Susceptibility to oxidative stress of mussels (Mytilus galloprovincialis) in the Venice Lagoon (Italy)

The aim of this study was to evaluate the susceptibility to pollutant mediated oxidative stress of the Mediterranean mussel Mytilus galloprovincialis in the Venice lagoon (Italy).

In June 2003, mussels from a farm were transplanted to eight sites in the lagoon for five weeks. Oxidative stress responses were measured by: (i) total oxyradical scavenging capacity (TOSC) assay, for an overall evaluation of the oxidative stress response capability; (ii) catalase (CAT), as a key enzyme involved in the antioxidant defence system; (iii) malondialdehyde (MDA), as an indicator of lipid peroxidation, to evaluate an oxidative damage; (iv) metallothioneins (MTs), as they play a role in the antioxidant defence.

The TOSC analysis revealed a reduced capability to eliminate: (i) peroxyl radical in mussels transplanted at Palude della Rosa, Valle Millecampi and Chioggia; (ii) hydroxyl radical at Campalto and Valle Millecampi; (iii) peroxynitrite at Valle Millecampi.

Inhibition in CAT activity, observed in all the monitored sites, confirms the presence of an oxidative pressure in transplanted mussels.

In addition, Pearson correlation analysis was performed in order to observe possible links between the various parameters. The PCA was a powerful tool to discriminate impacted sites, suggesting that the mussels transplanted throughout the Venice lagoon were subjected to different levels of oxidative pressure. Furthermore, it provided an easy and useful tool to summarize the obtained results.     

A numerical interpretation of load tests on vibro-piles

The finite element interpretation is discussed of two load tests carried out on instrumented vibro-piles in a granular deposit. A first back analysis, aimed at assessing the improvement of the mechanical characteristics of soil induced by the vibratory construction process, highlights an apparent contradiction between the experimental variation of the axial load along the pile and the numerical results. This suggests introducing as a free variable, in addition to the elastic and shear strength parameters of the granular soil, also the increase of the nominal diameter of pile caused by vibrations. The second back analysis provides some insight into the variation of the diameter with depth and leads to an acceptable interpretation, from the engineering standpoint, of the load tests. On these bases a quantitative comparison is presented between the calculated load–settlement diagram of the vibro-pile and that of a “standard” pile constructed without vibrations in the same granular deposit.     

Anomalous birefringence in andradite–grossular solid solutions: a quantum-mechanical approach

The static linear optical properties (refractive indices, birefringence and axial angle) of andradite–grossular (Ca₃Fe₂Si₃O₁₂–Ca₃Al₂Si₃O₁₂) solid solutions have been computed at the ab initio quantum-mechanical level through the Coupled Perturbed Kohn–Sham scheme, using an all-electron Gaussian-type basis set. Geometry relaxation after substitution of 1–8 Al for Fe atoms in the primitive cell of andradite yields 23 non-equivalent configurations ranging from cubic to triclinic symmetry. Refractive indices vary quite regularly between the andradite (1.860) and grossular (1.671) end-members; the birefringence δ and the axial angle 2V at intermediate compositions can be as large as 0.02° and 89°, respectively. Comparison with experiments suffers from inhomogeneities and impurities of natural samples; however, semi-quantitative agreement is observed.     

Topographic expression of active faults in the foothills of the Northern Apennines

Active faults that rupture the earth's surface leave an imprint on the topography that is recognized using a combination of geomorphic and geologic metrics including triangular facets, the shape of mountain fronts, the drainage network, and incised river valleys with inset terraces. We document the presence of a network of active, high-angle extensional faults, collectively embedded in the actively shortening mountain front of the Northern Apennines, that possess unique geomorphic expressions. We measure the strain rate for these structures and find that they have a constant throw-to-length ratio. We demonstrate the necessary and sufficient conditions for triangular facet development in the footwalls of these faults and argue that rock-type exerts the strongest control. The slip rates of these faults range from 0.1 to 0.3 mm/yr, which is similar to the average rate of river incision and mountain front unroofing determined by corollary studies. The faults are a near-surface manifestation of deeper crustal processes that are actively uplifting rocks and growing topography at a rate commensurate with surface processes that are eroding the mountain front to base level.     

