Natural and anthropogenic C2 to C6 hydrocarbons in the central-eastern Venezuelan atmosphere during the rainy season

The levels of low molecular weight hydrocarbons were measured at pristine sites and rural locations affected by hydrocarbon emissions from oil and gas producing fields in Venezuela. At the clean sites, lower concentrations of C₂ to C₆ alkanes were observed, whereas, in comparison with remotes sites, very much higher levels were measured at the polluted sites. Alkenes present relatively high concentrations, with isoprene being the most abundant, all over the study region. The main sources of alkenes are likely to be natural, mainly from vegetation. The levels of alkanes recorded at the clean sites and the alkene levels found everywhere in the region are in agreement with the values reported for other clean sites in the tropics. The increase of ozone production capacity due to the anthropogenic emissions of alkanes from oil and gas fields was estimated. Due to the presence in the atmosphere of important amounts of naturally emitted isoprene, ethene and propene, which makes a substantial contribution to the reactivity of the hydrocarbon mixture, a small increase (<5%) was estimated to occur in the capacity of the ozone production at a regional scale during the rainy season.     

An Origin for the Linear Magnetic Anomalies on Mars through Accretion of Terranes: Implications for Dynamo Timing

The proposed existence of magnetic lineations in the Terra Cimmeria and Terra Sirenum regions of Mars was initially explained by Earth-like sea-floor spreading. Here we argue instead that these lineations could have been formed at a convergent plate margin through collision and accretion of terranes. A similar process produced banded magnetic anomalies, similar in geometry and even in size to those in Earth's North American Cordillera. Because only sparse and generally weak anomalies have been detected in the martian northern lowlands, which could constitute an analog to the terrestrial oceanic crust, it is possible that the magnetic field stopped its activity while crustal recycling was still active in Mars.     

CFD simulation of airflow over a regular array of cubes. Part II: analysis of spatial average properties

In the first part of this study, results of a computational fluid dynamics simulation over an array of cubes have been validated against a set of wind-tunnel measurements. In Part II, such numerical results are used to investigate spatially-averaged properties of the flow and passive tracer dispersion that are of interest for high resolution urban mesoscale modelling (e.g. non resolved obstacle approaches). The results show that vertical profiles of mean horizontal wind are linear within the canopy and logarithmic above. The drag coefficient, derived from the numerical results using the classical formula for the drag force, is height dependent (it decreases with height). However, a modification of the formula is proposed (accounting for subgrid velocity scales) that makes the drag coefficient constant with height. Results also show that the dispersive fluxes are similar in magnitude to the turbulent fluxes, and that they play a very important role within the canopy. Vertical profiles of turbulent length scales (to be used in k–l closure schemes, where k is the turbulent kinetic energy and l a turbulent length scale) are also derived. Finally the distribution of the values around the mean over the reference volumes are analysed for wind and tracer concentrations.     

Ordovician igneous and metamorphic units in southeastern Puna: New U–Pb and Sm–Nd data and implications for the evolution of northwestern Argentina

New field, petrological, geochemical, and geochronological data (U–Pb and Sm–Nd) for Ordovician rock units in the southeastern Puna, NW Argentina, indicate two lithostratigraphic units at the eastern–northeastern border of salar Centenario: (1) a bimodal volcanosedimentary sequence affected by low- to medium-grade metamorphism, comprising metasediments associated with basic and felsic metavolcanic rocks, dated 485 ± 5 Ma, and (2) a plutonic unit composed of syenogranites to quartz-rich leucogranites with U–Pb zircon ages between 462 ± 7 and 475 ± 5 Ma. Felsic metavolcanic and plutonic rocks are peraluminous and show similar geochemical differentiation trends. They also have similar Sm–Nd isotopic compositions (T_DM model ages of 1.54–1.78 Ga; ε_Nd(T) values ranging from −3.2 to −7.5) that suggest a common origin and derivation of the original magmas from older (Meso-Paleoproterozoic?) continental crust. Mafic rocks show ε_Nd(T) ranging from +2.3 to +2.5, indicating a depleted mantle source. The data presented here, combined with those in the literature, suggest Ordovician magmatism mainly recycles preexisting crust with minor additions of juvenile mantle-derived material.     

