Coupling hydrogeological with surface runoff model in a Poltva case study in Western Ukraine

This paper presents the hydrological coupling of the software framework OpenGeoSys (OGS) with the EPA Storm Water Management Model (SWMM). Conceptual models include the Saint Venant equation for river flow, the 2D Darcy equations for confined and unconfined groundwater flow, a two-way hydrological coupling flux in a compartment coupling approach (conductance concept), and Lagrangian particles for solute transport in the river course. A SWMM river–OGS aquifer inter-compartment coupling flux is examined for discharging groundwater in a systematic parameter sensitivity analysis. The parameter study involves a small perturbation (first-order) sensitivity analysis and is performed for a synthetic test example base-by-base through a comprehensive range of aquifer parametrizations. Through parametrization, the test cases enables to determine the leakance parameter for simulating streambed clogging and non-ocillatory river-aquifer water exchange rates with the sequential (partitioned) coupling scheme. The implementation is further tested with a hypothetical but realistic 1D river–2D aquifer model of the Poltva catchment, where discharging groundwater in the upland area affects the river–aquifer coupling fluxes downstream in the river course (propagating feedbacks). Groundwater contribution in the moving river water is numerically determined with Lagrangian particles. A numerical experiment demonstrates that the integrated river–aquifer model is a serviceable and realistic constituent in a complete compartment model of the Poltva catchment.     

Uncertainties of geochemical modeling during CO<Subscript>2</Subscript> sequestration applying batch equilibrium calculations

One of the uncertainties in the field of carbon dioxide capture and storage (CCS) is caused by the parameterization of geochemical models. The application of geochemical models contributes significantly to calculate the fate of the CO₂ after its injection. The choice of the thermodynamic database used, the selection of the secondary mineral assemblage as well as the option to calculate pressure dependent equilibrium constants influence the CO₂ trapping potential and trapping mechanism. Scenario analyses were conducted applying a geochemical batch equilibrium model for a virtual CO₂ injection into a saline Keuper aquifer. The amount of CO₂ which could be trapped in the formation water and in the form of carbonates was calculated using the model code PHREEQC. Thereby, four thermodynamic datasets were used to calculate the thermodynamic equilibria. Furthermore, the equilibrium constants were re-calculated with the code SUPCRT92, which also applied a pressure correction to the equilibrium constants. Varying the thermodynamic database caused a range of 61% in the amount of trapped CO₂ calculated. Simultaneously, the assemblage of secondary minerals was varied, and the potential secondary minerals dawsonite and K-mica were included in several scenarios. The selection of the secondary mineral assemblage caused a range of 74% in the calculated amount of trapped CO₂. Correcting the equilibrium constants with respect to a pressure of 125 bars had an influence of 11% on the amount of trapped CO₂. This illustrates the need for incorporating sensitivity analyses into reaction pathway modeling.     

Engineering geological data in support of municipal land use planning—a case study in Analandia, southeast Brazil

This paper presents a method for transforming the information of an engineering geological map into useful information for non-specialists involved in land-use planning. The method consists of classifying the engineering geological units in terms of land use capability and identifying the legal and the geologic restrictions that apply in the study area. Both informations are then superimposed over the land use and a conflict areas map is created. The analysis of these data leads to the identification of existing and forthcoming land use conflicts and enables the proposal of planning measures on a regional and local scale. The map for the regional planning was compiled at a 1:50,000 scale and encompasses the whole municipal land area where uses are mainly rural. The map for the local planning was compiled at a 1:10,000 scale and encompasses the urban area. Most of the classification and operations on maps used spatial analyst tools available in the Geographical Information System. The regional studies showed that the greater part of Analandia’s territory presents appropriate land uses. The local-scale studies indicate that the majority of the densely occupied urban areas are in suitable land. Although the situation is in general positive, municipal policies should address the identified and expected land use conflicts, so that it can be further improved.     

Morphosedimentary analysis of the Limoeiro Stream (center-northern Minas Gerais State,Brazil): clues to the eastward tilting of southern Espinhaco range sites

The morphosedimentary evolution of a sector of the southern Espinhaco range (northern Minas Gerais State, Brazil) and its regional neotectonic setting are presented herein. The studied site is a stream at base level flowing along the western border of the range. Its identification was accomplished by using remote sensing techniques including the analysis of 3D slope models generated with shuttle radar topography mission images. The main geomorphological features of the identified site were surveyed in a 1:500 scale. In addition, seven stratigraphic logs are described. A regional geologic compilation and facies diagrams were used as a basis for the integration of the geomorphological and stratigraphic data, which produced some conclusions about the recent tectonic reactivations at the eastern border of Sao Francisco Craton. The results point to a local eastward tilting of the Espinhaco range. This fact is in accordance with previous findings in neighboring areas and results in the asymmetric evolution of the fluvial valley, as well as the regional relief.     

