Determination of In and Sn Mass Fractions in Sixteen Geological Reference Materials by Isotope Dilution MC‐ICP‐MS

Mass fractions of Sn and In were determined in sixteen geological reference materials including basaltic/mafic (BCR‐2, BE‐N, BHVO‐1, BHVO‐2, BIR‐1, OKUM, W‐2, WS‐E), ultramafic (DTS‐2b, MUH‐1, PCC‐1, UB‐N) and felsic/sedimentary reference materials (AGV‐2, JA‐1, SdAR‐M2, SdAR‐H1). Extensive digestion and ion exchange separation tests were carried out in order to provide high yields (> 90% for Sn, > 85% for In), low total procedural blanks (~ 1 ng for Sn, < 3 pg for In) and low analytical uncertainties for the elements of interest in a variety of silicate sample matrices. Replicate analyses (n = 2–13) of Sn–In mass fractions gave combined measurement uncertainties (2u) that were generally < 3% and in agreement with literature data, where available. We present the first high‐precision In data for reference materials OKUM (32.1 ± 1.5 ng g^?1), DTS‐2b (2.03 ± 0.25 ng g^?1), MUH‐1 (6.44 ± 0.30 ng g^?1) and PCC‐1 (3.55 ± 0.35 ng g^?1) as well as the first Sn data for MUH‐1 (0.057 ± 0.010 μg g^?1) and DTS‐2b (0.623 ± 0.018 μg g^?1).     

New understandings of the June 24th 2017 Xinmo Landslide,Maoxian, Sichuan,China

On June 24, 2017 (21:39 UTC, June 23rd), a catastrophic landslide occurred at Xinmo village of Mao County, Sichuan Province, China. Soon after the event, some research teams carried out field investigations in order to both support the emergency operations and to understand the failure mechanism and possible evolutionary scenarios. Based on further in-depth interpretation of high-resolution remote-sensing images and detailed field surveys, it is newly found that there are at least six old rockfall deposits in the source area that prove the historic activity of the landslide scarp. Seismic data of the event and morphological evidences along the slope indicate that the landslide was preceded by a significant rockfall. Mechanical calculations show that the surface force due to pore water was far less than the impact force due to the rockfall. It means that the subsequent major rock avalanche was more likely due to the impact of the rockfall on the rock slope below, which broke the rock bridges and caused drop of shear resistance along the fractures. According to these new understandings, a different triggering mechanism for the landslide is proposed.     

Hybrid Inversion Method to Estimate Hydraulic Transmissivity by Combining Multiple-Point Statistics and a Direct Inversion Method

Inversion methods that rely on measurements of the hydraulic head h cannot capture the fine-scale variability of the hydraulic properties of an aquifer. This is particularly true for direct inversion methods, which have the further limitation of providing only deterministic results. On the other hand, stochastic simulation methods can reproduce the fine-scale heterogeneity but cannot directly incorporate information about the hydraulic gradient. In this work, a hybrid approach is proposed to join a direct inversion method (the comparison model method, CMM) and multiple-point statistics (MPS), for determination of a hydraulic transmissivity field T from a map of a reference hydraulic head \(h^\mathrm {(ref)}\) and a prior model of the heterogeneity (a training image). The hybrid approach was tested and compared with pure MPS and pure CMM approaches in a synthetic case study. Also, sensitivity analysis was performed to test the importance of the acceptance threshold \(\delta \), a simulation parameter that allows one to tune the influence of \(h^\mathrm {(ref)}\) on the final results. The transmissivity fields T obtained using the hybrid approach take into account information coming from the hydraulic gradient while simultaneously reproducing some of the fine-scale features provided by the training image. Furthermore, many realizations of T can be obtained thanks to the stochasticity of MPS. Nevertheless, it is not straightforward to exploit the correlation between the T maps provided by the CMM and the prior model introduced by the training image, because the former depends on the boundary conditions and flow settings. Another drawback is the growing number of simulation parameters introduced when combining two diverse methods. At the same time, this growing complexity opens new possibilities that deserve further investigation.     

Landslide susceptibility modeling assisted by Persistent Scatterers Interferometry (PSI): an example from the northwestern coast of Malta

Natural Hazards - Persistent Scatterers Interferometry (PSI) techniques are widely employed in geosciences to detect and monitor landslides with high accuracy over large areas, but they also suffer...     

