The long-term residual circulation in Long Island sound

Current meter data were acquired in Long Island Sound over a period of about 6 mo in 1988 at six different transects. The averages of the low-passed residuals represent the contributions from tidal steering and density forcing. It is found that the long-term residual circulation starts out with a classical estuarine pattern at the Race. The flows into and out of the Sound are vertically partitioned by Long Sand Shoal; they gradually revert back to classical vertically layered estuarine circulation as the Central Basin is traversed. Further west, the bottom oceanic water becomes a westward flowing swift jet close to the Connecticut shore, while the East River water is constrained to flow eastward along the Long Island coast. Counterclockwise gyres, identified in the Eastern Narrows and Western Basin, may increase residence times of polluted East River water in the western Long Island Sound.     

U–Pb evidence for a polyorogenic evolution of the HP–HT units of the NW Iberian Massif

. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision.     

Rare earth and trace elements in igneous and high-temperature metamorphic minerals of oceanic gabbros (MARK area, Mid-Atlantic Ridge)

SIMS analyses have been carried out on clinopyroxenes, plagioclases and amphiboles of six gabbroic samples from Holes 921–924 of the Ocean Drilling Program Leg 153 sited in the MARK area of the Mid-Atlantic Ridge at the ridge–transform intersection, to investigate the rare earth, trace and volatile element distribution in the lower ocean crust during igneous crystallization and higher grade metamorphic conditions. The metagabbros underwent granulite to subgreenschist facies conditions through three main tectono-metamorphic phases: (1) ductile regime (750 < T < 1000 °C and P ≈ 0.3 GPa); (2) transitional regime (600 < T < 700 °C and P ≈ 0.2 GPa); (3) brittle regime (350 ≤ T < 600 °C and P < 0.2 GPa). Igneous clinopyroxenes show C1-chondrite normalized patterns depleted in LREE, and nearly flat for HREE. The rare earth and trace element distributions in igneous clinopyroxenes and plagioclases indicate that these minerals act as REE reservoirs, and comprise the main contribution to the overall rock content. The abundances in igneous minerals reflect the degree of fractionation of the parent liquids. In metamorphic clinopyroxenes recrystallized in anhydrous assemblages, the REE and trace elements patterns mimic those of the primary ones. Conversely, clinopyroxene re-equilibrated in amphibole-bearing assemblages shows a significant increase in REE, Ti, Zr, Y and V, a negative Eu anomaly, and slight decreases in Sr and Ba. An overall increase of REE and some trace elements is evident in hydrous assemblages, with preferential partitioning in the amphibole. It shows high Ti (18196–22844 ppm), LREE depleted patterns and La_N/Sm_N=0.10–0.33, La_N/Yb_N=0.10–0.30. Amphiboles from granoblastic assemblages show homogeneous patterns with no or a positive anomaly for Ti_N and negative anomalies for Sr_N and Zr_N. Volatiles in amphibole are low, with Cl/F < 1; H₂O% is significantly lower than the stoichiometric ratio (1.33–1.53%). The composition of the clinopyroxene and amphibole recrystallized in low-strain domains records evidence of incomplete re-equilibration, and element diffusion and partitioning is in part controlled by the textural site. The possible origins of the fluids involved in the metamorphic recrystallization are discussed: (1) remobilization from igneous amphibole; (2) exsolution from evolved melts; (3) introduction of seawater-derived fluids modified in rock-dominated systems; (4) injection of highly evolved hydrous melts during the metamorphic process. Received: 6 September 1999 / Accepted: 6 March 2000     

Response of single benthic metrics and multi-metric methods to anthropogenic pressure gradients, in five distinct European coastal and transitional ecosystems

