Relationship between the suspended particulate matter and microorganisms in the White Sea waters

During the summer periods of 2003–2005, the spatial and vertical distributions of the suspended particulate matter and bacteria in stratified and homogeneous waters of the White Sea was studied. The results of the study of various quantitative characteristics of the suspended particulate matter (first of all, the area of the surface and the volumetric and mass concentrations) and the abundance of microorganisms in the water are discussed. A direct correlation between the value of the surface area of the suspended particulate matter and the total number of bacteria in the water is revealed. However, it was manifested only during the early summer period of the observations and was not expressed at the end of the summer. The enhanced surface area of the suspended particulate matter can indicate the higher biochemical activity of its particles. The influence of the pelitic fraction on the bacteria abundance in different parts of the sea during the summer is estimated.     

Controls on the D/H ratios of plant leaf waxes in an arid ecosystem

The extent to which leaf water D-enrichment (transpiration) and soil water D-enrichment (evaporation) affect the D/H ratio of plant leaf waxes remains a contentious issue, with important implications for paleohydrologic reconstructions. In this study we measure δD values of precipitation (δD_p), groundwater (δD_gw), plant xylem water (δD_xw) and leaf water (δD_lw) to understand their impact on the δD values of plant leaf wax n-alkanes (δD_wax) in an arid ecosystem. Our survey includes multiple species at four sites across an aridity gradient (80-30% relative humidity) in southern California.We find that many species take up groundwater or precipitation without significant fractionation. D-enriched soil water is a minor source even in species known to perform and utilize waters from hydraulic lift, such as Larrea tridentata (+10‰). Measurements of leaf water isotopic composition demonstrate that transpiration is an important mechanism for D-enrichment of leaf waters (+74 ± 20‰, 1σ), resulting in the smallest net fractionation yet reported between source water and leaf waxes (L. tridentata −41‰; multi-species mean value is −94 ± 21‰, 1σ). We find little change in leaf water D-enrichment or net fractionation across the climatic gradient sampled by our study, suggesting that a net fractionation of ca. −90‰ may be appropriate for paleohydrologic reconstructions in semi-arid to arid environments. Large interspecies offsets in net fractionations (1σ = 21‰) are potentially troublesome, given the observed floristic diversity and the likelihood of species assemblage changes with climate shifts.     

Comparative petrology of silicates in the Udei Station (IAB) and Miles (IIE) iron meteorites: Implications for the origin of silicate-bearing irons

The textures and mineral chemistries of silicate inclusions in the Udei Station (IAB) and Miles (fractionated IIE) iron meteorites were studied using optical and electron microscopy, SEM, EMPA, and LA-ICP-MS techniques to better understand the origin of silicate-bearing irons. Inclusions in Udei Station include near-chondritic, basaltic/gabbroic, feldspathic orthopyroxenitic, and harzburgitic lithologies. In Miles, most inclusions can be described as feldspathic pyroxenite or pyroxene-enriched basalt/gabbro. The trace-element compositions of both orthopyroxene and plagioclase grains are similar in different lithologies from Udei Station; whereas in different inclusions from Miles, the compositions of orthopyroxene grains are similar, while those of clinopyroxene, plagioclase, and especially Cl-apatite are variable. Orthopyroxene in Miles tends to be enriched in REE compared to that in Udei Station, but the reverse is true for plagioclase and clinopyroxene.The data can be explained by models involving partial melting of chondritic protoliths, silicate melt migration, and redox reactions between silicate and metal components to form phosphate. The extent of heating, melt migration, and phosphate formation were all greater in Miles. Silicates in Miles were formed from liquids produced by ∼30% partial melting of a chondritic precursor brought to a peak temperature of ∼1250 °C. This silicate melt crystallized in two stages. During Stage 1, crystallizing minerals (orthopyroxene, clinopyroxene, chromite, and olivine) were largely in equilibrium with an intercumulus melt that was evolving by igneous fractionation during slow cooling, with a residence time of ∼20 ka at ∼1150 °C. During Stage 2, following probable re-melting of feldspathic materials, and after the silicate “mush” was mixed with molten metal, plagioclase and phosphate fractionally crystallized together during more rapid cooling down to the solidus. In Udei Station, despite a lower peak temperature (<1180 °C) and degree of silicate partial melting (∼3-10%), silicate melt was able to efficiently separate from silicate solid to produce melt residues (harzburgite) and liquids or cumulates (basalt/gabbro, feldspathic orthopyroxenite) prior to final metal emplacement. Olivine was generally out of equilibrium with other minerals, but orthopyroxene and plagioclase largely equilibrated under magmatic conditions, and clinopyroxene in basalt/gabbro crystallized from a more evolved silicate melt.We suggest that a model involving major collisional disruption and mixing of partly molten, endogenically heated planetesimals can best explain the data for IAB and fractionated IIE silicate-bearing irons. The extent of endogenic heating was different (less for the IABs), and the amount of parent body disruption was different (scrambling with collisional unroofing for the IAB/IIICD/winonaite body, more complete destruction for the fractionated IIE body), but both bodies were partly molten and incompletely differentiated at the time of impact. We suggest that the post-impact secondary body for IAB/IIICD/winonaite meteorites was mineralogically zoned with Ni-poor metal in the center, and that the secondary body for fractionated IIE meteorites was a relatively small melt-rich body that had separated from olivine during collisional break-up.     