Irrigated area determination: a case study in the Province of San Juan,Argentina

Much of the central-western region of Argentina, where San Juan Province is located, experiences arid to semi-arid climatic conditions with low average annual rainfall accompanied by substantial evapotranspiration. Consequently, a viable crop industry depends to a large extent upon irrigation from major river systems. Increasing demand for water in the lower basin of the San Juan River is emphasizing the need for more accurate estimates of water used for irrigation. Since the water demand for a particular crop is very closely related to crop area, monitoring the area of crop under irrigation is considered a proxy for the amount of water used. Landsat 5 imagery for the growing season, field data and aerial photographs were used to evaluate crop area.     

Analyticity, scaling and renormalization for some complex analytic dynamical systems

We review some results about the analytic structure of Lindstedt series for some complex analytic dynamical systems: in particular, we consider Hamiltonian maps (like the standard map and its generalizations), the semi-standard map and Siegel's problem of the linearization of germs of holomorphic diffeomorphisms of ( ,0). The analytic structure of those series can be studied numerically using Padé approximants, and one can show the existence of natural boundaries for real, diophantine values of the rotation number; by complexifying the rotation number, we show how these natural boundaries arise from the accumulation of singularities due to resonances, providing a new intuitive insight into the mechanism of the break-down of invariant KAM curves. Moreover, we study the Lindstedt series at resonances, i.e. for rational values of the rotation number, by suitably rescaling to 0 the value of the perturbative parameter, and a simple analytic structure emerges. Finally, we present some proofs for the simplest models and relate these results to renormalization ideas.     

Dynamical Properties of a Sample of Ellipticals

On the basis of Jeans equations we study some dynamical properties of a sample of E galaxies considered as oblate and prolate spheroids. Although the results emphasize the anisotropy as the dominant dynamical factor both for oblate and prolate configurations, the sample contains some oblate galaxies apparently isotropic consistent with full rotational support. Comparisons of the mass-to-luminosity ratios obtained from our models with ratios derived from recent evolutionary synthesis models do not seem to leave room for nonluminous matter within the ranges (of the order of one de Vaucouleurs' radius) of the kinematical observations. Such comparisons suggest that a flatter than the classical Salpeter IMF would lead to better agreement with the dynamical results obtained within the framework of our models.     

Levels of chlorinated hydrocarbons and trace metals in bivalves and nearshore sediments from the Dominican Republic

Bivalves (Crassostrea rizhophorae, Isognomon alatus, Codakia orbicularis Linné, and Tellina fausta) and sediment samples collected from 12 locations along the Dominican Republic coastline were used to assess the degree of nearshore contamination by selected chlorinated hydrocarbons and heavy metals. Concentrations of total chlordanes, DDTs and PCBs ranged from 0.51 to 7.47 ng/g, < MDL to 30.9 ng/g and 11.3 to 82.3 ng/g, and from < MDL to 1.73 ng/g, 0.21 to 12.5 ng/g and 0.46 to 41.9 ng/g in bivalves and surface sediments, respectively. The concentration ranges of predominantly anthropogenic Cu, Pb and Zn were 3.08–866 μg/g, 0.08–1.46 μg/g and 22.9–4380 μg/g in bivalve soft parts and 1.01–111 mg/g, 0.420–134 μg/g and 1.96–277 μg/g in surface sediments, respectively. Mercury concentrations ranged from 0.290 to 7.02 μg/g and from 0.096 to 0.565 μg/g in both matrices. The relatively high Hg concentrations found in bivalves from two stations in Bahia Samana, near to a known source of past Hg contamination in the sediments, require a more in-depth survey of the area. In general the concentrations of selected chlorinated hydrocarbons and trace metals, compared with those reported for the same matrices in the Caribbean and west Atlantic coastal areas, show at present the existence of only very localized contamination problems in the Dominican Republic.