Photobleaching of chromophoric dissolved organic matter in natural waters: kinetics and modeling

The effects of monochromatic and polychromatic UV and visible (VIS) radiation on the optical properties (absorption and fluorescence) of chromophoric dissolved organic matter (CDOM) were examined for a Suwannee River fulvic acid (SRFA) standard and for water from the Delaware and Chesapeake Bays. The primary (direct) loss of absorption and fluorescence occurred at the irradiation wavelength(s), with smaller secondary (indirect) losses occurring outside the irradiation wavelength(s). The efficiency of both direct and indirect photobleaching decreased monotonically with increasing wavelength. Exposure to polychromatic light increased the CDOM absorption spectral slope (S), consistent with previous field measurements. An analysis of the monochromatic photobleaching kinetics argues that a model based on a simple superposition of multiple chromophores undergoing independent photobleaching cannot apply; this conclusion further implies that the absorption spectrum of CDOM cannot arise solely from a simple superposition of the spectra of numerous independent chromophores. The kinetics of CDOM absorption loss with the monochromatic irradiation were employed to create a simple, heuristic model of photobleaching. This model allowed us to examine the importance of the indirect photobleaching losses in determining the overall photobleaching rates as well as to model the photobleaching of natural waters under polychromatic light fields. Application of this model to natural waters closely predicted the change in the CDOM spectral shape caused by photodegradation. The time scale of this process was consistent with field observations acquired during the summertime for coastal waters in the Middle Atlantic Bight (MAB). The results indicate that the ratio of the photodegradation depth to the mixed layer depth is a key parameter controlling the rate of the photobleaching in surface waters.     

Improvements on a unified dark matter model

We study, by means of a spherical collapse model, the effect of shear, rotation, and baryons on a generalized Chaplygin gas (gCg) dominated universes. We show that shear, rotation, and the baryon presence slow down the collapse with respect to the simple spherical collapse model. The slowing down in the growth of density perturbation is able to solve the instability of the unified dark matter (UDM) models described in previous papers (e.g., Sandvik et al. 2004) at the linear perturbation level, as also shown by a direct comparison of our model with previous results.     

Nonequilibrium Processes in the Solar Corona,Transition Region,Flares, and Solar Wind <Emphasis Type="Italic">(Invited Review)</Emphasis>

We review the presence and signatures of the non-equilibrium processes, both non-Maxwellian distributions and non-equilibrium ionization, in the solar transition region, corona, solar wind, and flares. Basic properties of the non-Maxwellian distributions are described together with their influence on the heat flux as well as on the rates of individual collisional processes and the resulting optically thin synthetic spectra. Constraints on the presence of high-energy electrons from observations are reviewed, including positive detection of non-Maxwellian distributions in the solar corona, transition region, flares, and wind. Occurrence of non-equilibrium ionization is reviewed as well, especially in connection to hydrodynamic and generalized collisional-radiative modeling. Predicted spectroscopic signatures of non-equilibrium ionization depending on the assumed plasma conditions are summarized. Finally, we discuss the future remote-sensing instrumentation that can be used for the detection of these non-equilibrium phenomena in various spectral ranges.     

JP3D compression of solar data-cubes: Photospheric imaging and spectropolarimetry

Hyperspectral imaging is an ubiquitous technique in solar physics observations and the recent advances in solar instrumentation enabled us to acquire and record data at an unprecedented rate. The huge amount of data which will be archived in the upcoming solar observatories press us to compress the data in order to reduce the storage space and transfer times. The correlation present over all dimensions, spatial, temporal and spectral, of solar data-sets suggests the use of a 3D base wavelet decomposition, to achieve higher compression rates. In this work, we evaluate the performance of the recent JPEG2000 Part 10 standard, known as JP3D, for the lossless compression of several types of solar data-cubes. We explore the differences in: a) The compressibility of broad-band or narrow-band time-sequence; I or V Stokes profiles in spectropolarimetric data-sets; b) Compressing data in [x,y, λ] packages at different times or data in [x,y,t] packages of different wavelength; c) Compressing a single large data-cube or several smaller data-cubes; d) Compressing data which is under-sampled or super-sampled with respect to the diffraction cut-off.     

