Molecular and isotopic characterization of organic samples from the wreck of the Saint-Etienne merchant ship (XVIIIth century): Identification of pitch,fat, hair and sulfur

The wreck U Pezzo, excavated within the Saint Florent Gulf in northern Corsica was identified as the pink, Saint Etienne, a merchant ship which sank on January 31, 1769. In order to determine the composition of organic materials used to coat the hull or to waterproof different parts of the pink, a study of several samples, using molecular biomarker and carbon isotopic analysis, was initiated. The results revealed that the remarkable yellow coat, covering the outside planks of the ship’s bottom under the water line, is composed of sulfur, tallow (of ox and not of cetacean origin) and black pitch which corresponds to a mixture called “couroi” or “stuff”. Onboard ropes had been submitted to a tarring treatment with pitch. Hairs mixed with pitch were identified in samples collected between the two layers of the hull or under the sheathing planking. The study also provides a key model for weathering of pitch, as different degrees of degradation were found between the surface and the heart of several samples. Accordingly, molecular parameters for alteration were proposed. Furthermore novel mixed esters between terpenic and diterpenic alcohols and the free major fatty acids (C_14:0, C_16:0, C_18:0) were detected in the yellow coat.     

U–Pb dating, Hf-isotope characteristics and trace-REE-patterns of zircons from Medet porphyry copper deposit, Bulgaria: implications for timing, duration and sources of ore-bearing magmatism

Precise U–Pb geochronology, Hf isotope compositions and trace element distributions in zircons are combined in the present study to define the timing and sources of the magmatism forming the Medet porphyry copper deposit, Bulgaria. ID-TIMS U–Pb-zircon dating demonstrates that ore-bearing magmatism extended for less than 1.12 Ma. As inferred from the field relationships, it started with the intrusion of a quartz-monzodiorite at 90.59?±?0.29 Ma followed by granodiorite porphyries at 90.47?±?0.30 and 90.27?±?0.60 Ma and by crosscutting aplite dykes at 90.12?±?0.36 Ma. These units were overprinted by potassic alteration and host economic copper-(Mo–Au) mineralization. The main magmatic–hydrothermal activity ceased after that, and a later quartz-granodiorite porphyry dyke, dated at 89.26?±?0.32 Ma, only contains an uneconomic quartz–pyrite mineralization. Assimilation of Lower Paleozoic rocks with a mantle to mantle–crust signature is characteristic of the fertile magma in the Medet deposit, as defined by positive ?-Hf values of the inherited zircons. The positive Ce-anomalies and the higher Eu/Eu* ratios of the zircons in the mineralized Cretaceous rocks of Medet deposit argue for crystallization from a generally more oxidized magma compared to the later quartz-granodiorite porphyry dyke. A change in paleostress conditions occurred during the intrusion of the Medet pluton and its dykes. The initial stage reveals E–W extension associated with N–S compression, whereas the younger granodiorite dyke was emplaced during subsequent N–S extension. The large-scale switch of the extensional stress regime during the mineralization was favourable for ore deposition by channelling the fluids and increasing the effective permeability.     

Structure and kinematics of the Jungfrau syncline, Faflertal (Valais, Alps), and its regional significance

The formation and structural evolution of the Jungfrau syncline is described, based on excellent outcrops occurring in the Lötschental, in the Central Alps of Switzerland. The quality of the outcrops allows us to demonstrate that the External Massifs of the Swiss Alps have developed due to internal folding. The Jungfrau syncline, which separates the autochtonous Gastern dome from the Aar massif basement gneiss folds, is composed of slivers of basement rocks with their Mesozoic sedimentary cover. In the Inner Faflertal, a side valley of the Lötschental, the 200 m thick syncline comprises four units, the Gastern massif with a reduced Mesozoic sedimentary cover in a normal stratigraphic succession, two units of overturned basement rocks with their Mesozoic sedimentary cover, and the overturned lower limb of the Tschingelhorn gneiss fold of the Aar massif with lenses of its sedimentary cover. Stratigraphy shows that the lower units, related to the Gastern massif, are condensed and that the upper units, deposited farther away from a Gastern paleo-high, form a more complete sequence, linked to the Doldenhorn Meso-Cenozoic basin fill. The integration of these local observations with published regional data leads to the following model. On the northern margin of the Doldenhorn basin, at the northern fringe of the Alpine Tethys, the pre-Triassic crystalline basement and its Mesozoic sedimentary cover were folded by ductile deformation at temperatures above 300 °C and in the presence of high fluid pressures, as the Helvetic and Penninic nappes were overthrusted towards the northwest during the main Alpine deformation phase. The viscosity contrast between the basement gneisses and the sediments caused the formation of large basement anticlines and tight sedimentary synclines (mullion-type structures). The edges of basement blocks bounded by pre-cursor SE-dipping normal faults at the northwestern border of the Doldenhorn basin were deformed by simple shear, creating overturned slices of crystalline rocks with their sedimentary cover in what now forms the Jungfrau syncline. The localisation of ductile deformation in the vicinity of pre-existing SE-dipping faults is thought to have been helped by the circulation of fluids along the faults; these fluids would have been released from the Mesozoic sediments by metamorphic dehydration reactions accompanied by creep and dynamic recrystallisation of quartz at temperatures above 300 °C. Quantification of the deformation suggests a strain ellipsoid with a ratio (1+ e₁ / 1+ e₃) of approximately 1000. The Jungfrau syncline was deformed by more brittle NW-directed shear creating well-developed shear band cleavages at a late stage, after cooling by uplift and erosion. It is suggested that the external massifs of the Alps are basement gneiss folds created at temperatures of 300 °C by detachment through ductile deformation of the upper crust of the European plate as it was underthrusted below the Adriatic plate.     