Experimental partitioning of halogens and other trace elements between olivine, pyroxenes, amphibole and aqueous fluid at 2 GPa and 900–1,300 °C

We present new partition coefficients for various trace elements including Cl between olivine, pyroxenes, amphibole and coexisting chlorine-bearing aqueous fluid in a series of high-pressure experiments at 2 GPa between 900 and 1,300 °C in natural and synthetic systems. Diamond aggregates were added to the experimental capsule set-up in order to separate the fluid from the solid residue and enable in situ analysis of the quenched solute by LA–ICP–MS. The chlorine and fluorine contents in mantle minerals were measured by electron microprobe, and the nature of OH defects was investigated by infrared spectroscopy. Furthermore, a fluorine-rich olivine from one selected sample was investigated by TEM. Results reveal average Cl concentrations in olivine and pyroxenes around 20 ppm and up to 900 ppm F in olivine, making olivine an important repository of halogens in the mantle. Chlorine is always incompatible with Cl partition coefficients D _Cl ^{olivine/fluid} varying between 10^?5 and 10^?3, whereas D _Cl ^{orthopyroxene/fluid} and D _Cl ^{clinopyroxene/fluid} are ~10^?4 and D _Cl ^{amphibole/fluid} is ~5 × 10^?3. Furthermore, partitioning results for incompatible trace element show that compatibilities of trace elements are generally ordered as D ^amph/fluid ≈ D ^cpx/fluid > D ^opx/fluid > D ^ol/fluid but that D ^{mineral/fluid} for Li and P is very similar for all observed silicate phases. Infrared spectra of olivine synthesized in a F-free Ti-bearing system show absorption bands at 3,525 and ~3,570 cm^?1. In F ± TiO₂-bearing systems, additional absorption bands appear at ~3,535, ~3,595, 3,640 and 3,670 cm^?1. Absorption bands at ~3,530 and ~3,570 cm^?1, previously assigned to humite-like point defects, profit from low synthesis temperatures and the presence of F. The presence of planar defects could not be proved by TEM investigations, but dislocations in the olivine lattice were observed and are suggested to be an important site for halogen incorporation in olivine.     

Planform architecture,stratigraphic signature and morphodynamics of an exhumed Jurassic meander plain (Scalby Formation,Yorkshire, UK)

Modern fluvial meander plains exhibit complex planform transformations in response to meander‐bend expansion, downstream migration and rotation. These transformations exert a fundamental control on lithology and reservoir properties, yet their stratigraphic record has been poorly evaluated in ancient examples due to the lack of extensive three‐dimensional exposures. Here, a unique exhumed meander plain exposed to the north of Scarborough (Yorkshire, UK) is analysed in terms of architecture and morphodynamics, with the aim of developing a comprehensive model of facies distribution. The studied outcrop comprises tidal platforms and adjacent cliffs, where the depositional architecture of un‐tilted deposits was assessed on planform and vertical sections, respectively. In its broader perspective, this study demonstrates the potential of architectural mapping of extensive planform exposures for the reconstruction of ancient fluvial morphodynamics. The studied exhumed meander plain is part of the Scalby Formation of the Ravenscar Group, and originally drained small coastal incised valleys within the Jurassic Cleveland Basin. The meander plain is subdivided into two storeys that contain in‐channel and overbank architectural elements. In‐channel elements comprise expansional and downstream‐migrating point bars, point‐bar tails and channel fills. Overbank elements comprise crevasse complexes, levées, floodplain fines and lake fills. The evolution of the point bars played a significant role in dictating preserved facies distributions, with high flood‐stage nucleation and accretion of meander scrolls later reworked during waning flood‐stages. At a larger scale, meander belt morphodynamics were also a function of valley confinement and contrasts in substrate erodibility. Progressive valley infilling decreased the valley confinement, promoting the upward transition from prevalently downstream migrating to expansional meander belts, a transition associated with enhanced preservation of overbank elements. Strikingly similar relations between valley confinement, meander‐bend transformations and overbank preservation are observed in small modern meandering streams such as the Beaver River of the Canadian prairies and the Powder River of Montana (USA).     

Elastic properties of six silicate garnet end members from accurate ab initio simulations

The elastic properties of six silicate garnet end members, among the most important rock-forming minerals, are investigated here for the first time via accurate ab initio theoretical simulations. The Crystal program is used, which works within periodic boundary conditions and allows for all-electron basis sets to be adopted. From the computed elastic tensor, Christoffel’s equation is solved along a set of crystallographic directions in order to fully characterize the seismic wave velocity anisotropy in such materials. Polycrystalline isotropic aggregate elastic properties are derived from the computed single-crystal data via the Voigt-Reuss-Hill averaging procedure. Transferability of the elastic properties from end members to their solid solutions with different chemical compositions is also addressed.     

