects on the detected periodicities. Daily periodicities ofK _p-index activities at the values 32.7, 21.2, 12.9, 11.6 and 9.2 days have been obtained to be common in the spectra of the three stations. The existence of 5-days periodicity in these stations has also been detected.     

Signatures of solar wind interaction with the nightside ionosphere of Venus

Plasma and field relationships observed across the nightside of Venus evidence a chaotic variety of interactions between the ionosphere and the combined effect of the solar wind and interplanetary magnetic field draped about the planet. Close examination of these data reveal within the chaos a number of repeatable signatures key to understanding fundamental field-plasma interactions. Observed from the Pioneer Venus Orbiter, (PVO), nightside conditions range from extensive, full-up ionospheres with little evidence of dynamic or energetic perturbations, to an almost full depletion, sometimes described as disappearing ionospheres. Between these extremes, the ionospheric structure is often irregular, sometimes exhibiting well-defined density troughs, at other times complex intervals of either abundant or minimal plasma concentration. Consistently, large B-fields (typically exceeding 5–10 nanoteslas) coincide with plasma decreases, whereas stable, abundant plasma distributions are associated with very low-level field. We examine hundreds of nightside orbits, identifying close correlations between regions of elevated magnetic fields featuring polarity reversals, and (a) exclusive low-frequency or distinctive broadband noise, or both, in the electric field data, (b) turbulent, superthermal behavior of the the ions and electrons. We review extensive studies of nightside fields to show that the correlations observed are consistent with theoretical arguments that the presence of strong magnetic fields within normal ionospheric heights indicates the intrusion of magnetosheath fields and plasma within such regions. We find abundant evidence that the ionosphere is frequently disrupted by such events, exhibiting a chaotic, auroral-like complexity appearing over a wide range of altitude and local time. We show that field-plasma disturbances, widely suggested to be similar to conditions in the Earth's auroral regions, are tightly linked to the electric field noise otherwise attributed to lightning. Owing to the coincidence inherent in this relationship, we suggest that natural, predictable plasma instabilities associated with the plasma gradients and current sheets evident within these events produce the E-field noise. The data relationships argue for a more detailed investigation of solar wind induced E-field noise mechanisms as the appropriate scientific procedure for invoking sources for the noise previously attributed to lightning. Consistent with these views, we note that independent analyses have offered alternative explanations of the noise as arising from ionospheric disturbances, that repeated searches for optical evidence of lightning have found no such evidence, and that no accepted theoretical work has yet surfaced to support the inference of lightning at Venus.     

Effects of hall current on the hydromagnetic free convection with mass transfer in a rotating fluid

An exact analysis of Hall current on hydromagnetic free convection with mass transfer in a conducting liquid past an infinite vertical porous plate in a rotating fluid has been presented. Exact solution for the velocity field has been obtained and the effects ofm (Hall parameter),E (Ekman number), andS _c (Schmidt number) on the velocity field have been discussed.Nomenclature C species concentration - C _w concentration at the porous plate - C species concentration at infinity - C _p specific heat at constant pressure - D chemical molecular diffusivity - g acceleration due to gravity - E Ekman number - G Grashof number - H ₀ applied magnetic field - j _x, j_y, j_z components of the current densityJ - k thermal conductivity - M Hartman number - m Hall parameter - P Prandtl number - Q heat flux per unit area - S _c Sehmidt number - T temperature of the fluid near the plate - T _w temperature of the plate - T temperature of the fluid in the free-stream - u, v, w components of the velocity fieldq, - U uniform free stream velocity - w ₀ suction velocity - x, y, z Cartesian coordinates - Z dimensionless coordinate normal to the plate. Greek symbols coefficient of volume expansion - ^* coefficient of expansion with concentration - _e cyclotron frequency - dimensionless temperature - ^* dimensionless concentration - v kinematic viscosity - density of the fluid in the boundary layer - coefficient of viscosity - _e magnetic permeability - angular velocity - electrical conductivity of the fluid - _e electron collision time - _u skin-friction in the direction ofu - _v skin-friction in the direction ofv     

Effects of rotation on Rayleigh-Taylor instabilities of an accelerating,compressible, perfectly conducting plane layer

The stability of a plane-stratified slab of perfectly conducting, rotating, compressible, inviscid plasma accelerated by a magnetic field is considered. Exact solutions for the growth rates of the unstable modes are determined for a -law gas when the undisturbed equilibrium is an isothermal atmosphere of semi-infinite extent with no frozen-in field. It is shown that the rotation has no effect on the region of unstable modes which has wavelengths long compared with the atmospheric scale height. On the other side, the growth rates in the presence of rotation are less than those in the absence of rotation for unstable modes.     

A catalogue and finding list of galactic novae

A catalogue of galactic novae and an atlas of finding charts are under preparation and will be published in 1984. The status of the project is described.Paper presented at the Lembang-Bamberg IAU Colloquium No. 80 on Double Stars: Physical Properties and Generic Relations, held at Bandung, Indonesia, 3–7 June, 1983.     

Phosphine absorption in the 5-μm window of Jupiter

Since the original suggestion by Gillett et al. (1969) it has generally been assumed that the region of partial transparency near 5 μm in Jupiter's atmosphere (the 5-μm window) is bounded by the v₄ NH₃ at 6.1 μm and the v₃ CH₄ band at 3.3 μm. New measurements of Jupiter and of laboratory phosphine (PH₃) samples show that PH₃ is a significant contributor to the continuum opacity in the window and in fact defines its short-wavelength limit. This has important implications for the use of 5-mu;m observations as a means to probe the deep atmospheric structure of Jupiter. The abundance of PH₃ which results from a comparison of Jovian and laboratory spectra is about 3 to 5 cm-am. This is five to eight times less than that found by Larson et al. [Astrophys. J. (1977) 211, 972–979] in the same spectral region, but is in good agreement with the result of Tokunaga et al. [Astrophys. J. (1979) 232, 603–615] from 10-μm observations.