High resolution imaging of Pluto and Charon with the Faint Object Camera of the Hubble Space Telescope

Images of the Pluto-Charon system were obtained with the Faint Object Camera (FOC) of the Hubble Space Telescope (HST) with the aim of determination of radii, fluxes, and albedos. The resolution of the already diffraction limited images was further improved by image restoration, yielding indications of surface albedo distributions which are qualitatively consistent with models derived from observations of Pluto-Charon mutual eclipses.Based on Observations with the NASA-ESA Hubble Space Telescope, which is operated by AURA, Inc., under NASA contract NAS 5-26555.     

Alpine and pre-Alpine magmatism in the root-zone of the western Central Alps

 The highest grade of metamorphism and associated structural elements in orogenic belts may be inherited from earlier orogenic events. We illustrate this point using magmatic and metamorphic rocks from the southern steep belt of the Lepontine Gneiss Dome (Central Alps). The U-Pb zircon ages from an anatectic granite at Verampio and migmatites at Corcapolo and Lavertezzo yield 280–290 Ma, i.e., Hercynian ages. These ages indicate that the highest grade of metamorphism in several crystalline nappes of the Lepontine Gneiss Dome is pre-Alpine. Alpine metamorphism reached sufficiently high grade to reset the Rb-Sr and K-Ar systematics of mica and amphibole, but generally did not result in crustal melting, except in the steep belt to the north of the Insubric Line, where numerous 29 to 26 Ma old pegmatites and aplites had intruded syn- and post-kinematically into gneisses of the ductile Simplon Shear Zone. The emplacement age of these pegmatites gives a minimum estimate for the age of the Alpine metamorphic peak in the Monte Rosa nappe. The U-Pb titanite ages of 33 to 31 Ma from felsic porphyritic veins represent a minimum-age estimate for Alpine metamorphism in the Sesia Zone. A porphyric vein emplaced at 448±5 Ma (U-Pb monazite) demonstrates that there existed a consolidated Caledonian basement in the Sesia Zone. Received: 23 May 1995/Accepted: 12 October 1995     

Faltung und Gangbildung im Gebiet der Eisenspatgrube “Ameise” bei Siegen

Zusammenfassung Die Bildung des Spateisensteinganges von Grube Ameise fällt wahrscheinlich in das Ende der Faltung.Der Gang entwickelt sich aus einer Scherfläche, an der Abschiebungen stattfanden, die die Faltenachsen antithetisch verwerfen.     

Simulation of the geochemical transformations of sterols: superacid effect of clay minerals

The heating of cholestanol 2a with kaolinite (140°C, 16 hr) mainly leads to a mixture of steranes (40%) and sterenes (35%). The major compounds which are formed have been identified as 5α(H)- and 5β(H)-cholestanes, 4a and 4b, the diacholestenes, 5, the diacholestanes, 6, and the D-homodiacholestanes 7. With the exception of the latter, these compounds have all been observed previously in ancient sediments and crude oils. Several of these compounds are identical or bear structural similarities with those obtained from cholestanol at low temperature in acidic or superacidic conditions. The comparison with the results obtained using other minerals (montmorillonite, talc, alumina, polyphos-phate-treated montmorillonite) shows that the observed transformations are catalysed by superacid sites which are present in kaolinite and montmorillonite.     

Secular non-random variations of cosmogenic carbon-14 in the terrestrial atmosphere

The time dependence of the¹⁴C content of bristlecone pine wood samples dated by their tree rings and grown during the last 8000 years was examined. The¹⁴C values as measured by the La Jolla Radiocarbon Laboratory were used for the investigation.Two different smoothing techniques were used for constructing values for equal time intervals. In this manner the introduction of regularities, that could have resulted from applied mathematical techniques, could be excluded.There is good evidence for non-random features in the power spectrum, in particular for a 200-year periodicity.The regularities in the power spectrum are further indications supporting the assumption that the¹⁴C variations reflect a property of the sun.