Differential Hydrogeological Effects of Draining Tunnels Through the Northern Apennines,Italy

Water inflows are a major challenge in tunnelling and particularly difficult to predict in geological settings consisting of heterogeneous sedimentary rock formations with complex tectonic structure. For a high-speed railway line between Bologna and Florence (Italy), a series of seven railway tunnels was drilled through turbiditic formations, ranging from pelitic rocks with thin arenitic layers over sequences including thick-bedded sandstone to calcareous rocks showing chemical dissolution phenomena (karstification). The tunnels were built as draining tunnels and caused significant impacts, such as drying of springs and base-flow losses at mountain streams. A comprehensive hydrological monitoring programme and four multi-tracer test were done, focusing on four sections of the tunnel system. The tracer tests delivered unprecedented data on groundwater flow and transport in turbiditic aquifers and made it possible to better characterize the differential impacts of tunnel drainage along a geological gradient. The impact radius is 200 m in the thin-bedded sequences but reaches 2.3–4.0 km in calcareous and thick-bedded arenitic turbidites. Linear flow velocities, as determined from the peaks of the tracer breakthrough curves, range from 3.6 m/day in the thin-bedded turbidites to 39 m/day in the calcareous rocks (average values from the four test sites). At several places, discrete fault zones were identified as main hydraulic pathways between impacted streams and draining tunnels. This case shows that ignoring the hydrogeological conditions in construction projects can cause terrible damage, and the study presents an approach to better predict hydraulic impacts of draining tunnels in complex sedimentary rock settings.     

A Bayesian vulnerability assessment tool for drinking water mains under extreme events

Drinking water security is a life safety issue as an adequate supply of safe water is essential for economic, social and sanitary reasons. Damage to any element of a water system, as well as corruption of resource quality, may have significant effects on the population it serves and on all other dependent resources and activities. As well as an analysis of the reliability of water distribution systems in ordinary conditions, it is also crucial to assess system vulnerability in the event of natural disasters and of malicious or accidental anthropogenic acts. The present work summarizes the initial results of research activities that are underway with the intention of developing a vulnerability assessment methodology for drinking water infrastructures subject to hazardous events. The main aim of the work was therefore to provide decision makers with an effective operational tool which could support them mainly to increase risk awareness and preparedness and, possibly, to ease emergency management. The proposed tool is based on Bayesian Belief Networks (BBN), a probabilistic methodology which has demonstrated outstanding potential to integrate a range of sources of knowledge, a great flexibility and the ability to handle in a mathematically sound way uncertainty due to data scarcity and/or limited knowledge of the system to be managed. The tool was implemented to analyze the vulnerability of two of the most important water supply systems in the Apulia region (southern Italy) which have been damaged in the past by natural hazards. As well as being useful for testing and improving the predictive capabilities of the methodology and for possibly modifying its structure and features, the case studies have also helped to underline its strengths and weaknesses. Particularly, the experiences carried out demonstrated how the use of BBN was consistent with the lack of data reliability, quality and accessibility which are typical of complex infrastructures, such as the water distribution networks. The potential applications and future developments of the proposed tool have been also discussed accordingly.     

Vestan lithologies mapped by the visual and infrared spectrometer on Dawn

We present global lithological maps of the Vestan surface based on Dawn mission's Visible InfraRed (VIR) Spectrometer acquisitions with a spatial sampling of 200 m. The maps confirm the results obtained with the data set acquired by VIR with a spatial sampling of 700 m, that the reflectance spectra of Vesta's surface are dominated by pyroxene absorptions that can be interpreted within the context of the distribution of howardites, eucrites, and diogenites (HEDs). The maps also partially agree with the ground and Hubble Space Telescope observations: they confirm the background surface being an assemblage of howardite or polymict eucrite, as well as the location of a diogenitic‐rich spot; however, there is no evidence of extended olivine‐rich regions in the equatorial latitudes. Diogenite is revealed on the Rheasilvia basin floor, indicating that material of the lower crust/mantle was exposed. VIR also detected diogenites along the scarp of Matronalia Rupes, and the rims of Severina and a nearby, unnamed crater, and as ejecta of Antonia crater. The diogenite distribution is fully consistent with petrological constraints; although the mapped distribution does not provide unambiguous constraints, it favors the hypothesis of a magma ocean.