Investigating the uncertainty of satellite altimetry products for hydrodynamic modelling

Satellite altimetry products are increasingly used in many hydraulic applications, and recent studies demonstrate their suitability for the calibration of hydraulic models. The study investigates the effect of satellite‐data uncertainty on the calibration of a quasi‐two‐dimensional (quasi‐2D) model of the middle‐lower portion of the Po river (~140 km). We refer to extended (~16 years of observations) ERS and ENVISAT altimetry products (i.e. River and Lake Hydrology data, RLH) to investigate the effect of (i) record length (i.e. number of satellite measurements at a given satellite track) and (ii) data uncertainty (i.e. altimetry measurements errors) on the calibration of the quasi‐2D model. We first present an assessment of ERS and ENVISAT altimetry errors and then perform the investigations in a Monte Carlo framework by generating datasets of synthetic altimetry products. The results of our analysis further emphasize the suitability of satellite data for the calibration of hydraulic models, providing also a quantitative assessment of the effect of the uncertainty of altimetry products. The analysis highlights the higher accuracy of ENVISAT data, which ensures a stable calibration with ~1.5 years of data (Mean Absolute Error, MAE, lower than 0.4 m, ~0.2 m of which results directly from the uncertainty of ENVISAT data). ERS‐based calibrations become stable with longer series (~3.5–5 years of data), and the negative effect of uncertainty in ERS data is higher (i.e. MAE of 0.6–0.9 m, of which 0.4–0.6 m results from the uncertainty of ERS measurements). Copyright © 2015 John Wiley & Sons, Ltd.     

Statistics and characteristic scales for bed load in a channel flow with sidewall effects

Results are presented for a long-duration sediment transport experiment with a plane bed. High-frequency time series of sediment concentration, sediment velocity and solid discharge per unit width were measured using image analysis of video records. A range of transport intensities from a single experiment has been analysed considering transport at different distances from the sidewalls as an independent variable. First and second order temporal statistics of the spatially-averaged values of the transport parameters are presented, which are in agreement with previous studies. A refined statistical analysis of the sediment concentration dynamics, reflecting bed load process, is also given. The characteristic scales of the sediment concentration dynamics are evaluated and analyzed in conjunction with those of the near-bed and bulk flow fields.     

Double-average characteristics of sediment motion in one-dimensional bed load

The sediment transport process on a flat bed was investigated experimentally, with reference to the relationship between the average solid discharge and the concentration and velocity of the moving grains. The instantaneous values of the quantities were measured and, therefore, it was possible to quantify the contribution of the temporal fluctuations of concentration and velocity to the resulting average sediment transport rate. Recognizing that the sediment transport process is an episodic phenomenon, an intermittency factor was defined and its contribution to the solid discharge, typically implicit in earlier formulations of the sediment flux, was highlighted. Conceptual analyses of the spatial scale dependence of the quantities were also made.     

Scenarios of Earthquake-Generated Tsunamis for the Italian Coast of the Adriatic Sea

We calculated the expected impact on the Italian coast of the Adriatic Sea of a large set of tsunamis resulting from potential earthquakes generated by major fault zones. Our approach merges updated knowledge on the regional tectonics and scenario-like calculations of expected tsunami impact. We selected six elongated potential source zones. For each of them we determined a Maximum Credible Earthquake and the associated Typical Fault, described by its size, geometry and kinematics. We then let the Typical Fault float along strike of its parent source zone and simulated all tsunamis it could generate. Simulations are based on the solution of the nonlinear shallow water equations through a finite-difference technique. For each run we calculated the wavefields at specified simulation times and the maximum water height field (above mean sea level), then generated travel-time maps and maximum water height profiles along the target coastline. Maxima were also classified in a three-level code of expected tsunami threat. We found that the southern portion of Apulia facing Albania and the Gargano promontory are especially prone to the tsunami threat. We also found that some bathymetric features are crucial in determining the focalization-defocalization of tsunami energy. We suggest that our results be taken into account in the design of early-warning strategies.