The structure and the phyllosilicates (chemistry, crystallinity and texture) of Talas Ala-Tau (Tien Shan, Kyrgyz Republic): comparison with more recent subduction complexes

Geological mapping and structural analysis of the Talas Ala Tau (Tien Shan, Kyrgyz Republic) have revealed a complex structure composed of folds with axial-plane cleavage and thrust faults verging towards the NE. The main structures of the range correspond to minor Tertiary and Carboniferous–Permian deformation superimposed on the main deformation event that took place during the Baikalian orogeny. The pervasive axial-plane cleavage diminishes in penetrativity from the hinterland to the foreland in both the Uzunakhmat and Karagoin sheets. The main thrusts developed phyllonitic shear-related rocks on the hangingwall immediately above the thrust planes. A crystal-chemical study of the phyllosilicates growth during the Baikalian deformation event along a cross-section revealed changes in the crystallinity, composition and lattice parameters of them. The phyllosilicates present in the Talas Ala Tau rocks were crystallized in very low-grade metamorphic conditions, that is below 300 °C, as indicated by their Kübler Index (KI), which decreases from SW towards the NE. Detailed TEM study of the phyllosilicates reveals a clear textural difference at the lattice level between samples with higher or lower KI parameters. There is also a clear difference in crystal-chemical parameters (KI and b) and composition between the phyllosilicates growth in relation to the axial-plane cleavage and the ones belonging to the thrust-related phyllonites. The first ones are more affected by the ferrimuscovitic vector than the phyllosilicates of phyllonites, closer to the theoretical phengitic component. Huge ranges of values of phengitic content of micas at sample level are interpreted as the result of a decompression path from at least 8 kbar. We propose a subduction geodynamic environment for the regional deformation and the origin of the phyllosilicates, as they are similar to those obtained in more recent accretionary complexes.     

晚泥盆世海岸平原的沼泽沉积——沉积特征和碳酸盐层序地层学意义

沼泽碳酸盐是盐水从淡到浓的沉积物,具有成土作用的证据,是环海或湖的典型沉积物(Freytet,1973; Freytet 和Plaziat,1982; Alonso-Zarza,2003).如果气候允许,它们能形成在位于海岸平原和潮坪的浅水、富碳、由淡到浓的盐水沼泽中 (Monty和Hardie,1976;Shinn,1983; Platt和Wright,1992).在这些边缘海环境中,沼泽沉积能覆盖数千平方千米,可能伴随发生喀斯特和钙质结壳岩现象(Platt和Wright,1992).     

Influence of atmospheric inputs on the iron distribution in the subtropical North-East Atlantic Ocean

Aerosol (soluble and total) iron and water-column dissolved (DFe, < 0.2 μm) and total dissolvable (TDFe, unfiltered) iron concentrations were determined in the Canary Basin and along a transect towards the Strait of Gibraltar, in order to sample across the Saharan dust plume. Cumulative dust deposition fluxes estimated from direct aerosol sampling during our one-month cruise are representative of the estimated deposition fluxes based on near surface water dissolved aluminium concentrations measured on board. Iron inventories in near surface waters combined with flux estimates confirmed the relatively short residence time of DFe in waters influenced by the Saharan dust plume (6–14 months). Enhanced near surface water concentrations of DFe (5.90–6.99 nM) were observed at the Strait of Gibraltar mainly due to inputs from metal-rich rivers. In the Canary Basin and the transect towards Gibraltar, DFe concentrations (0.07–0.76 nM) were typical of concentrations observed in the surface North Atlantic Waters, with the highest concentrations associated with higher atmospheric inputs in the Canary Basin. Depth profiles showed that DFe and TDFe were influenced by atmospheric inputs in this area with an accumulation of aeolian Fe in the surface waters. The sub-surface minimum of both DFe and TDFe suggests that a simple partitioning between dissolved and particulate Fe is not obvious there and that export may occur for both phases. At depths of around 1000–1300 m, both regeneration and Meddies may explain the observed maximum. Our data suggest that, in deep waters, higher particle concentrations likely due to dust storms may increase the scavenging flux and thus decrease DFe concentrations in deep waters.     

