Assessment of chemical dispersant effectiveness in a wave tank under regular non-breaking and breaking wave conditions

Current chemical dispersant effectiveness tests for product selection are commonly performed with bench-scale testing apparatus. However, for the assessment of oil dispersant effectiveness under real sea state conditions, test protocols are required to have hydrodynamic conditions closer to the natural environment, including transport and dilution effects. To achieve this goal, Fisheries and Oceans Canada and the US Environmental Protection Agency (EPA) designed and constructed a wave tank system to study chemical dispersant effectiveness under controlled mixing energy conditions (regular non-breaking, spilling breaking, and plunging breaking waves). Quantification of oil dispersant effectiveness was based on observed changes in dispersed oil concentrations and oil-droplet size distribution. The study results quantitatively demonstrated that total dispersed oil concentration and breakup kinetics of oil droplets in the water column were strongly dependent on the presence of chemical dispersants and the influence of breaking waves. These data on the effectiveness of dispersants as a function of sea state will have significant implications in the drafting of future operational guidelines for dispersant use at sea.     

Soil fertility evolution and landscape dynamics in a Mediterranean area: a case study in the Sant Llorenç Natural Park (Barcelona, NE Spain)

The cartography of land covers was used to study fertility and soil evolution in a mountainous Mediterranean area during the anthropocene period ( Crutzen P J 2002 Geology of mankind Nature 415 23). The aim was to determine changes in fertility as agricultural lands were abandoned in the 14 000 hectare area that constitutes Sant Llorenç del Munt Natural Park in a pre-coastal Catalan mountain range (north-eastern Iberian Peninsula). The analysis of land covers using vegetation maps, orthorectified images and aerial photography has allowed us to differentiate six vegetation groups: holm-oak wood, pine grove, oak wood, scrub, active agricultural fields and abandoned agricultural fields. The anthropic covers over the past 100 years were subdivided into five categories: active fields and those abandoned over four time periods. Study variables include field shape (concave, convex, flat), orientation (north, south) and slope (ranging from 12º to 24º). The parameters used for the physical-chemical soil analysis included organic material, phosphorous and potassium; fertility was classified based on groups, types and classes. The results indicate that even when the visual appearance of certain landscapes is similar, the edaphic characteristics may be very different. Changes induced by human disturbance share this phenomenon. Therefore, land management should be considered globally, taking into account vegetation, soils and water as interdependent factors, since it is their interaction that produces landscape and most affects its evolution over time.     

An Intercomparison of Large-Eddy Simulations of the Stable Boundary Layer

Results are presented from the first intercomparison of large-eddy simulation (LES) models for the stable boundary layer (SBL), as part of the Global Energy and Water Cycle Experiment Atmospheric Boundary Layer Study initiative. A moderately stable case is used, based on Arctic observations. All models produce successful simulations, in as much as they generate resolved turbulence and reflect many of the results from local scaling theory and observations. Simulations performed at 1-m and 2-m resolution show only small changes in the mean profiles compared to coarser resolutions. Also, sensitivity to subgrid models for individual models highlights their importance in SBL simulation at moderate resolution (6.25 m). Stability functions are derived from the LES using typical mixing lengths used in numerical weather prediction (NWP) and climate models. The functions have smaller values than those used in NWP. There is also support for the use of K-profile similarity in parametrizations. Thus, the results provide improved understanding and motivate future developments of the parametrization of the SBL.     

Evaluation of the Weather Research and Forecasting Mesoscale Model for GABLS3: Impact of Boundary-Layer Schemes,Boundary Conditions and Spin-Up

We evaluated the performance of the three-dimensional Weather Research and Forecasting (WRF) mesoscale model, specifically the performance of the planetary boundary-layer (PBL) parametrizations. For this purpose, Cabauw tower observations were used, with the study extending beyond the third GEWEX Atmospheric Boundary-Layer Study (GABLS3) one-dimensional model intercomparison. The WRF model (version 3.4.1) contains 12 different PBL parametrizations, most of which have been only partially evaluated. The GABLS3 case offers a clear opportunity to evaluate model performance, focusing on time series of near-surface weather variables, radiation and surface flux budgets, vertical structure and the nighttime inertial oscillation. The model results revealed substantial differences between the PBL schemes. Generally, non-local schemes tend to produce higher temperatures and higher wind speeds than local schemes, in particular, for nighttime. The WRF model underestimates the 2-m temperature during daytime (about \(2\) K) and substantially underestimates it at night (about \(4\) K), in contrast to the previous studies where modelled 2-m temperature was overestimated. Considering the 10-m wind speed, during the night turbulent kinetic energy based schemes tend to produce lower wind speeds than other schemes. In all simulations the sensible and latent heat fluxes were well reproduced. For the net radiation and the soil heat flux we found good agreement with daytime observations but underestimations at night. Concerning the vertical profiles, the selected non-local PBL schemes underestimate the PBL depth and the low-level jet altitude at night by about 50 m, although with the correct wind speed. The latter contradicts most previous studies and can be attributed to the revised stability function in the Yonsei University PBL scheme. The local, turbulent kinetic energy based PBL schemes estimated the low-level jet altitude and strength more accurately. Compared to the observations, all model simulations show a similar structure for the potential temperature, with a consistent cold bias ( \(\approx \) 2 K) in the upper PBL. In addition to the sensitivity to the PBL schemes, we studied the sensitivity to technical features such as horizontal resolution and domain size. We found a substantial difference in the model performance for a range of 12, 18 and 24 h spin-up times, longer spin-up time decreased the modelled wind speed bias, but it strengthened the negative temperature bias. The sensitivity of the model to the vertical resolution of the input and boundary conditions on the model performance is confirmed, and its influence appeared most significant for the non-local PBL parametrizations.     

