Microstructural evolution of the Seridó Belt, NE-Brazil: the effect of two tectonic events on development of c-axis preferred orientation in quartz

The polyphase evolution of the Seridó Belt (NE-Brazil) includes D₁ crust formation at 2.3–2.1 Ga, D₂ thrust tectonics at 1.9 Ga and crustal reworking by D₃ strike-slip shear zones at 600 Ma. Microstructural investigations within mylonites associated with D₂ and D₃ events were used to constrain the tectono-thermal evolution of the belt. D₂ shear zones commenced at deeper crustal levels and high amphibolite facies conditions (600–650 °C) through grain boundary migration, subgrain rotation and operation of quartz c-prism slip. Continued shearing and exhumation of the terrain forced the re-equilibration of high-T fabrics and the switching of slip systems from c-prism to positive and negative a-rhombs. During D₃, enhancement of ductility by dissipation of heat that came from syn-D₃ granites developed wide belts of amphibolite facies mylonites. Continued shearing, uplift and cooling of the region induced D₃ shear zones to act in ductile-brittle regimes, marked by fracturing and development of thinner belts of greenschist facies mylonites. During this event, switching from a-prism to a-basal slip indicates a thermal path from 600 to 350 °C. Therefore, microstructures and quartz c-axis fabrics in polydeformed rocks from the Seridó Belt preserve the record of two major events, which includes contrasting deformation mechanisms and thermal paths.     

Validation of Landslide Susceptibility Maps; Examples and Applications from a Case Study in Northern Spain

A procedure for validating landslide susceptibility maps wasapplied in a study area in northern Spain and the results obtained compared. Validationwas used to carry out sensitivity analysis for individual variables and combinationsof variables. The validity of different map-making methods was tested, as well as theutility of different types of Favourability Functions. The results obtained show thatvalidation is essential to determine the predictive value of susceptibility maps. Italso helps to better select the most suitable function and significant variables, thus improving the efficiency of the mapping process. Validation based on a temporal strategy makes it possible to derive hazard maps from susceptibility maps.     

Modelling nitrogen and oxygen isotope fractionation during denitrification in a lacustrine redox-transition zone

The stable isotope composition (δ¹⁵N and δ¹⁸O) of nitrate was measured during Summer 1999 in the anaerobic hypolimnion of eutrophic Lake Lugano (Switzerland). Denitrification was demonstrated by a progressive nitrate depletion coupled to increasing δ¹⁵N and δ¹⁸O values for residual nitrate. Maximum δ¹⁵N and δ¹⁸O values amounted to 27.2 and 15.7‰, respectively.¹⁵N and ¹⁸O enrichment factors for denitrification (ε) were estimated using a closed-system model and a dynamic diffusion-reaction model. Using the Rayleigh equation (closed-system approach), we obtained ε values of −11.2 and −6.6‰ for nitrogen and oxygen, respectively. The average ε values derived using the diffusion-reaction model were determined to be −20.7 ± 3.8 for nitrogen and −11.0 ± 1.7 for oxygen. Both N and O isotope fractionation appeared to be lower when denitrification rates where high, possibly in association with high organic carbon availability. In addition, variations in the isotope effects may be attributed to the variable importance of sedimentary denitrification having only a small isotope effect on the water column. The combined measurement of N and O isotope ratios in nitrate revealed that coupled nitrification-denitrification in the open-water was of minor importance. This is the first study of nitrogen and oxygen isotope effects associated with microbial denitrification in a natural lake. Moreover, this study confirms the high potential of δ¹⁸O of nitrate as a valuable biogeochemical tracer in aquatic systems, complementing nitrate δ¹⁵N.     

The large earthquake of 8 August 1303 in Crete: seismic scenario and tsunami in the Mediterranean area

By conducting a historical review of this large seismic event in the Mediterranean, it has been possible to identify both the epicentral area and the area in which its effects were principally felt. Ever since the nineteenth century, the seismological tradition has offered a variety of partial interpretations of the earthquake, depending on whether the main sources used were Arabic, Greek or Latin texts. Our systematic research has involved the analysis not only of Arab, Byzantine and Italian chronicle sources, but also and in particular of a large number of never previously used official and public authority documents, preserved in Venice in the State Archive, in the Marciana National Library and in the Library of the Museo Civico Correr. As a result, it has been possible to establish not only chronological parameters for the earthquake (they were previously uncertain) but also its overall effects (epicentral area in Crete, Imax XI MCS). Sources containing information in 41 affected localities and areas were identified. The earthquake also gave rise to a large tsunami, which scholars have seen as having certain interesting elements in common with that of 21 July 365, whose epicentre was also in Crete. As regards methodology, this research made it clear that knowledge of large historical earthquakes in the Mediterranean is dependent upon developing specialised research and going beyond the territorial limits of current national catalogues.     

