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91.
Current chemical dispersant effectiveness tests for product selection are commonly performed with bench-scale testing apparatus. However, for the assessment of oil dispersant effectiveness under real sea state conditions, test protocols are required to have hydrodynamic conditions closer to the natural environment, including transport and dilution effects. To achieve this goal, Fisheries and Oceans Canada and the US Environmental Protection Agency (EPA) designed and constructed a wave tank system to study chemical dispersant effectiveness under controlled mixing energy conditions (regular non-breaking, spilling breaking, and plunging breaking waves). Quantification of oil dispersant effectiveness was based on observed changes in dispersed oil concentrations and oil-droplet size distribution. The study results quantitatively demonstrated that total dispersed oil concentration and breakup kinetics of oil droplets in the water column were strongly dependent on the presence of chemical dispersants and the influence of breaking waves. These data on the effectiveness of dispersants as a function of sea state will have significant implications in the drafting of future operational guidelines for dispersant use at sea. 相似文献
92.
H. Albert Gilg Yves Krüger Heinrich Taubald Alfons M. van den Kerkhof Martin Frenz Giulio Morteani 《Mineralium Deposita》2014,49(7):861-877
Fluid inclusion studies in combination with hydrogen, oxygen and sulphur isotope data provide novel insights into the genesis of giant amethyst-bearing geodes in Early Cretaceous Paraná continental flood basalts at Amestita do Sul, Brazil. Monophase liquid inclusions in colourless quartz, amethyst, calcite, barite and gypsum were analysed by microthermometry after stimulating bubble nucleation using single femtosecond laser pulses. The salinity of the fluid inclusions was determined from ice-melting temperatures and a combination of prograde and retrograde homogenisation temperatures via the density maximum of the aqueous solutions. Four mineralisation stages are distinguished. In stage I, celadonite, chalcedony and pyrite formed under reducing conditions in a thermally stable environment. Low δ34SV-CDT values of pyrite (?25 to ?32?‰) suggest biogenic sulphate reduction by organotrophic bacteria. During the subsequent stages II (amethyst, goethite and anhydrite), III (early subhedral calcite) and IV (barite, late subhedral calcite and gypsum), the oxidation state of the fluid changed towards more oxidising conditions and microbial sulphate reduction ceased. Three distinct modes of fluid salinities around 5.3, 3.4 and 0.3 wt% NaCl-equivalent characterise the mineralisation stages II, III and IV, respectively. The salinity of the stage I fluid is unknown due to lack of fluid inclusions. Variation in homogenisation temperatures and in δ18O values of amethyst show evidence of repeated pulses of ascending hydrothermal fluids of up to 80–90 °C infiltrating a basaltic host rock of less than 45 °C. Colourless quartz and amethyst formed at temperatures between 40 and 80 °C, while the different calcite generations and late gypsum precipitated at temperatures below 45 °C. Calculated oxygen isotope composition of the amethyst-precipitating fluid in combination with δD values of amethyst-hosted fluid inclusions (?59 to ?51?‰) show a significant 18O-shift from the meteoric water line. This 18O-shift, high salinities of the fluid inclusions with chloride-sulphate composition, and high δ34S values of anhydrite and barite (7.5 to 9.9?‰) suggest that sedimentary brines from deeper parts of the Guaraní aquifer system must have been responsible for the amethyst mineralisation. 相似文献
93.
In this paper, the authors present the results of both macroscopic and microscopic investigations on structure development created by repeated ice lensing in various loamy experiments. Experimental data are compared with observations performed on active forms in High Arctic and Alpine Mountain environments. Those observations are also compared with phenomena observed in fossil periglacial formations of Western Europe. Platy and short prismatic structure formation is bonded to the hydraulic and thermal conditions during ice segregation. When a long series of alternating freezing and thawing affects platy structures, the fabric evolves, also being influenced by slope and drainage conditions: cryoturbations, frostcreep, and gelifluction can appear. They are characterized by specific microfabrics which are better developed with an increasing number of cycles: this is clear in experiments where hydraulic and thermal parameters are better controlled. Vesicles are also a prominent characteristic of the surface horizon in experiments and arctic soils. The genesis of vesicles is discussed on the basis of new observations and is related to the mechanical collapse of frost-created aggregates under the mechanical work of soil air escape during soil saturation by water at thaw. 相似文献
94.
95.
Concentrations of selected heavy metals (Cr, Cu, Ni, Pb and Zn) from surface sediments, suspended particulate matter and settling particles in the southern Barcelona continental margin were studied in order to evaluate the environmental impact of the anthropogenic metals discharged by the Llobregat River in this Mediterranean area. The temporal variation of heavy metals discharged by this river onto the continental shelf is clearly related to the river water flow. Part of the fine sediment and associated heavy metals transported by the Llobregat River during periods of low river flow accumulate on the river bed, and they are totally removed and discharged onto the Barcelona continental shelf during sporadic river water flow increases. Metals produce significant anomalies of chromium (×2.5), copper (×3.4) and zinc (×3.7) in the surface sediments of the Llobregat prodelta and tend to be transported along the continental shelf following the mean flow. Metals associated with the finest suspended flocs transferred to the slope are controlled by the shelf-slope density front and are transported along slope by the general geostrophic current, instead of accumulating and becoming concentrated in the slope bottom sediments. Settling particulate matter collected in sediment traps on the Barcelona continental slope offshore of the shelf-slope front shows low heavy metal concentrations except in a few sediment trap samples that are significantly metal-enriched in chromium (×4.5) and zinc (×6.8). This enrichment is associated with very short and sporadic river flow increases and is only recorded inside the Foix submarine canyon, which acts as a preferential conduit for the shelf-slope sediment transfer. 相似文献
96.