Influence of friction on the motion of quasigeostrophic vortices

Abstract

Who show through numerical experiments that friction may enhance westward motion of vortices on the beta-plane and establish a relation betwen the dissipation coefficients and westward aceleration. This suggests an explanation fot the dunamics of westward intensification.     

Field Evaluation of a Slim-Hole Borehole Induction Tool

The Geonics EM-39 borehole induction tool was field tested to evaluate its performance under controlled conditions. The effects of temperature changes and borehole fluids were found to be negligible under most conditions. The instrument can be calibrated in large bodies of water of known electrical conductivity. When properly calibrated, the ± 5 percent accuracy claimed by the manufacturer is obtainable. A geologic unit must be at least 4m thick for the electrical conductivity of the unit to be accurately measured. Geologic units thinner than 4m thick can be detected if the conductivity contrast to adjacent units is sufficiently large.     

Characteristics of the seismic attenuation in two tectonically active zones of Southern Europe

The seismic energy attenuation in the frequency range of 1–18 Hz was studied in the two tectonically active zones of Irno Valley (Southern Italy) and Granada Basin (South-East Spain). Data were recorded by short period vertical components seismographs for low-magnitude local earthquakes. The method of coda waves, assuming singleS toS scattering approximation, was used to calculate the quality factorQ from the two data set. Results show a quality factor increasing with frequency, following the empirical lawQ=Q _o f ⁿ .Q _o andn are lower for the Irno Valley than for Granada. This result is interpreted in terms of different scattering environments present in the two investigated areas.     

Site response using coda-wave techniques: Applications to short period data from central and southern Italy

The method of coda waves was applied to two different sets of data for the evaluation of the relative site response.The first set of data consists of low magnitude earthquakes with closely spaced locations, recorded at a small aperture array of velocimeters located in the Abruzzo region, central Italy. The second set of data is composed of events with epicentral distance ranging from 20 to 300 km, recorded at a seismological network with an aperture of about 100 km located in the Puglia region, southern Italy.Results show that the coda wave method furnishes stable estimates of the site effect. An amplification, relative to an arbitrary site, of a factor of about 2 occurs in the 1.7–6 Hz frequency band for two stations of the Abruzzo network, while an amplification factor of about 0.5 occurs in the whole frequency band (1–24 Hz) for one of the stations of the Puglia network. This station is located in an area which is correlated with a low macroseismic intensity anomaly.     

Petrogenesis of calc-alkaline,shoshonitic and associated ultrapotassic Oligocene volcanic rocks from the Northwestern Alps,Italy

Along the Western Alps there is geological evidence of late-Alpine (Oligocene) magmatic activity which clearly postdates the Lepontine (Eocene-early Oligocene) metamorphism and related deformation of the Alpine nappe pile. This magmatic activity was notably delayed in relation to the most important convergent processes and may be related to buoyancy of lithosphere, tensional tectonics and thermal updoming subsequent to the collision between the Eurasian and African plates. The geochemical features of the rocks and the geophysical characteristics of the Alpine chain, suggest that: (a) shoshonitic and calcalkaline melts may have been generated by partial melting of metasomatized peridotitic material and subsequent fractional crystallization and crustal contamination; silicic andesites and latites, however, could have been also derived from metasomatized eclogite or deep continental crust material; (b) the ultrapotassic lamprophyres with high K, P, LREE, Th, Zr, U and high ⁸⁷Sr/⁸⁶Sr ratios were generated by partial melting of strongly metasomatized mantle; the varied Sr-isotopic ratios may partially also reflect additional radiogenic component from the continental crust following magma segregation from the source.     

Error analysis in hypocentral locations at Phlegraean Fields

The location reliability of the earthquakes occurred at Phlegraean Fields has been analyzed, and the theoretical errors, inferred from the diagonal elements of the covariance matrix, have been estimated. Using only first P-phase arrivals to the local network (22 stations) and assuming a reading error of 0.05 sec., the average error on the spatial coordinates is estimated to be of the order of 0.2 km.Shallow events (depth<1 km) are very poorly constrained in depth at the borders of the network. The use of both P and S arrival times, recorded by a smaller three component network (10 stations), improves the depth determination.Further analysis has been performed on a set of about 350 selected earthquakes, using two different velocity models.Differences in depth considerably greater than the theoretical errors, and showing highly different patterns have been found.Tests with artificial events, randomly distributed in space, indicate that the observed depth distribution is essentially due to the used velocity model.