Assessing Winter Wheat Responses to Climate Change Scenarios: A Simulation Study in the U.S. Great Plains

Hard red winter wheat (Triticum aestivum L.) is a major crop in the Great Plains region of the U.S. The goal of this assessment effort was to investigate the influence of two contrasting global climate change projections (U.K. Hadley Center for Climate Prediction and Research and Canadian Centre for Climate Modelling and Analysis) on the yield and percent kernel nitrogen content of winter wheat at three locations in Nebraska. These three locations represent sub-humid and semi arid areas and the transition between these areas and are also representative of major portions of the winter wheat growing areas of the central Great Plains. Climate scenarios based on each of the projections for each location were developed using the LARS-WG weather generator along with data from automated weather stations. CERES-Wheat was used to simulate the responses for two contrasting cultivars of wheat using two sowing dates. The first sowing date represented current sowing dates appropriate for each location. The second sowing date was later and represents the approximate date when the mean air temperature from the climate scenarios is the same as the mean air temperature from the actual climate data at the current sowing dates. The yield and percent kernel nitrogen content using the two climate scenarios generally decrease going from the sub-humid eastern to the semi arid western parts of Nebraska. Results from these simulations indicate that yield and percent kernel nitrogen content using the two climate scenarios could not both be maintained at levels currently simulated. Protein content (directly related to kernel nitrogen content) and end-use quality are the primary determinants for the use of hard red winter wheat in baked goods. Nitrogen management and new cultivars, which can enhance the uptake and translocation of nitrogen, will be proactive steps to meet the challenges of global climate change as represented by these climate scenarios.     

西藏高原南部雅鲁藏布江缝合带地区地壳电性结构研究

为了探测西藏高原南部雅鲁藏布江缝合带地区地壳浅部和深部构造沿东西和南北方向的变化特征,在雅鲁藏布江缝合带地区布设了三条南北向剖面(错那—墨竹工卡、亚东—雪古拉、吉隆—措勤),采用超宽频带大地电磁测深方法进行了地壳、上地幔电性结构探测研究,发现该区主要电性结构特征为：1. 雅鲁藏布江缝合带附近表层发育大规模的高阻体,岩体延伸最深达30km以上,是冈底斯花岗岩体的反映. 2. 雅鲁藏布江缝合带的南部有小规模的良导体,在其下方和北侧发育有大规模良导体. 3. 沿剖面从南往北壳内普遍发育良导体,各良导体主体间是不连续的,规模逐渐增大,总体北倾,在缝合带附近产状较陡. 4. 在雅鲁藏布江缝合带附近良导体由西往东规模逐渐增大,导电性逐渐变好,相对雅鲁藏布江在剖面上的位置逐渐南移. 这些重要的电性特征可能是印度板块向北俯冲所形成的,深部大规模的良导体特征沿东西向的差异可能是板块碰撞引起物质沿东西向运移作用的结果.     

Crustal thickening and crustal extension as controls on the evolution of the drainage network of the central Swiss Alps between 30 Ma and the present: constraints from the stratigraphy of the North Alpine Foreland Basin and the structural evolution of the Alps

The combined information about sedimentary petrography from the North Alpine Foreland Basin and structural geology from the Alps allows a qualitative reconstruction of the drainage network of the central Swiss Alps between 30 Ma and the present. This study suggests that crustal thickening and crustal thinning significantly controlled the location of the drainage divide. It also reveals the possible controls of crustal thickening/thinning on the change of the orientation of the drainage network from across-strike between 30 and 14 Ma to along-strike thereafter. Initial crustal thickening in the rear of the wedge is considered to have formed the drainage divide between north and south at 30 Ma. Because the location of crustal thickening shifted from east to west between ≈30–20 Ma, the catchment areas of the eastern dispersal systems reached further south than those of the western Alpine palaeorivers for the same time slice. Similarly, the same crustal dynamics appear to have controlled two phases of denudation that are reflected in the Molasse Basin by petrographic trends. Uplift in the rear of the wedge caused the Alpine palaeorivers to expand further southward. This is reflected in the foreland basin by increasing admixture of detritus from structurally higher units. However, tectonic quiescence in the rear of the wedge allowed the Alpine palaeorivers to cut down into the Alpine edifice, resulting in an increase of detritus from structurally lower units. Whereas uplift in the rear of the wedge was responsible for initiation of the Alpine drainage systems, underplating of the external massifs some 50 km further north is thought to have caused along-strike deviation of the major Alpine palaeorivers. Besides crustal thickening, extension in the rear of the wedge appears to have significantly controlled the evolution of the drainage network of the western Swiss Alps. Slip along the Simplon detachment fault exposed the core of the Lepontine dome, and caused a 50-km-northward shift of the drainage divide.