Circular plumes in Lake Pontchartrain estuary under wind straining

Circular shaped density plumes of low turbidity, low fecal indicator (Escherichia coli and enterococci) concentrations, and high salinity have been observed near the Industrial Canal in Lake Pontchartrain, north of the City of New Orleans. A conceptual model in polar coordinates and a numerical model are developed, together with data analysis, to illustrate the dense plume. It is demonstrated that the northward expansion of the plume occurs under northerly winds. The northward expansion of the plume occurs under northerly winds that drive downwind flow at the surface and upwind radial flow at the bottom. Northerly wind-induced straining, similar to tidal straining, promotes vertical stratification. As a result, the water becomes stratified near a thin bottom layer (<1 m), within which density currents are facilitated. The stability of the stratified plume suppresses wind-induced turbulent mixing inside the plume. The bottom water outside of the plume is more effectively stirred by the wind, the result being that the suspended sediment concentration outside of the plume area is much higher than inside. This contrast in mixing makes the plume visible from the surface by satellites even though the stratification is at the bottom. Laterally, wind stress produces a torque (vorticity) in areas of non-uniform depth such that upwind flow is developed in deep water and downwind flow in shallow water. The continuity requirement produces an upwind flow along the axis of the Industrial Canal (IC). The upwind flow is balanced by the downwind flow over the shallower peripheral areas along the coast.     

Generation of high-silica rhyolite: A Nd,Sr, and O isotopic study of Sierra La Primavera,Mexican Neovolcanic Belt

High-silica rhyolites of the Sierra La Primavera, a late Pleistocene center near Guadalajara, are extremely Sr-poor (0.3–1.3 ppm), yet (with one exception) values of ⁸⁷Sr/⁸⁶Sr_i are relatively low at 0.7041–0.7048. Values of ¹⁴³Nd/¹⁴⁴Nd for all the rhyolites are (within errors) identical to a basalt at 0.5129. These surprisingly primitive values, along with feldspar ¹⁸O of +6.6, are consistent with an origin by fractional crystallization of mantle-derived basalt. However, absence of the large volume of associated intermediate rocks that would be expected if the 40 km³ of erupted rhyolite were produced mainly by fractional crystallization suggests alternative processes involving partial melting of Mesozoic or Tertiary mafic intrusive rocks (or lower-crustal metamorphic equivalents). The latter interpretation is preferred, especially in light of comparative data for other North American, Cenozoic, high-silica rhyolites. Isotopic compositions correlate with basement age, but generally lie between values for associated basalts and the underlying crust. Nearly all can be interpreted as containing both a young mantle-derived component and a crustal component, probably derived by partial melting at intermediate to deep levels of the crust. No matter what the proportions of mantle- and crust-derived material in parental magmas, the extremely low concentrations of Sr and Ba in the high-silica rhyolites require extensive fractional crystallization of feldspar-rich assemblages after parental liquids attain rhyolitic compositions.At La Primavera, contamination by shallow roof rocks probably led to the 0.708 ⁸⁷Sr/⁸⁶Sr_i ratio of the earliest postcaldera lava dome, which is thought to have erupted through the same vent as the caldera-forming pyroclastic flows. Contamination associated with collapse apparently affected only a small volume of magma in contact with brecciated wall rocks close to the vent, as nearby lavas that erupted during the same episode about 95 ky ago are unaffected. No identifiable lowering of ¹⁸O took place on caldera collapse. Rhyolitic lavas that erupted 75, 60, and 30 ky ago document postcaldera chemical recovery of the chamber to progressively more evolved compositions in its upper reaches, but show little variation in ¹⁸O, ⁸⁷Sr/ ⁸⁶Sr_i, or ¹⁴³Nd/¹⁴⁴Nd with time, suggesting that the bulk of the rhyolitic magma within the chamber was isolated from significant wall-rock contamination. Most of the small range of ⁸⁷Sr/⁸⁶Sr_i among the rhyolites can be attributed to pre-eruptive, in situ decay of ⁸⁷Rb, resulting in a measurable secular increase of ⁸⁷Sr/⁸⁶Sr in these Sr-poor magmas. The ⁸⁷Sr/⁸⁶Sr_i of the youngest rhyolite, however, is somewhat lower than predicted, suggesting that the silicic magma chamber was at times open to interaction with more-mafic magmas from below.