In recent times many benthic indices have been proposed to assess the ecological quality of marine waters worldwide. In this study we compared single metrics and multi-metric methods to assess coastal and transitional benthic status along human pressure gradients in five distinct environments across Europe: Varna bay and lake (Bulgaria), Lesina lagoon (Italy), Mondego estuary (Portugal), Basque coast (Spain) and Oslofjord (Norway). Hence, 13 single metrics (abundance, number of taxa, and several diversity and sensitivity indices) and eight of the most common indices used within the European Water Framework Directive (WFD) for benthic assessment were selected: index of size spectra (ISS), Benthic assessment tool (BAT), Norwegian quality index (NQI), Multivariate AMBI (M-AMBI), Benthic quality index (BQI), (Benthic ecosystem quality index (BEQI), Benthic index based on taxonomic sufficiency (BITS), and infaunal quality index (IQI). Within each system, sampling sites were ordered in an increasing pressure gradient according to a preliminary classification based on professional judgement. The different indices are largely consistent in their response to pressure gradient, except in some particular cases (i.e. BITS, in all cases, or ISS when a low number of individuals is present). Inconsistencies between indicator responses were most pronounced in transitional waters (i.e. IQI, BEQI), highlighting the difficulties of the generic application of indicators to all marine, estuarine and lagoonal environments. However, some of the single (i.e. ecological groups approach, diversity, richness) and multi-metric methods (i.e. BAT, M-AMBI, NQI) were able to detect such gradients both in transitional and coastal environments, being these multi-metric methods more consistent in the detection than single indices. This study highlights the importance of survey design and good reference conditions for some indicators. The agreement observed between different methodologies and their ability to detect quality trends across distinct environments constitutes a promising result for the implementation of the WFD’s monitoring plans. Moreover, these results have management implications, regarding the dangers of misclassification, uncertainty in the assessment, use of conflicting indices, and testing and validation of indices.     

Love wave tomography in Italy from seismic ambient noise

We estimate Love wave empirical Green's functions from cross-correlations of ambient seismic noise to study the crust and uppermost mantle structure in Italy.Transverse-component ambient noise data from October 2005 through March 2007 recorded at 114 seismic stations from the Istituto Nazionale di Geofisica e Vulcanologia (INGV) national broadband network,the Mediterranean Very Broadband Seismographic Network (MedNet) and the Austrian Central Institute for Meteorology and Geodynamics (ZAMG) yield more than 2 000 Love wave group velocity measurements using the multiple-filter analysis technique.In the short period band (5-20 s),the cross-correlations show clearly one-sided asymmetric feature due to non-uniform noise distribution and high local activities,and in the long period band (20 s) this feature becomes weak owing to more diffusive noise distribution.Based on these measurements,Love wave group velocity dispersion maps in the 8-34 s period band are constructed,then the SH wave velocity structures from the Love wave dispersions are inverted.The final results obtained from Love wave data are overall in good agreement with those from Rayleigh waves.Both Love and Rayleigh wave inversions all reveal that the Po plain basin is resolved with low velocity at shallow depth,and the Tyrrhenian sea is characterized with higher velocity below 8 km due to its thin oceanic crust.     

Potentially modified hydropower production under climate change in the Italian Alps

We present an assessment of the potential impacts of climate change on hydropower production within a paradigmatic, very highly exploited cryospheric area of upper Valtellina valley in the Italian Alps. Based on dependable and unique hydrological measures from our high‐altitude hydrometric network Idrostelvio during 2006–2015, we set up the Poly‐Hydro model to mimic the cryospheric processes driving hydrological flow formation in this high‐altitude area. We then set up an optimization tool, which we call Poly‐Power, to maximize the revenue of the plant manager under given hydrological regimes, namely, by proper operation of the hydroelectric production scheme (reservoirs, pipelines, and power plants) of the area. We then pursue hydrological projections until 2100, feeding Poly‐Hydro with the downscaled outputs of three general circulation models from the Intergovernmental Panel on Climate Change Fifth Assessment Report, under the scenarios Representative Concentration Pathway (RCP) 2.6, RCP 4.5, and RCP 8.5. We assess hydrological flows in two reference decades, that is, at half century (2040–2049), and end of century (2090–2099). We then feed the so obtained hydrological scenarios as inputs to Poly‐Power, and we project future production of hydroelectric power, with and without reoperation of the system. The average annual stream flows for hydropower production decreases along the century under our scenarios (?21 to +7%, on average ? 5% at half century; ?17 to ?2%, average ? 8%, end of century), with ice cover melting unable to offset such decrease. Reduction in snowfall and increase in liquid rainfall are the main factors affecting the modified hydrological regime. Energy production (and revenues) at half century may increase under our scenarios (?9 to +15%, +3% on average). At the end of century in spite of a projected increase on average (?7 to +6%, +1% on average), under the warmest scenario RCP 8.5 decrease of energy production is consistently projected (?4% on average). Our results provide an array of potential scenarios of modified hydropower production under future climate change and may be used for brain storming of adaptation strategies.     