An approach for quantifying geomorphological impacts for EIA of transportation infrastructures: a case study in northern Spain

A methodological proposal for the assessment of impacts due to linear infrastructures such as motorways, railways, etc. is presented. The approach proposed includes a series of specific issues to be addressed for each geomorphological feature analysed—both ‘static’ and ‘dynamic’—as well as a series of steps to be followed in the process.Geomorphic characteristics potentially affected were initially identified on the basis of a conceptual activities/impacts model that helps to single out geomorphic impacts related to environmental concerns for the area. The following issues were addressed for each individual impact: nature of potential effects; indicators that can be used to measure impacts; criteria of ‘geomorphologic performance’; procedure for measurement/prediction of changes; translation of geomorphologic impacts into significant terms from the viewpoint of human concerns; possible mitigation and/or compensation measures.The procedure has been applied to a case study corresponding to a new motorway in the Basque Country, northern Spain. Geomorphological impacts considered in this analysis included: (1) consumable resources; (2) sites of geomorphological interest; (3) land units with high potential for use, high productivity or value for conservation; (4) visual landscape; (5) slope instability processes. The procedure has been designed for implementation in a Geographic Information System (GIS) environment. Details are given on the application of the method to each individual impact analysed and results are presented in both numerical and map form.Impacts assessed were initially expressed by means of heterogeneous magnitudes, depending on the geomorphological feature considered. Those geomorphological impacts were then translated into significant terms and homogeneous magnitudes. Integration was carried out on the basis of impact values thus obtained. Final integrated results were also expressed in numerical and map form.The method proposed enables comparison of alternatives as well as ‘prediction’ and assessment of impacts in terms directly related to geomorphic characteristics. It also facilitates the expression of those impacts in terms that allow integration with other types of environmental impacts.     

Determination of Lithium, Beryllium and Boron at Trace Levels by Laser Ablation-Inductively Coupled Plasma-Sector Field Mass Spectrometry

The analytical capabilities of laser ablation (LA)-ICP-MS in determining Li, Be and B at trace levels in geological samples have been tested on a series of glass reference materials and natural samples. The LA-ICP-MS instrument used consisted of a sector-field ICP-MS coupled with a laser ablation microprobe operating at either 266 or 213 nm wavelength. Reference glasses from NIST (SRM 612, 614 and 616) and MPI-DING (KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, T1-G and ATHO-G) were selected to develop the analytical method and to assess the best instrumental configuration. A series of calcic amphiboles with different Li, Be and B concentrations were also analysed using both LA-ICP-MS and SIMS to test the applicability of the method to natural minerals. Results indicated that with a spot size of 40 μm the agreement between measured and reference values of Li, Be and B is generally better than 10% for NIST SRM 612 and 20% for NIST SRM 614. Average reproducibility at the 2s level was 10% for Li, 20% for Be and 15% for B. Limits of detection were approximately 100 ng g^-1 for Be and B and 200 ng g^-1 for Li. These results were confirmed by analyses carried out on natural amphiboles and compared well in terms of precision and accuracy with those commonly achieved by SIMS.     

Prediction of ground displacements and velocities from groundwater level changes at the Vallcebre landslide (Eastern Pyrenees, Spain)

In active landslides, the prediction of acceleration of movement is a crucial issue for the design and performance of warning systems. The landslide of Vallcebre in the Eastern Pyreenes, Spain, has been monitored since 1996 and data on rainfall, groundwater levels and ground displacements are measured on a regular basis. Displacements observed in borehole wire extensometers have shown an immediate response of the landslide to rainfall episodes. This rapid response is likely due to the presence of preferential drainage ways. The occurrence of nearly constant rates of displacement in coincidence with steady groundwater levels suggests the presence of viscous forces developed during the movement. An attempt to predict both landslide displacements and velocities was performed at Vallcebre by solving the momentum equation in which a viscous term (Bingham and power law) was added. Results show that, using similar rheological parameters for the entire landslide, computed displacements reproduce quite accurately the displacements observed at three selected wire extensometers. These results indicate that prediction of displacements from groundwater level changes is feasible.