Groundwater flow model, recharge estimation and sustainability in an arid region of Patagonia, Argentina

The Península Valdés, in northeastern Patagonia, Argentina, is characterised by its arid climate and the lack of perennial watercourses; thus, all economic activities depend on the groundwater resources. Water demand is mainly associated with tourism, which is centralised in Puerto Pirámides and supplied by a water desalination plant, and to sheep farming, supplied by the local aquifer. Due to the exponential growth of tourism, the government is planning to exploit groundwater and convey it by aqueduct to the abovementioned locality. The objectives of this study were to corroborate the conceptual geohydrological model, to develop a mathematical model to simulate the response of the aquifer to different scenarios, and to assess the incidence of water input into the system as a variable—a function that poses difficulties in the models for arid regions. The Visual Modflow 4.1 code was used, calibrating it in trial-and-error mode, changing the recharge and hydraulic conductivity parameters with different variants in the recharge zone and in the inclusion or exclusion of the evapotranspiration module. Results indicate the importance of the recharge analysis by treating rainfall at daily time steps. The adjusted model was exposed to four scenarios with variations in water input and in output by pumping. It can be concluded that under different input conditions, but with a controlled extraction, the system responds in a sustainable manner.     

Geological and anthropogenic influences on sediment metal composition in the upper Paracatu River Basin, Brazil

This work reports a geochemical study of sediments from the upper Paracatu River Basin. The objective is to define the influences of Au, Zn, and Pb mineral deposits and mining activities on the sediment metal sources, distribution, and accretion. The samples were analyzed using ICP/OES, AAS, and XRD techniques and were treated with principal components analysis and the geo-accumulation index. The main geochemical processes that control the sediment composition are pyrite oxidation, muscovite weathering, carbonate dissolution, and the erosion of oxisols enriched with Zn and Pb. The upper Rico Stream has high Al, Fe, Cu, Cr, Co, and Mn concentrations due erosion of oxisols and pyrite oxidation and muscovite alteration present in the parental rock. The artisanal alluvial gold mining increased the primary rock-minerals?? weathering and Hg sediment concentration. The lower Escuro River and Santa Catarina Stream are enriched with Zn and Pb due the erosion of metal-rich soils formed over galena, sphalerite, calamine, and willemite mineral deposits located upstream. Elements such as Ca, Mg, and Ba have low concentrations throughout the sampled area due the high solubility of these metals-bearing minerals. The dispersion of metals is limited by the basin geomorphology and their affinity to silt-clayey minerals and Fe and Mn oxides and hydroxides in circumneutral pH waters.     

A Truncated Pareto Model to Estimate the Under Recovery of Large Diamonds

The metallurgical recovery processes in diamond mining may, under certain circumstances, cause an under-recovery of large diamonds. In order to predict high quantiles or tail probabilities we use a Bayesian approach to fit a truncated Generalized Pareto Type distribution to the tail of the data consisting of the weights of individual diamonds. Based on the estimated tail probability, the expected number of diamonds larger than a specified weight can be estimated. The difference between the expected and observed frequencies of diamond weights above an upper threshold provides an estimate of the number of diamonds lost during the recovery process.     

A Dutch multi-date land use database: Identification of real and methodological changes

Land cover and land use are important information sources for environmental issues. One of the most important changes at the Earth's surface concerns land cover and land use. Knowledge about the location and type of these changes is essential for environmental modeling and management. Remote sensing data in combination with additional spatial data are recognized as an important source of information to detect these land cover and land use changes.     

Terrestrial laser scanning to estimate plot-level forest canopy fuel properties

This paper evaluates the potential of a terrestrial laser scanner (TLS) to characterize forest canopy fuel characteristics at plot level. Several canopy properties, namely canopy height, canopy cover, canopy base height and fuel strata gap were estimated. Different approaches were tested to avoid the effect of canopy shadowing on canopy height estimation caused by deployment of the TLS below the canopy. Estimation of canopy height using a grid approach provided a coefficient of determination of R² = 0.81 and an RMSE of 2.47 m. A similar RMSE was obtained using the 99th percentile of the height distribution of the highest points, representing the 1% of the data, although the coefficient of determination was lower (R² = 0.70). Canopy cover (CC) was estimated as a function of the occupied cells of a grid superimposed upon the TLS point clouds. It was found that CC estimates were dependent on the cell size selected, with 3 cm being the optimum resolution for this study. The effect of the zenith view angle on CC estimates was also analyzed. A simple method was developed to estimate canopy base height from the vegetation vertical profiles derived from an occupied/non-occupied voxels approach. Canopy base height was estimated with an RMSE of 3.09 m and an R² = 0.86. Terrestrial laser scanning also provides a unique opportunity to estimate the fuel strata gap (FSG), which has not been previously derived from remotely sensed data. The FSG was also derived from the vegetation vertical profile with an RMSE of 1.53 m and an R² = 0.87.