An enhanced ensemble Kalman filter scheme incorporating model error in sequential coupling between flow and geomechanics

In this work, we construct a new methodology for enhancing the predictive accuracy of sequential methods for coupling flow and geomechanics while preserving low computational cost. The new computational approach is developed within the framework of the fixed-stress split algorithm procedure in conjunction with data assimilation based on the ensemble Kalman filter (EnKF). In this context, we identify the high-fidelity model with the two-way formulation where additional source term appears in the flow equation containing the time derivative of total mean stress. The iterative scheme is then interlaced with data assimilation steps, which also incorporate the modeling error inherent to the EnKF framework. Such a procedure gives rise to an “enhanced one-way formulation,” exhibiting substantial improvement in accuracy compared with the classical one-way method. The governing equations are discretized by mixed finite elements, and numerical simulation of a 2D slab problem between injection and production wells illustrate the tremendous achievement of the method proposed herein.     

A polarimetric study of Asteroid 25143 Itokawa

The near-Earth Asteroid 25143 Itokawa, the target of the Japanese space mission Hayabusa, was observed in June, 2004 with the Torino photopolarimeter attached at the 2.15 m telescope of the El Leoncito Observatory (Argentina). The degree of linear polarization in five colors was measured over a wide range of phase angles, between 40° and 80°. The data obtained are sufficient to derive an estimate of the asteroid's albedo of 0.24±0.01, which is in good agreement with the S-type taxonomic classification of this object. The phase-polarization curve has been sampled in UBVRI colors, covering a wide range of phase angles that cannot be reached by Earth-based observations of Main Belt asteroids.     

Seasonal variation of gaseous HNO3 and NH3 at a Tropical Savannah site

Gaseous nitric acid and ammonia were sampled with annular denuders at a forest savannah site from April to December 1987. The analysis of the extract was made spectrophotometrically and by a selective electrode for NO₃ ^– and NH₄ ⁺, respectively. Higher concentrations were observed during the vegetation burning period at the end of the dry season. In the studied savannah area, large soil emissions of NO occur during the rainy season, although very low concentrations of HNO₃ (0.035 ppb) and also of particulate NO₃ ^– (0.43 g m^-3) were observed; it is likely that NO_x are lost by fast vertical transport to the upper troposphere. During the nonburning period, the average concentration of NH₃ was 2.7 ppb, which is much lower than values given in the literature for the tropical America atmosphere. The concentrations of HNO₃ and NH₃ were always below the values needed to produce ammonium nitrate aerosols.     

Impacts of Realistic Urban Heating,Part I: Spatial Variability of Mean Flow,Turbulent Exchange and Pollutant Dispersion

As urbanization progresses, more realistic methods are required to analyze the urban microclimate. However, given the complexity and computational cost of numerical models, the effects of realistic representations should be evaluated to identify the level of detail required for an accurate analysis. We consider the realistic representation of surface heating in an idealized three-dimensional urban configuration, and evaluate the spatial variability of flow statistics (mean flow and turbulent fluxes) in urban streets. Large-eddy simulations coupled with an urban energy balance model are employed, and the heating distribution of urban surfaces is parametrized using sets of horizontal and vertical Richardson numbers, characterizing thermal stratification and heating orientation with respect to the wind direction. For all studied conditions, the thermal field is strongly affected by the orientation of heating with respect to the airflow. The modification of airflow by the horizontal heating is also pronounced for strongly unstable conditions. The formation of the canyon vortices is affected by the three-dimensional heating distribution in both spanwise and streamwise street canyons, such that the secondary vortex is seen adjacent to the windward wall. For the dispersion field, however, the overall heating of urban surfaces, and more importantly, the vertical temperature gradient, dominate the distribution of concentration and the removal of pollutants from the building canyon. Accordingly, the spatial variability of concentration is not significantly affected by the detailed heating distribution. The analysis is extended to assess the effects of three-dimensional surface heating on turbulent transfer. Quadrant analysis reveals that the differential heating also affects the dominance of ejection and sweep events and the efficiency of turbulent transfer (exuberance) within the street canyon and at the roof level, while the vertical variation of these parameters is less dependent on the detailed heating of urban facets.