Albert M. Swain 《Quaternary Research》1978,10(1):55-68
A 2000-year accumulation of varved sediments from Hell's Kitchen Lake in north-central Wisconsin was analyzed for pollen, charcoal, and seeds. The varves provided an accurate time scale for the study. The pollen record indicates changes on two different time scales. Short-term changes lasting several decades appear to be superimposed on long-term changes lasting several centuries. The short-term changes are related to individual fires, and the long-term changes result from increases or decreases in the frequency of these perturbations. From 2000 to 1150 years ago the average interval between fires was about 100 years, and from 1150 to 120 years ago the interval increased to about 140 years. Evidence from pollen, seeds, and charcoal at Hell's Kitchen Lake suggests that at least two “moist” intervals occurred during the past 2000 years, one between 2000 and 1700 years ago and the other between 600 and 100 years ago. A third but minor “moist” period occurred about 1150 to 850 years ago. A pollen and seed diagram shows that these intervals are characterized by increased percentages of white pine pollen, hemlock pollen, and yellow birch seeds, and by decreased levels of charcoal. The “dry” interval of 1700 to 1150 years ago is characterized by increased percentages of paper birch seeds, oak pollen, and aspen pollen, along with high levels of charcoal. The times of climatic change indicated at Hell's Kitchen Lake are nearly synchronous with those based on studies of tree rings, soils, glacial activity, and other pollen studies from various regions of North America, but the direction of these inferred changes is not always the same. This result suggests that the long-wave pattern of the general circulation has been variable during the past 2000 years. 相似文献
97.
Robert J. Beare Malcolm K. Macvean Albert A. M. Holtslag Joan Cuxart Igor Esau Jean-Christophe Golaz Maria A. Jimenez Marat Khairoutdinov Branko Kosovic David Lewellen Thomas S. Lund Julie K. Lundquist Anne Mccabe Arnold F. Moene Yign Noh Siegfried Raasch Peter Sullivan 《Boundary-Layer Meteorology》2006,118(2):247-272
Results are presented from the first intercomparison of large-eddy simulation (LES) models for the stable boundary layer (SBL), as part of the Global Energy and Water Cycle Experiment Atmospheric Boundary Layer Study initiative. A moderately stable case is used, based on Arctic observations. All models produce successful simulations, in as much as they generate resolved turbulence and reflect many of the results from local scaling theory and observations. Simulations performed at 1-m and 2-m resolution show only small changes in the mean profiles compared to coarser resolutions. Also, sensitivity to subgrid models for individual models highlights their importance in SBL simulation at moderate resolution (6.25 m). Stability functions are derived from the LES using typical mixing lengths used in numerical weather prediction (NWP) and climate models. The functions have smaller values than those used in NWP. There is also support for the use of K-profile similarity in parametrizations. Thus, the results provide improved understanding and motivate future developments of the parametrization of the SBL. 相似文献
98.
Microzooplankton production in the oceans 总被引:7,自引:0,他引:7
99.
Markov chain Monte Carlo methods for conditioning a permeability field to pressure data 总被引:3,自引:0,他引:3
Generating one realization of a random permeability field that is consistent with observed pressure data and a known variogram
model is not a difficult problem. If, however, one wants to investigate the uncertainty of reservior behavior, one must generate
a large number of realizations and ensure that the distribution of realizations properly reflects the uncertainty in reservoir
properties. The most widely used method for conditioning permeability fields to production data has been the method of simulated
annealing, in which practitioners attempt to minimize the difference between the ’ ’true and simulated production data, and
“true” and simulated variograms. Unfortunately, the meaning of the resulting realization is not clear and the method can be
extremely slow. In this paper, we present an alternative approach to generating realizations that are conditional to pressure
data, focusing on the distribution of realizations and on the efficiency of the method. Under certain conditions that can
be verified easily, the Markov chain Monte Carlo method is known to produce states whose frequencies of appearance correspond
to a given probability distribution, so we use this method to generate the realizations. To make the method more efficient,
we perturb the states in such a way that the variogram is satisfied automatically and the pressure data are approximately
matched at every step. These perturbations make use of sensitivity coefficients calculated from the reservoir simulator. 相似文献
100.
Albert J. Parker 《The Professional geographer》1992,44(2):147-160
Variation in seedling/sapling densities and stand diameter forms for six coniferous tree species is related to stand structural development and to elevation and topography in Lassen Volcanic National Park, California. Understory density patterns reflect differences in species tolerance; densities decrease with stand development for shade intolerant pines, but increase for shade tolerant firs and mountain hemlock. Pine species exhibit reverse-J diamter structures on recently disturbed sites, and decreaser and random forms elsewhere. More tolerant fir species show topographically mediated patterns of diameter structure, with reverse-J form common on northerly exposures and upland sites, but with decreaser and random forms on more xeric slopes. Interaction among species tolerance, environmental setting, and disturbance history yields a complex mosaic of stand diameter structures in the Lassen landscape. 相似文献